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Studies on the reactions of isomerized products of butaduene and isoprene iron complexes with triphenyl phosphine and triphenyl phosphite

丁二烯-和异戊二烯二羰基铁配合物的异构化产物与三苯膦和亚磷酸三苯酯的反应研究

Using poly (4-merhylpentene-l) as a membrane material and cyclohexane, irich-loroethylene, tetrachloroethylene, mixture of cyclohexane and trichloroethylene or tetrachloro-ethylene as solvents, the solution were cast to form homogeneous dense membranes, and the crystalline properties and surface morphology were investigated by DSC and TEM.

以聚4-甲基戊烯-1为膜材质,分别以环己烷、三氯乙烯、四氯乙烯、环己烷/三氯乙烯及环己烷/四氯乙烯为溶剂,研究了这些溶液浇铸膜的结晶性质和表面形态。结果表明,溶剂对PMP的相对溶解能力和挥发速度同所成膜内PMP的结晶形式和结晶度密切相关;不同溶剂体系的PMP溶液浇铸膜的表面形态也不尽相同。

It was concluded that PG not only played an important role in trimer formation but also effected the pigments binding and the energy transfer within the LHCⅡ.

以上实验结果证明,PG及其反式十六碳一烯酸不仅在LHCⅡ三聚体的形成中具重要作用,而且还影响色素分子在LHCⅡ三聚体中的结合状态以及叶绿素b到叶绿素a的正常能量传递。

The results show that there is intensive synergistic effect among cetyltrimethylammonium bromide, benzalacetone and polyethylene glycol. A bright and compact nanocrystalline zinc was produced due to the coexistence of such three additives.

结果表明,十六烷基三甲基溴化铵、4-苯基-3-丁烯-2-酮和聚乙二醇三种添加剂之间具有较强的协同作用,采用三者组成的混合添加剂可制备出光亮致密的纳米晶锌镀层。

The biomarkers such as the n-Alkanes, the isoprenoids, the terpane, and cholestane were detected through GC-MS analysis. Based on the study of the biomarkers, the biological evolution during Permian and Triassic can be divided as three stages, namely, the mixing source stage of low biota such as thallose and advanced plant in late Permian (below bed 63), the stage of low biota such as thallose in the boundary transitional layer (bed 63-69) and the mixing source stage of advanced plant and low biota such as thallose in early Triassic (above bed 69). What's more, the second stage near the boundary transitional layer can be subdivided into 4 stages. The stages of biota evolution is close related with sedimentary environment changing and the boundary transitional layer.

利用GC—MS分析技术,在陆相地层中检测出正构烷烃、类异戊二烯烷烃、萜烷和甾烷类生物标志化合物并根据生物标志化合物和特征值研究,将二叠系—三叠系生物演化划分为三个大的阶段,即晚二叠世的菌藻类低等生物与高等植物混源阶段(63层以下),界线异常层的菌藻类低等生物阶段(63-69层)和早三叠世高等植物与菌藻类低等生物混源阶段(69层以上),界线附近异常层的第二阶段又进一步细分为4个次一级阶段,生物演化阶段与沉积环境变化及界线异常层具有非常密切关系。

The trifluoroethylester silane was synthesized by modifying a PEG diacid to form the corresponding bistrifluoroethylester, followed by a reaction with 3-aminopropyltriethoxysilane.

通过用PEG二酸修饰合成三氟乙基乙烯醚硅烷,由此形成相应的双丙烯酰胺三氟乙基乙烯醚,再将其与3-APS相互作用。

Starting with commercial available tosylmethyl isocyanide and but-2-enoic methyl ester, pyrrolo[2,1-f][1,2,4]triazine derivatives was prepared by twelve-steps process in total yiled of 5.0%~8% via pyrrole and pyrrolo [2,1-f] [1,2,4] triazine ring formation, substitution and amination reactions etc.

本文以简单的对甲基苯磺酰甲基乙腈和反-2-丁烯酸为原料,经过形成吡咯,吡咯并[2,1-f][1,2,4] 三嗪环,取代,酰胺化等等12步反应,合成了结构新颖的吡咯并[2,1-f][1,2,4] 三嗪衍生物,总收率达5%~8%。

In chapter four, molecular imprinting polymers against amino acid derivatives utilizing 2-VP+AM as combined functional monomer and trimethylolpropane trimethacrylate as tribasic cross-linker were prepared and result was compared with those with the same amino acid derivative as the imprinted molecules utilizing ethyleneglycol dimethacrylate as dibasic cross-linker. It was found that cross-link intensity of the molecular imprinting polymer is higher when TRIM was utilized and baseline separation for the imprinted molecule could be achieved. When TRIM was utilized as cross-linker more molecule is imprinted during the polymerization.

第四章采用2-乙烯基吡啶+丙烯酰胺复合功能单体,考察了三元交联剂三甲氧基丙烷三甲基丙烯酸酯烙印氨基酸衍生物的情况,并与二元交联剂乙二醇二甲基丙烯酸酯烙印相同氨基酸衍生物的情况进行了对比,发现三甲氧基丙烷三甲基丙烯酸酯交联剂在较小的用量下就可使分子烙印聚合物达到足够的交联度,实现烙印分子的基线分离。

Water-soluble air drying alkyd resin is formulated by flax oil acid,trimethylol propane,dimethyl isophthalate,benzoic acid,maleic anhydride and trimellitic anhydride.

以亚麻油酸、三羟甲基丙烷、间苯二甲酸、苯甲酸、顺丁烯二酸酐、偏苯三酸酐为原料合成水溶性醇酸树脂,中和后制得的涂料具有干性好、硬度高、耐水性和贮存稳定性优良等特性。

Hydroesterification of tert-butyl alcohol with ethanol catalyzed by transition metal triphenylphosphine complexes were investigated in room temperature ionic liquids as reaction medium at 100-140℃ and 3-6MPa of CO.

首次在超强酸氯铝酸离子液体中实现了饱和烷烃的羰化反应。发现2,2,4-三甲基戊烷可直接与CO反应,产物叔丁基异丁基酮,叔丁基异丁烯基酮和3,3,5-三甲基环己酮。

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