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三氯氢硅

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Base on analysis on production and development of silane coupling agent and polysilicon in China . it is forecast that by 2010 the market demand on trichlorosilane in China will reach above 300,000t, by then , silane coupling agent and polysilicon may go halves on the market of trichlorosilane By 2015 , the demand on trichlorosilane will amount to more than 80,000t .

根据对我国硅烷偶联剂及多晶硅生产发展的分析,预训2010 年,我国二氯氢硅的市场需求量应达到30万t 以上,届时,硅烷偶联剂和多晶硅有可能平分三氯氢硅的市场。2015 年,我国三氯氢硅的需求量应达到8 万t 以上。

Jintai Polyvlnyl Chloride Plant for 100,000t of Chlor – alkali in Mizhi County can produce 14,000t of liquid chlorine yearly ,i.e .daily average output of 35 - 40t , thus can fully satisfy the needs of annual output 5,000t of trichlorosilane .

我县金泰氯碱10万吨聚氯乙烯厂,年产液氯1.4万吨,日均产3540吨,完全可满足年产5000吨三氯氢硅的原料需求。

Project Introduction: Trichlorosilane, also named Silicochloroform ,is mainly used in the synthesis of organic silicone, alkyl, aryl and organic functional group chlorosilane. It's the most basic monomer of the organic silane coupling agent,and the production material for semiconductor silicon and silicon; Manufacturing process of the tetrachlorosilane includes the reciprocal effect by the trichlorosilane steam and the hydric steam which has been heated up to 1700-2500SiCK by the plasma accelerator; the steam compound in the reactor goes into the condensing system that separates trichlorosilane. After that, polycrystalline silicon can be made.

三、项目概况:三氯氢硅:又名三氯硅烷、硅氯仿,主要用于有机硅烷和烷基、芳基以及有机官能团氯硅烷的合成,是有机硅烷偶联剂中最基本的单体,也是生产半导体硅、单晶硅的原料;四氯氢硅工艺包括在等离子加速器内加热到1700-2500SiCK的氢气流和四氯氢硅的蒸汽相互作用,在反应器内形成的蒸汽气体混合物进入分离三氯氢硅的冷凝系统,下步可制取多晶硅。

Trichlorosilane is the raw materials for making organosilicon compounds , and also the basic materials for making polysilicon .

三氯氢硅是制造有机价化合物的原料,也是生产多晶硅的基本原料。

Starting from chiral proline, pipecolinic acid, piperazine-2-carboxylic acid and 1,2-diphenyl amino alcohol, a series of structurally simple and easily prepared amides were developed as highly effective Lewis basic organocatalysts for the asymmetric reduction of imines with trichlorosilane as the reducing agent, which promoted the reduction of N-aryl imines with high yields and excellent enantioselectivities with an unprecedented substrate spectrum.

本文分别由手性脯氨酸、哌啶酸、哌嗪酸以及氨基醇出发,设计和合成了一系列结构新颖、合成简便、性能优良的酰胺类有机小分子路易斯碱催化剂,以廉价的三氯氢硅为氢源,用这些催化剂催化亚胺不对称还原,得到了非常优良的收率、对映选择性和前所未有的底物普适性。

The product qualities,safety,transportation,storage,useful deposition ratios,deposition rates,one pass conversions,deposition temperatures,electrical energy consumption and manufacturing costs are summarized for silane,dichlorosilane,trichlorosilane and tetrachloro silane method s.

三氯氢硅法、四氯化硅法、二氯二氢硅法和硅烷法生产的多晶硅质量、安全性、运输和存贮的可行性、有用沉积比、沉积速率、一次转换率、生长温度、电耗和价格进行了对比;对还原或热分解使用的反应器即钟罩式反应器、流床反应器和自由空间反应器也进行了比较。

The annual production capacity of trichlorosilane is 60 thousand tons and the annual production capacity of silicon tetrachloride is 12 thousand tons.

公司年产6万吨三氯氢硅,1.2万吨四氯化硅的规模,三孚硅业为国内最大的三氯氢硅生产基地。

It is a private joint-stock enterprise of pruducing trichlorosilane, silicon tetrachloride, potassium hydroxide.

唐山三孚硅业有限公司成立于2006,是一家以生产三氯氢硅,四氯化硅,氢氧化钾为主的民营股份制企业。

The project is designed to produce 100,000t/a of production appliance and byproduce silicon tetrachloride and hydrogen .

生产规模为100000t/a的生产装置,副产四氯化硅和氢气,每生产1t 三氯氢硅可副产四氯化硅约220kg 、氢气约21ONm3 ,建设工期1年。

After dryness, silica powder is put into chlorinated furnace in fluid bed and reacts with dried hydrogen chloride gas in the environment of 340℃ to form crude trichlorosilane. The crude trichlorosilane , through hydroscrubber and pipe bundle condenser to extract silicon tetrachloride in distillation column produces trichlorosilane gas out of the d istillation column , which can be made into the finished product of trichlorosilane by condensation .

硅粉经干燥后加入氯化沸腾炉,与通入炉中的干燥氯化氢气体在340o C进行反应,生成的粗三氯氢硅经湿法除尘器、列管冷凝器去蒸馏塔分离匹氯化硅,由蒸馏塔出来的三氯氢硅气体经冷凝,制得三氯氢硅成品。

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