三氯硅烷

Base on analysis on production and development of silane coupling agent and polysilicon in China . it is forecast that by 2010 the market demand on trichlorosilane in China will reach above 300,000t, by then , silane coupling agent and polysilicon may go halves on the market of trichlorosilane By 2015 , the demand on trichlorosilane will amount to more than 80,000t .

根据对我国硅烷偶联剂及多晶硅生产发展的分析，预训2010 年，我国二氯氢硅的市场需求量应达到30万t 以上，届时，硅烷偶联剂和多晶硅有可能平分三氯氢硅的市场。2015 年，我国三氯氢硅的需求量应达到8 万t 以上。

Synthesis of mesitylene by catalytic alkylation of mixed C9 arenes and isobutene

可由三甲基氯硅烷与无水烯丙醇反应来制取。

A very mild and extremely efficient hydrolysis method for transformation of polystyrene-b-poly (tert-butyl acrylate) to polystyrene-b-poly was designed and carried out using more convenient and inexpensive chlorotrimethylsilane/sodium iodide as reagents.

在温和的条件下使用廉价方便的三甲基硅氯烷/碘化钠作试剂，在乙腈溶剂中，50℃下使聚苯乙烯-嵌-聚丙烯酸特丁酯高效的水解。用透射电镜和动态光散射对嵌段共聚物聚苯乙烯-b-聚丙烯酸在水介质中的胶束化进行了研究。

Part three, preparation of colloidal gold. Wash the terrarium with the chloroform solution of 5% Dime thyldichlorichlorosilame, then we can make the colloidal gold.

第三部分胶体金的制备将所需容器按要求用5%的二氯二钾硅烷的氯仿溶液清洗后进行胶体金的制备。

The crosslinked PEG-20M glass capillary column was prepared by dynamic coating method with boron trifluoride as catalyst,3-glvcidyl-oxypropyl-trimethoxysilane as crosslinking agent.

以PEG－20M为固定相，三氟化硼为催化剂，3－缩甘油氧丙基三甲氧基硅烷（简称KH－560）为交联剂，二氯甲烷为溶剂，对预先用氯化钠沉积法粗糙化的玻璃毛细管柱进行动态涂渍。

In order to check the corresponding compound at 31P NMR –45.4 ppm, stable pentacoordinate spirobicyclic 2-phenoxy-1,3-phenylene-dioxo-1,3,2-iminoacetoxyphosphoranes were synthesized through a new and efficient method whereby phosphorus pentachloride was displaced stepwise by catechol, N,O-bisamino acid and phenol, or catechol, phenol and N,O-bisamino acid, their 31P NMR chemical shifts are at about 31P NMR –45.0 ppm, the results showed that the compound 4 at 31P NMR –45.4 ppm was pentacoordinate phosphorane containing amino acid residue.

采用磷谱跟踪来研究上述成肽反应机理。例如在氮气保护下，0.1mmol O，O-亚苯基磷酰氯（1）和0.15mmol N，O-二苯丙氨酸（2）苯溶液加入0.6ml核磁管中，混合均匀，反应过程用磷谱检测。反应1分钟后，起始原料1(δp=19ppm)很快转变成N-磷酰苯丙氨酸的三甲基硅基酯（3）(δp=19.8ppm)，在8分钟内，3完全转变成苯丙氨酸磷烷4(δp =-45.4ppm)，同时出现环磷三酯（6）(δp=3.5ppm)。随着反应的进行，对应于化合物4的峰逐渐变小，而6逐渐变大。

A reduction-coupling-etherification reaction between aromatic aldehydes or ketones (1) and alcohols ( 2 ) to yield corresponding diether ( 3 ) of pinacol in the presence of tin and chlorotrimethylsilane.

在三甲基氯硅烷、四氢呋喃体系中，芳香醛、酮和醇在金属锡的作用下发生还原-偶联-醚化反应生成相应的频那醇二醚类化合物。

Methods for synthesizing of pinacol are reviewed,the difference of catalytic effects and stereoselectivity with various catalytic systems are introduced in this paper.Highlights are laid on the mechanism and stereoselectivity of new synthetic methods catalyzed by low valent Samarium, Titanium and Trimethyl chlorosilane, etc.

频哪醇合成新进展* The Recent Progress in the Synthesis of Pinacol 李有桂蒋昌盛尤田耙**(中国科学技术大学化学系合肥 230026)本文综述了合成频哪醇的方法，介绍了不同催化体系的催化效果和立体选择性的差异，着重介绍了低价钐、低价钛、三甲基氯硅烷等新的合成频哪醇反应的机理和立体选择性。

This thesis studied three different kinds of hydrolytic condensation methods of Me_3SiCl and MeSiHCl_2: co-hydrolytic condensation reaction, step-by-step hydrolytic condensation reaction and reversive hydrolytic condensation reaction, and analysized the hydrolytic condensation mechanism of chlorosilane.

论文研究了Me_3SiCl和MeSiHCl_2的三种不同的水解缩合方法：共水解缩合法、分步水解缩合法及逆水解缩合法，并对氯硅烷的水解缩合机理进行分析。

The product qualities,safety,transportation,storage,useful deposition ratios,deposition rates,one pass conversions,deposition temperatures,electrical energy consumption and manufacturing costs are summarized for silane,dichlorosilane,trichlorosilane and tetrachloro silane method s.

对三氯氢硅法、四氯化硅法、二氯二氢硅法和硅烷法生产的多晶硅质量、安全性、运输和存贮的可行性、有用沉积比、沉积速率、一次转换率、生长温度、电耗和价格进行了对比；对还原或热分解使用的反应器即钟罩式反应器、流床反应器和自由空间反应器也进行了比较。

What would he tell Judith and the children?

他将怎样告诉朱迪丝和孩子们呢？

I this is at that time, the opinion with peacockish true girl is full of in a heart.

这就是当时的我，一个心中布满虚荣的女孩子真实的想法。