三晶的

Firstly, we studied the effects of synthetic temperatures on AgSbPb18Te20 samples in specific pressure. The XRD results indicate that AgSbPb18Te20 can be synthesized at more than and equal to 1120℃ and synthesized AgSbPb18Te20 samples are belong to cubic system.

结合指标化程序给出的晶格参数和我们实验测定的密度，我们认为我们所合成的样品是固溶体，然后又对样品三的原始XRD谱，利用Material Studio中的Reflex模块中的Reflex Solve对其进行了结构求解，得到其最好的结构为符合空间群为FM-3M的结构（如图4.9）。

The effects, such as the acidity of leaching system, the temperature and the concentration of the sodium chloride, on oxidation and leaching of copper-bearing gold ores were analyzed. The results show that the sequence of sulfide ores oxidized and dissolved are pyrrhotite firstly, sulphide secondly, then chalcopyrite, pyrite lastly.

结果表明：硫化矿的氧化溶解首先是磁黄铁矿，其次是铜的次生硫化矿，再次是黄铜矿，最后是黄铁矿；载金黄铜矿的氧化首先是铁从黄铜矿的晶格中氧化溶解出来，生成中间产物CuS2和CuS；较高的酸度和氯化钠浓度有利于单质硫的生成、三价铁的水解和铜的浸出，进而有利于金浸出率的提高。

Then follow the saints: Peter, prince of the Apostles, vice-regent of Christ; Paul, the Apostle of the Gentiles; Andrew, who first heeded the call of the Master; James the Greater and John the Evangelist, the beloved disciple, who, with St. Peter, were most favoured by Christ; Thomas, called Didymus, who received from Christ signal proofs of His Resurrection; James the Less, first Bishop of Jerusalem; Philip; Bartholomew; Matthew, once called Levi, the toll-gatherer, who wrote the First Gospel; Simon the Zealot; Jude Thaddeus; Matthias, who was chosen to fill the place of Judas Iscariot; Barnabas, called to the Apostolate by the Holy Ghost (Acts 13:2); Luke, the physician, writer of the Third Gospel and the Acts; Mark, the Evangelist, disciple of St. Peter; all the Apostles and Evangelists; the holy disciples of the Lord; the Holy Innocents, the infant martyr-flowers,"Who, slain at the command of Herod, confessed the name of the Lord not by speaking but by dying" Rom. Brev.

然后按照圣人：黄匡源，王子使徒，副丽晶基督；保罗，使徒的外邦人；黄宏发，谁第一个响应号召的主人；詹姆斯更大和约翰福音，心爱的弟子，谁，与圣彼得大教堂，最喜欢的基督；托马斯，所谓didymus ，谁收到了基督的信号证明他的复活；詹姆斯少，首先主教在耶路撒冷；弘；巴尔多禄茂；马修，一旦所谓的Levi ，不收费的采集，谁写的第一福音；西蒙该zealot ；裘德项；马提亚，谁被选为以填补地方犹大iscariot ；巴拿巴，所谓向使徒由圣灵（使徒13时02分）；卢克，医生，作家对第三个福音和行为；马克，传道，门徒圣彼得；所有使徒和福音；圣地的门徒主；圣地无辜的，婴儿的烈士-鲜花，"谁，杀害在指挥希律，坦白的名称，主没有发言，而是由死"。

The novel complex (1) in which both benzylic nitrogens and heteroaromatic ones to the same metal ion with the rigid ligand imposed by the large heteroaromatic moiety first time was synthesized; a 2: 1 (ligand: metal ions) type complex which has steric resistance and strong thermochemical driving force was obtained. The crystal structures of characteristic ligand (LA4) and complexes (4, 7, 10), in which one cell includes two moieties: there exist minute difference in coordinated bonds and angles despite the same metal ions with the same ligand, were obtained. It shows that several stable conformation in one complex cell.

首次合成了含邻菲罗啉的具有较大刚性的四氮配体中四个氮原子全部与同一金属离子配位的配合物的晶体结构；得到了一个在空间上存在位阻作用的配体与金属离子2：1结构的晶体；解析了具有特色的一个配体（LA4）和三个配合物（4、7和10）的晶体结构，其中的配体与金属离子的配位作用显示出细微的差异，表明在同一金属配合物的晶胞中，可以同时存在着多个稳定的构象。

The results show that the technical parameters and the concentration of sodium molybdate have obvious effect on the composition of the alloy. The crystal grain size is from 6.2 to 12.7 nm and changes with current density, temperature and the pH value of the electrolyte.The crystalline growth of the alloy accords with the model of three-dimensional growth. The surface morphology is mainly determined by the rate competitions between the growing direction of vertical surface and the expanding direction along the surface towards circumambient. The results of the X-ray data show the presence of the multiphase containing solid solution and intermetallic compound in the deposits. The deposit phases alter from the FeNi and FeMo solid solution to the FeNi and MoNi4structure at 3 A/dm2. The deposits internal stress increases linearly with the decrease of the grain size. The lattice parameter of the deposits are slightly distorted

结果表明：工艺条件和钼酸钠浓度对合金组成的影响较大；所得合金晶粒尺寸为6.2~12.7 nm，并随电流密度、温度和电镀液的pH值的改变而变化；合金的晶体生长符合晶核三维生长模型，镀层表面形貌由平行和垂直于基体的生长速度的相对大小决定；镀层物相为固溶体和金属间化合物的多相结构，当电流密度为3 A/dm2时，镀层物相由FeNi和FeMo固溶相转化为FeNi和

In the passivated REBAR electrode surface formed by ORCs the grain observed from AFM examination is composed of γ-Fe〓O〓 and Fe〓O〓 0 At+0.7V, the passive film on REBAR electrode formed by single-step polarization is composed of Fe (Ⅲ oxide highly doped by Fe〓. In some areas, small γ-Fe〓O〓 particals or some polymeric structure which contains dioxy and dihydroxy bridging bonds between the iron atoms may also exist in the other region.

通过AFM实验观察到的钢筋电极经循环电位扫描至+0.7V形成的钝化膜中具有的结晶颗粒主要由γ-Fe〓O〓和Fe〓O〓·yH〓O0 阶跃电位形成的钢筋钝化膜在+0.7V下主要是由掺杂了大量Fe〓的三价铁氧化物构成，在某些微小的区域可能存在γ-Fe〓O〓微晶，而在另外一些区域则具有聚合物膜的结构。

In this thesis, a series of complexes based on aromatic multicarboxylic acids have been successfully synthesized in solutions or under hydrothermal conditions. Their structure and properties are investigated.(1) Eight complex compounds have been synthesized and characterized by X-ray single crystal diffractive technology: The eight complexes are listed as following: [Cu242] complex 1 [Cd22(H2O)4]·4H2O complex 2 [Co(H2btc)(H2O)3] complex 3 [Co2(H2O)2]·H2O complex 4 [Ni22(H2O)4] complex 5 [Cu22(H2O)4] complex 6 [Co(H2biim)2(H2O)2](H2btc) complex 7 [Zn(H2biim)2(H2O)2](H2btc) complex 8 The structure of complex 1 is dinuclear complex resulted from weak interactions（0-D chain）; complex 2 is 1-D chain stucture result from interactions of water molecules; complex 3、4、5、6 are coordination polymers using hydrothermal synthses, where the first kind ligand is H4btc, the second kind ligand is phen and Co2+、Ni2+、Cu2+ as center ions, respectively. While the coordination enviroment of Co2+ is the same in complex 3, the coordination geometries around the Co atoms in complex 4 are obviously different because of the different reaction conditions. In complex 4, the 1-D chains are connected into 2-D layer through carboxy groups of ligand H4btc. The structures of complex 5、6 are 1-D chain stucture result from interactions of carboxy groups in ligand H4btc. Complex 7、8 are homeomorphy compounds. Either of them are linked to the 3-D chains through intermolecular hydrogen bonds. Each H4btc lose two protons and H2btc2- acts as negative electron balance.

合成了8个结构新颖的配合物，并用X-射线单晶结构分析方法确定了晶体结构，分别为： [Cu242] 配合物1 [Cd22(H2O)4]·4H2O 配合物2 [Co(H2btc)(H2O)3] 配合物3 [Co2(H2O)2]·H2O 配合物4 [Ni22(H2O)4] 配合物5 [Cu22(H2O)4] 配合物6 [Co(H2biim)2(H2O)2](H2btc)配合物7 [Zn(H2biim)2(H2O)2](H2btc)配合物8 配合物1是一个依靠弱作用连接的双核铜结构；配合物2借助水分子形成一维链状结构；配合物3、4、5、6是以H4btc为第一配体、phen为第二配体，通过水热法合成的配合物，其中，Co2+、Ni2+、Cu2+为中心离子；配合物3中的二价钴离子具有相同的配位环境，不同反应条件下得到的配合物4中的二价钴离子存在不同的配位环境，在配合物4中，一维链通过H4btc上的羧基形成一个二维层结构；配合物5、6是借助H4btc上的羧基形成的一维链状结构；配合物7、8属于异质同晶结构，它们的分子通过分子间氢键形成三维网状结构，H4btc上的羧基失去2个质子，作为一个二价负离子起到电荷平衡作用。

The performace of material was tested by DSC,XRD,SEM,EIS and charge-discharge cycles . The influences of various synthesized condition , sintering time and the amount of F were studied and correlative technics parameter to improve performance of material were optimized. DSC shows that three endotherimc peaks and one large exothermic peak are observed in the temperature range 150-400℃, which is because of the removal of water,the decomposition of the organic constituents and the formation of spinel. Only the citrate precursor is sintered at least 450℃, the crystallinity of spinel phase could be formed intactly.

通过DSC、XRD、SEM、EIS和充放电循环等手段对材料进行性能测试，比较了不同合成温度、烧结时间和不同掺杂元素量等条件对材料性能的影响，优选出提高材料性能的相关工艺参数， DSC表明，采用溶胶-凝胶-络合法制备的前驱体在150-400℃中有三个小的吸热峰和一个大的放热峰，这是前驱体中的水分、柠酸酸及其盐和醋酸及其盐在蒸发及分解，柠檬酸前驱体至少需在450℃以上才可能形成完整的尖晶石材料。

Photonic quantum-well structures can be constructed by stacking 3 photonic crystals with the same photonic band gap and different defect modes. On condition that the defect mode of the PC in the well region is located into nontransmission frequency ranges of the PCs in the barrier regions, the confined photonic state appears and can completely transmit through the structure by tunneling. However, its transmission will be strongly prohibited due to vanishing of the photonic QW induced by shifting the defect mode frequency of either of the PCs in the surrounded regions to that of the middle PC.

把三块各带有一个缺陷的光子晶体结合起来，如果中央晶体的缺陷模处在两侧晶体的禁带中，缺陷模内的光波会受到两侧晶体的阻碍并被局域在中央晶体内，形成量子阱结构；若一侧晶体的缺陷模被移动到中央晶体缺陷模处，则只有一侧晶体阻碍在中央晶体缺陷模内传播的光波，量子阱效应完全消失，光的传输受到最大程度的阻碍。

Through cyclic hydrogen bonding with motif formed by coordinated water molecules and coordinated hydroxyl groups of dhbd from adjacent tetranuclear units, these adjacent neighbors are connected to afford a 1D supramolecular chain along axis a, which is further extended via aromatic intercalations and other crystallization water molecules into a 3D structure with channels.

毗邻的四核单元通过配位H2O分子和配位羟基O原子形成的 R 22(8)型环形氢键桥的连接，沿a轴方向构建了四核单元交替相连的一维超分子链；链间籍苯环的π-π堆积作用和晶格水分子氢键链的连接进一步扩展为具有隧道的三维结构。

The split between the two groups can hardly be papered over.

这两个团体间的分歧难以掩饰。

This approach not only encourages a greater number of responses, but minimizes the likelihood of stale groupthink.

这种做法不仅鼓励了更多的反应，而且减少跟风的可能性。