三烯

Three chiral phosphorus ligands were prepared using anisole as the startingat material.Their applications in the asymmetric hydroformylation and asymmetric conjug ed addition of diethylzinc to enones were investigated.

以苯甲醚为原料，合成了三种新的手性含磷配体，考察了三种配体在不对称氢甲酰化反应和ZnEt2对环己烯酮的不对称共轭加成反应中的应用。

To develop an eco-friendly epoxy impregnating resin system for groundwall insulation of large generators, the curing reaction mechanism has been fully studied, the formulation and the curing techniques have been optimized, and the influence of different constitution on the curing reaction, microstructure, and final performances have been studied and characterized.In this paper, influences of different reactive organo-siloxanes on the curing reaction and performances of epoxy V.P.I.

本文研究比较了含有环氧基、氨基或乙烯基的反应性硅氧烷，包括：γ-缩水甘油醚氧丙基甲基二乙氧基硅烷、β-(3，4环氧环已基)乙基三乙氧基硅烷、γ-缩水甘油醚氧丙基三甲氧基硅、β-(3，4环氧环已基)乙基三甲氧基硅烷、γ-甲基丙烯酰氧基丙基三甲氧基硅烷、乙烯基三乙氧基硅烷和苯胺甲基三乙氧基硅烷对环氧V.P.I。

These salts can beprepared on treatment of phosphinimines with trifluoroaceticanhydride. After addition-elimination, triflromethylated β-enaminoesters and β-iminoesters were synthesized by thereaction of the above salts with organozinc reagents.

通过膦亚胺和三氟乙酸酐反应制备了N-三氟乙酰基氨基膦盐，该膦盐和锌试剂发生加成-消除反应后，合成了含有三氟甲基的β-烯胺酯和β-亚胺酯。

This paper reports the experimental equipment and technology parameter for the synthesis of diisopropylbenzene and triisopropylbenzene by catalytic alkylation between benzene and propene, the conversion of benzene is more than 98%,the selectivity of diisopropylbenzene and triisopropylbenzene is more than 40% and 36% respectively.

报道了苯与丙烯催化烷基化合成二异丙苯和三异丙苯的实验装置与工艺条件，苯的转化率达98%以上，二异丙苯的选择性≥40%，三异丙苯的选择性≥36%，经分离后可获得纯度≥95%的二异丙苯和三异丙苯产品，所提供的合成工艺基本上无污染，在国内外具有先进的技术。

Ambient temperature self-crosslinking acrylic latexes were prepared through semicontinuous emulsion polymerization using 3 different polymerizable alkoxysilanes, i.e. vinyl tri silane (A172), Vinyl triethoxy silane and γ-methacryloxypropyl trimethoxy silane (A174). The hydrolysis of these siloxanes under different pH was characterized, and dependence of the latex and polymer properties on these siloxanes and their incorporated amounts in the polymers was studied.

使用三种含不饱和双键硅氧烷，乙烯基三硅烷(A172)、乙烯基三乙氧基硅烷和γ-甲基丙烯酰氧丙基三甲氧基硅烷(A174)为功能单体，采用半连续乳液聚合法制备了室温自交联丙烯酸酯乳液，探讨了硅氧烷功能单体在不同pH条件下水解情况以及其种类和用量对乳液及乳胶膜性能的影响。

In addition, we found that 4-phenyl-l,2,4-triazolinium N-ylides reacted withvarious electron-deficient olefins to afford pyrrole derivatives in good yields via 1,3-dipolar cycloaddition oxidative ring fission, In some cases, tetrahydropyrrolo[1,2-b]triazole and pyrrolo[1,2-b]triazole, which are stable and are not aromatized orcleaved in the reaction conditions, could be isolated, This is a facile and novel route forthe synthesis of pyrrole derivatives.

此外，本文研究了五员三氮杂环化合物4-苯基1，2，4-三氮唑的N-叶立德，发现在氧化剂存在下与缺电子烯烃发生1，3-偶极环加成反应生成的吡咯并[1，2-b]三氮唑，在大多数情况下开环生成吡咯衍生物，反应条件温和，收率良好，是合成吡咯衍生物的一个新的途径。

We are interesting in the synthesis and the application of 1,2,3-triazoles inthis paper, which including the following:In the first chapter, we reviewed mainly the development of Huisgen\'s 1,3-dipolar[3+2]-cycloaddition from organoazides and alkynes or alkenes to synthize1,2,3-triazoles in recent years.

本论文针对1，2，3-三唑的合成和应用，主要包括以下方面：第一章对近几年来1，2，3-三唑合成研究进行了概述，总结了有机叠氮和炔烃、烯烃的1，3-偶极环加成反应以及其他方法合成三唑的进展。

The invention relates to a surface chemistry modified latex which can be obtained by carrying out radical polymerization in emulsion in the presence of at least one ethylenically unsaturated monomer or at least one polymer having ethylinically unsaturated residual bonds, at least one radical polymerization, at least one single, double or triple block polymer which is soluble or dispersible in water, comprising an active group at the end thereof, capable of forming a radical, and chosen from dithioesters, xanthates, thioether-thiones and dithiocarbamates.

本发明涉及具有改良表面化学性质的胶乳，它可以通过在以下物质的存在下进行自由基乳液聚合来获得：至少一种烯属不饱和单体或至少一种含残留烯属不饱和键的聚合物，至少一种自由基聚合引发剂，至少一种水溶性和/或水可分散的单嵌段、二嵌段或三嵌段聚合物，在其端部包括选自二硫酯，硫醚-硫酮，二硫代氨基甲酸酯和黄原酸酯中的能够形成自由基的活性基团。

Then, it was condensed with-valine methyl ester to form a chiral imine, which was reacted with allyl zinc bromide in the presence of CeCl3·7H2O to afford the corresponding chiral homoallylic amine with high optical activity.

-N-Boc-3-苯基-2-氨基丙醛与-缬氨基酸甲酯缩合生成手性亚胺，在七水合三氯化铈（CeC13·7H2O）催化以及底物的手性诱导作用下，该手性亚胺与烯丙基溴化锌经不对称加成反应合成了高光活性的单烯丙基化手性胺。

Feeding for 24h by third instar larvae of the maize stalk borer induced farnesyl pyrophosphate synthase gene expressing, but had no effect on expression of AOC, BX9, PAL and PR2a genes and DIMBOA content.

3玉米螟3龄幼虫处理24h能诱导玉米根中法呢烯基焦磷酸合成酶基因表达，但不能诱导丙二烯氧化物环化酶、β－1，3葡聚糖酶基因（PR2a）、糖基转移酶（BX9）、苯丙氨酸转氨酶基因表达，同时对第二叶和根中丁布含量无显著影响，使第二叶对羟基苯甲酸及第三叶丁布、对羟基苯甲酸、香草酸含量显著降低。

This one mode pays close attention to network credence foundation of the businessman very much.

这一模式非常关注商人的网络信用基础。

Cell morphology of bacterial ghost of Pasteurella multocida was observed by scanning electron microscopy and inactivation ratio was estimated by CFU analysi.

扫描电镜观察多杀性巴氏杆菌细菌幽灵和菌落形成单位评价遗传灭活率。