三偶氮的
- 与 三偶氮的 相关的网络例句 [注:此内容来源于网络,仅供参考]
-
Starting from 3-benzoyl-5-formyl-indolizine, 3-benzoyl-5-(2'2'-diacetylethenyl)-indolizines and analogs were obtained by the 〓mediated aldol condensation or Wittig reaction. These compounds,promoted by low-valent titanium, gave highly functionlizedcycl[3,2,2]azine derivatives. The coupling reaction proceeded betweenthe carbonyl group and the carbon-carbon double bond, a rare example inMcMurry reaction.
我们以3-苯甲酰基-5-甲酰基中氮茚为原料,通过三碘化钐促进的aldol反应和Wittig反应制备了3-羰基-5-羰基乙烯基中氮茚,随后经低价钛还原偶联,没有生成正常的分子内羰基-羰基偶联产物,而是得到反常的羰基与α,β-不饱羰基的双键偶联产物,较高收率地得到了含多官能团的CycI[3,2,2]azine衍生物。
-
The third order nonlinear optical coefficient of a novel azobenzene compound was investigated by using Z-scan technique.
采用Z扫描技术对一种新的偶氮苯类化合物的三阶非线性光学系数进行了测量。
-
In part three, the absorption spectral behavior of binding reaction of cuprum- p-nitro-chlorophosphonazo Cu(Ⅱ-CPA-pN complex on bovine serum albumin was investigated.
第三部分:研究了蛋白质与Cu与对硝基偶氮氯膦的相互作用,发现蛋白质的加入能使配合物溶液的紫红色褪为紫色。
-
A series of azobenzenes with different electron effect substituents were prepared from diazonium salts and benzoguanamine.
将含有不同取代基的芳胺在盐酸介质中进行重氮化反应,制得相应的重氮盐,再与苯代三聚氰胺发生偶合反应,最终得到一系列含有不同取代基的偶氮化合物。
-
Using 2,4,6-〓 as phase-transfer catalyst, ten symmetrical azobenzene were prepared with a saturated solution of potassium ferricyanide in 2N aqueous potassium hydroxide and dichloromethane.
用2,4,6-三叔丁基苯酚为相转移催化剂,芳胺类化合物在饱和铁氰化钾的氢氧化钾溶液和二氯甲烷的两相转移催化下合成了10个对称取代偶氮苯,并对反应机理也做了合理的解释。
-
The method is based on the catalytic effect of trace activated manganese on the oxidation of brilliant green and 1-(2-pyridylazo)-2-naphthol by patassium periodate in Na2HPO4-KH2PO4 medium.
研究了在pH6.15的Na2HPO4-KH2PO4缓冲溶液介质中,氨三乙酸活化痕量锰催化高碘酸钾氧化灿烂绿和1-(2-吡啶偶氮)-2-萘酚褪色的指示反应。
-
On basis of the color reactions of 4-(2-pyridine azo)-resorcin with copper, zinc and manganese, but the absorption spectrum of complex compounds which they created overlapped with each other seriously. Dealing with the spectrum data with the method of multivariate calibrations of chemometrics, we can simultaneously analyze the measured spectrum of mixture.
基于这三种金属离子均能和4-(2-吡啶偶氮)-间苯二酚发生显色反应,但所生成络合物的吸收光谱重叠比较严重,采用化学计量学的多元校正方法,解析了Cu(上标 2+)、Zn(上标 2+)、Mn(上标 2+)混合物的测量光谱。
-
In addition, we found that 4-phenyl-l,2,4-triazolinium N-ylides reacted withvarious electron-deficient olefins to afford pyrrole derivatives in good yields via 1,3-dipolar cycloaddition oxidative ring fission, In some cases, tetrahydropyrrolo[1,2-b]triazole and pyrrolo[1,2-b]triazole, which are stable and are not aromatized orcleaved in the reaction conditions, could be isolated, This is a facile and novel route forthe synthesis of pyrrole derivatives.
此外,本文研究了五员三氮杂环化合物4-苯基1,2,4-三氮唑的N-叶立德,发现在氧化剂存在下与缺电子烯烃发生1,3-偶极环加成反应生成的吡咯并[1,2-b]三氮唑,在大多数情况下开环生成吡咯衍生物,反应条件温和,收率良好,是合成吡咯衍生物的一个新的途径。
-
Recently, ''click'' reaction has been regarded as a simple and versatile coupling strategy for the functionalization of nanoparticles.12 It is a green and ecient coupling approach, utilizing the copper-catalyzed 1,2,3-triazole formation between azides and terminal acetylenes.
近来,&点击&反应已经被看作一种用于纳米粒子功能化的简单而万能的偶联策略。[12] 它是一种绿色而有效的偶联方法,利用叠氮化物和端乙炔之间的铜催化1,2,3三氮唑的形成。
-
In this dissertation, preparation of polysubstituted ethene and heterocyclic compounds based on 2-hydroxyalkyl phenyl selenides andα-phenylselenopropionic acid reagents were further investigated as follow: Firstly, O-ethyl-O-vinyl phosphonates were prepared in a one-pot, two-step transformation by Mitsunobu reaction of 2-hydroxyalkyl phenyl selenides with monoethyl esters of phosphonic acid in the presence of diethyl azodicarboxylate and triphenyl phosphine (PPh3) followed by oxidation-eliminatio...
中文摘要:本文主要进一步探索了2-羟基烷基苯基硒醚、α-苯硒基丙酸试剂在制备多取代乙烯和杂环化合物反应中的应用,具体研究内容和结果如下:一、在偶氮二羧酸乙酯和三苯膦(PPh3)存在下,苯基-2-羟基烷基硒醚和O-乙基膦酸单酯发生Mitsunobu反应,无需分离和纯化反应中间体,直接使用30 %的双氧水进行氧化-消除反应,提供了&两步、一锅&合成O-乙基-O-乙烯基膦酸酯的新方法,该方法反应条件温和,操作简便,产物收率良好(76-82 %)。
- 推荐网络例句
-
I can not make it blossom and suits me
我不能让树为我开花
-
When temperatures are above approximately 80 °C discolouration of the raceways or rolling elements is a frequent feature.
当温度高于 80 °C 左右时,滚道或滚动元件褪色是很常见的特征。
-
The lawyer's case blew up because he had no proof.
律师的辩护失败,因为他没有证据。