三氯硅烷

The alcoholysis of trichlorosilane has been studied experimentally and theoretically,each step is cooperating endothermic process.

采用溶剂法和B3LYP/6-31G基组研究了三氯硅烷的乙醇解反应，计算得出每一步醇解均为放热反应，并得出了反应的最佳温度、最佳进样方式、主反应和副反应的活化能及其可能的反应途径曲线。计算结果和实验结果有较好的一致性

Progress on preparation and purification of trichlorosilane ;2. Study on synthesis of trifluoropropyl trichlorosilane ;3. The alcoholysis of trichlorosilane has been studied experimentally and theoretically,each step is cooperating endothermic process.

采用溶剂法和B3LYP/6-31G基组研究了三氯硅烷的乙醇解反应，计算得出每一步醇解均为放热反应，并得出了反应的最佳温度、最佳进样方式、主反应和副反应的活化能及其可能的反应途径曲线。

While all the phenyl groups in tetraphenylphenyl groups or benzophenanthrene groups are not coplanar. At the same time, by density function theory, the electronic energy gap between HOMO and LUMO frontier molecular orbitals of condensed aromatics are calculated and the Eg of acenaphthenyl groups in C_2 gum is the smallest, which explains the reason why C_2 gum has the best radiation protection effects.

利用甲基三氯硅烷和溴苯的格氏反应合成了甲基苯基二氯硅烷，用核磁分析证实了格氏反应中高沸点副产物为甲基二苯基氯硅烷；通过甲基苯基二氯硅烷和二甲基二氯硅烷的共水解，再裂解而制得含Me_2SiO链节的甲基苯基环硅氧烷混合物，进而利用碱胶开环聚合得到甲基苯基硅橡胶生胶；也可通过甲基苯基二氯硅烷水解所得甲基苯基环硅氧烷D_3~(3Ph、D_4~(4Ph_)与D_4开环聚合制得甲基苯基硅橡胶生胶。

Chiral compounds Ⅰ for the first time was applied to allylation of acylhydrazones with allyltrichlorosilane and the results showed that the compound Ⅰ can contribute to the occurrence of the reaction.

首次将手性化合物Ⅰ应用于烯丙基三氯硅烷和酰腙的烯丙基化加成反应中，结果表明化合物Ⅰ能够促进该反应的发生。

Project Introduction: Trichlorosilane, also named Silicochloroform ,is mainly used in the synthesis of organic silicone, alkyl, aryl and organic functional group chlorosilane. It's the most basic monomer of the organic silane coupling agent,and the production material for semiconductor silicon and silicon; Manufacturing process of the tetrachlorosilane includes the reciprocal effect by the trichlorosilane steam and the hydric steam which has been heated up to 1700-2500SiCK by the plasma accelerator; the steam compound in the reactor goes into the condensing system that separates trichlorosilane. After that, polycrystalline silicon can be made.

三、项目概况：三氯氢硅：又名三氯硅烷、硅氯仿，主要用于有机硅烷和烷基、芳基以及有机官能团氯硅烷的合成，是有机硅烷偶联剂中最基本的单体，也是生产半导体硅、单晶硅的原料；四氯氢硅工艺包括在等离子加速器内加热到1700-2500SiCK的氢气流和四氯氢硅的蒸汽相互作用，在反应器内形成的蒸汽气体混合物进入分离三氯氢硅的冷凝系统，下步可制取多晶硅。

Methyltrichlorosilicane and phenyltrichlorosilicane are applied for the synthesization of the ladderlike polymethylsilsesquioxane and ladderlike polyphenylsilsesquioxane.

选用甲基三氯硅烷和苯基三氯硅烷为主要原料合成了梯形聚甲基倍半硅氧烷和梯形聚苯基倍半硅氧烷。

Finally the application of the homemade ODS for MSPD and the economical availability of the product was evaluated. Results show as the following: 1. It is a simple method for the preparation of a bonded octadecyl phase which has large particle and high extent of coverage of the bonded phase.

研究结果表明：①采用大粒径无定形硅胶为基质，选择十八烷基三氯硅烷为硅烷化试剂，完整地合成了一种大颗粒、高表面积的ODS键合相，合成的ODS可作为基质固相分散MSPD的固相分散剂，用于样品的前处理。

The mechanism of redistribution of trichloromethyl and chlorotrimethyl silane catalyzed by ZnCl2 has been obtained by calculation.

通过计算，得出了ZnCl2催化的一甲基三氯硅烷和三甲基氯硅烷歧化反应的机理，得出了IRC曲线和过渡态的虚振动模式。

The manufacturing method was a batch reaction of Trichlorosilane or Silicon Tetrachloride in a molten Lithium Aluminum Hydride salt bath

当时的制造方法批次法，是将三氯硅烷或四氯化硅放在熔化的氢化铝锂盐浴中进行反应。

Polymer-based thin film transistors with poly(3-hexylthiophene)(P3HT) as semiconducting active layers were successfully fabricated on silicon substrates in air which was used as gate electrode, HfTiO film deposited by RF sputtering method was used as gate insulators, and gold metal was used as source and drain electrodes. The HfTiO surface was modified by using octadecyltrichlorosilane solution during fabrication process.

以高掺杂Si单晶片作为衬底且充当栅电极，采用磁控溅射法在硅片上沉积HfTiO薄膜作为栅介质层，聚三己基噻吩(P3HT)薄膜作为半导体活性层，金属Au作为源、漏电极，并采用十八烷基三氯硅烷对栅介质层表面修饰，在空气环境下成功地制备出聚合物薄膜晶体管。

What would he tell Judith and the children?

他将怎样告诉朱迪丝和孩子们呢？

I this is at that time, the opinion with peacockish true girl is full of in a heart.

这就是当时的我，一个心中布满虚荣的女孩子真实的想法。