三烯

FeCl_3 was used to catalyse the acylation reaction of triisobutylene by acetic anhydride at room temperature.

室温下FeCl3用于催化三聚异丁烯与乙酸酐的酰化反应。

We investigated constituent of triterpenoid saponins ofAlbizzia, two new compounds together with two known compounds were isolated from Albizzia julibrissin Durazz. by using column chromatography (macroreticular resin, silica gel, Sephadex gel, reverse phase silica gel),preparative HPLC methods et al.On the basis of spectroscopic analysis, including IR,ESI-MS,~1H-NMR,~(13)C-NMR,HMBC,HMQC,~1H-~1HCOSY and chemical methods, the structure of two new compounds were identified as 3 - O -[β-D-xylopyranosyl(1→2)-β-D-fucopyranosyl (1→6)-β- D -2- deoxy - 2 - acetoamidoglucopyranosyl] -21-O-[(6S)-2- trans- 2,6-dimethyl - 6 - O-β- D - quinovopyranosyl -2,7- octadienoyl] - acacic acid- 28 - O-β-D-glucopyranosyl(1→3)[α-L-arabinofuranosyl(1→4)]-α-L-rhamnopyranosyl(1→2)-β-D-glucopyranoside acacic acid 3- O -β- D- glucopyranosy(1→3)-β- D- fucopyranosl(1→6) [β-D- xylopyranosyl (1→2)]-β-D-glucopyranoside ;two known compounds were acacic acid lactone 3- O -β-D- xylopyranosyl-(1→2)-β-D-fucopyranosl (1→6)- 2-deoxy -2 -acetoamido -β-D- glucopyranoside ; acacic acid lactone 3- O-β-D-xylopyranosyl(1→2)-α-L- arabinopyranosl (1→6)- 2- deoxy - 2- acetoamido -β-D-glucopyranoside . The study lays chemical foundation and chemical reference substance for enhancing quality standard of Albizzia julibrissin Durazz.

本研究论文在综述国内外对合欢属Albizzia三萜皂苷化学成分和药理作用研究进展的基础上，利用传统植化分离手段和现代分离技术，包括大孔树脂、硅胶、葡聚糖凝胶、反相硅胶等柱色谱，制备高效液相色谱法等技术从中药合欢皮中分离得到了4个化合物，其中，2个新化合物和2个己知化合物，并进一步通过现代分析技术IR，ESI-MS，~1H-NMR，~(13C-NMR，HMBC，HMQC，~1H-~1HCOSY等和化学方法鉴定了2个新化合物的结构分别是：3-O-[β-D-吡喃木糖基(1→2)-β-D-吡喃夫糖基(1→6)-β-D-2-去氧-2-乙酰氨基吡喃葡萄糖基]-21-O-[(6S)-2-反式-2，6-二甲基-6-O-β-D-吡喃鸡纳糖基-2，7-辛二烯酸基]-金合欢酸-28-O-α-L-呋喃阿拉伯糖基(1→4)[β-D-吡喃葡萄糖基(1→3)]-α-L-吡喃鼠李糖基(1→2)-β-D-吡喃葡萄糖苷，金合欢酸3-O-β-D-吡喃葡萄糖基(1→3)-β-D-吡喃夫糖基(1→6)[β-D-吡喃木糖基(1→2)]-β-D-吡喃葡萄糖苷；2个已知化合物结构分别是：金和欢酸内酯3-O-β-D-吡喃木糖基(1→2)-β-D-吡喃夫糖基(1→6)-β-D-2-去氧-2-乙酰氨基吡喃葡萄糖苷，金和欢酸内酯3-O-β-D-吡喃木糖基(1→2)-α-L-吡喃阿拉伯糖基(1→6)-β-D-2-去氧-2-乙酰氨基吡喃葡萄糖苷。

Results showed that using aluminum trichloride combined catalyst under the conditions of a catalyst dosage of 5%, a benzene/olefin molar ratio of 8, a reaction temperature of 60℃ and a reaction time of 6 h, the yield of alky-benzene reached 19.6% and the quality of the obtained alkylate was significantly improved as compared with coker gas oil.

结果表明，采用三氯化铝复合催化剂，在催化剂质量分数为5%、反应温度60℃、苯烯摩尔比为8、反应时间6 h的条件下，烷基苯收率达到19.6％，烷基化油的质量明显优于焦化柴油。

When the mol quantity of Cu2+ dissolved was 5% of those of AlCl3 in ionic liquids, alkylation results from ionic liquids is comparable with those obtained with concentrated sulfur acid: the yield of alkylate reaching 178% of the volume of butene inputted, the selectivity of C8 reaching 75% and the octane number of alkylate reaching 92.2.

溶入Cu2+和Cu+后，离子液体的催化性能有显著的改善，当Cu2+的摩尔加入量为三氯化铝的5%时，烷基化油收率达到丁烯体积的178%，对C8的选择性为75%，烷基化油辛烷值为92.2，并且离子液体可以重复使用。

Among them,the main type of the constituents is alkylene, which amount to about 71% in Changium smyrnioides, and about 60% in Chuanminshen violaceum and Glehnia littoralis .

从三种植物中鉴定出21种挥发性成分，其中烯类精油是挥发油的主要成分，在明党参中约占71%左右，川明参及珊瑚菜中则约为60%左右。

A process for preparing alkylene glycols including reacting an alkylene oxide with water in the presence of a combination of additives and an anion exchange resin, wherein the combination of additives comprises carbon dioxide and an organic or inorganic base provided in an amount sufficient to maintain a pH of the reaction mixture between about 5.0 and 9.0, with the proviso that, when the base is bicarbonate or carbonate, then the anion exchange resin is a trimethyl benzyl ammonium anion exchange resin.

制备亚烷基二醇的方法，包括让烯化氧与水在添加剂组合和阴离子交换树脂存在下进行反应，其中添加剂组合包括二氧化碳和以足以保持反应混合物的pH值在约5.0和9.0之间的量提供的有机或无机碱，前提条件是当碱是碳酸氢盐或碳酸盐时，阴离子交换树脂是三甲基苄基铵阴离子交换树脂。

A desire to elucidate this reaction, and the analogous alkyne metathesis reaction, led to the discovery and development of high oxidation state complexes that contain a M=C or M C bond, so-called alkylidene and alkylidyne complexes, respectively.

为了阐述复分解反应，发现和发展了含有双键和三键的金属有机化合物，分别被称谓杂金属烯烃和杂金属炔烃。

For the reaction of propylene and benzene, acetone and phenol occurs, catalysts using aluminum chloride.

二为将丙烯与苯发生反应生成丙酮与苯酚，催化剂采用三氯化铝。

The coordinated COD of 3 and 4 can be replaced by carbon monoxide to yield the corresponding dicarbonyl species [(C,N-pyN^C-R) M2]BF4 (14, M= Rh; 15, M= Ir). Ligand substitution of 11a by phosphines and azide causes the de-complexation of pyridinyl-nitrogen donor to generate the corresponding carbene rhodium complexes [(C-pyN^C-Mes)RhPR3] (17a, R = Ph, 17b, R = Et) and [RhN3] (19), respectively, indicating the labile nature of steric-hindered pyridinyl-nitrogen donor.

螯合错合物的吡啶配位，可以容易被σ-予体，如卤离子、叠氮阴离子、膦试剂，置换；但是铑与铱金属螫合物与π-酸试剂，如一氧化碳、异腈，则发生COD被置的产物14a与16；与三甲基亚磷酸酯反应时，COD及吡啶均会被取代而得到单芽的三铑-碳烯错合物18；双膦化合物则会取代铑金属上全部的配位基。

Ethane＞ toluene＞1, 3, 5-trimethylbenzene＞methyl isobutyl ketone＞1, 4-Dioxane＞isoprene＞ 1, 2, 4-trimethylbenzene＞cyclohexane＞1, 3-Butadiene＞methyl butyl ketone were the most reactive VOC species in PRD.

化学活性排名前十位的化合物为：乙烯＞甲苯＞1，3，5-三甲苯＞甲基异丁基酮＞1，4-环氧乙烷＞异戊二烯＞1，2，4-三甲苯＞环己烷＞1，3-丁二烯＞甲基丁基酮。

Lugalbanda was a god and shepherd king of Uruk where he was worshipped for over a thousand years.

Lugalbanda 是神和被崇拜了一千年多 Uruk古埃及喜克索王朝国王。

I am coming just now,' and went on perfuming himself with Hunut, then he came and sat.

我来只是现在，'歼灭战perfuming自己与胡努特，那麼，他来到和SAT 。