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They had suppressed the cathodic process of carbon steel electrode. Their inhibition performance was also related with their molecule stereo conformation and electron configuration. Four of bis-(1, 1'-benzotriazoly)-α,β-diamide compounds linked via-CO 〓CO-chain were synthesized and certified by IR and 〓H-NMR. The minimum energy conformations of these compounds were obtained by MM2 forcefield program. The two benzotriazole moiety in BBT1 was more planar than in other compounds. This was beneficial in increasing the inhibition effects of BBT1. In 0.5M H〓SO〓 solution, BBT1 suppressed anodic corrosion reaction. In 3%NaCl solution, BBT1 suppressed both cathodic and anodic corrosion reactions. 1- [ (1'-imidazolly)-methyl] benzotriazole was synthesized by Mannich reaction.

合成了四个通过-CO〓CO-连接的双(1,1'-苯并三唑)-α,ω-二酰胺化合物,采用MM2分子力学程序优化了它们的分子结构,双(1,1'-苯并三唑)-α,ω-二酰胺化合物的缓蚀作用与其分子内两个苯并三唑单元的空间取向有关系,良好的平面性有利于苯并三唑二聚体的吸附和缓蚀作用,苯并三唑二聚体BBT1分子内两个苯并三唑单元近似平行,所以显示出较好的缓蚀效果。0.5M硫酸中BBT1主要抑制铜的阳极溶解的电化学反应;3%NaCl溶液中,BBT1对铜的阳极溶解和氧的阴极还原过程均有抑制作用,相比较而言对阴极过程的抑制作用更大一些。

Cephalotaxine ester of 2-oxo-6-methylheptanoic acid was treated with lithium diisopropylamide and Me O-(1-methoxyisopropyl)glycolate to give a mixture of homoisoharringtonine and its stereoisomers with 56% yield. The four stereoisomers separated by TLC showed identical mass spectra and almost superimposed IR but with different 1H NMR spectra. The configuration of the 2'-C and 3'-C of the four isomers were postulated based upon their 1H NMR spectra as compared with the 1H NMR spectra of isoharringtonine and its stereoisomers.

2-氧代-6-甲基庚酰基三尖杉碱(3)与0-(1-甲氧基异丙基)羟基乙酸甲酯(4)在强碱性试剂二异丙胺锂存在下,起亲核加成反应,反应中间体5在室温用酸性丙酮水解,得到一种新的三尖杉酯类生物碱一一高异三尖杉酯碱(6c)及其立体异构体(6a、6b、6d)的混合物,产率56%、通过制备薄层层析分得这四个立体异构体,它们的1H NMR和异三尖杉酯碱及其立体异构体的1H NMR类似,推定了它们的绝对构型。

At each penton, a hole (φ=20〓) can be seen connecting the inside and the outside of the capsid, and there is a hole (φ=12〓) at each hexton and the center of 2-fold axis, so there are 132 holes in total at the surface of CSBV.

应用冷冻电镜技术和计算机三维结构重构的方法,我们测定了CSBV核衣壳的三维结构,分辩率为25 〓,病毒的核衣壳是按T=1(P=3)的对称结构排列二十面体,病毒表面比较光滑,有12个五邻体、60个六邻体的结构,每个五邻体的中央有孔洞,六邻体的中央也有孔洞,另外在2次轴的位置上也有孔洞,这样病毒共有132个孔洞,五邻体的孔洞的直径为20 〓,而六邻体和二次轴的孔洞的直径月为12 〓。

Objective To study the incidence of trisomy 18 in NMRI mice and its developmental malformations.

目的 通过对 18三体在 NMRI小鼠发生率的研究及 18三体胚鼠和正常胚鼠的大体形态学对照观察,进一步认识 18三体 NMRI小鼠的生长发育畸形。

This is very rare and is thought to involve trisomy rescue; ie, the zygote started off as a trisomy and one of the three chromosomes was lost, leading to uniparental disomy in 1/3 of cases.

这是很罕见的并被认为还涉及三体挽救,即合子开始时为三体,而三条染色体中的一条丢失后在1/3的情况下导致单亲二体。

In addition ,nine new O,O-dialkyl-[α-(1,3,4,6-tetraacetyl-2-deoxy-β-D-glucoamino)-p-methyl benzlidene] phosphonatesand eight O,O-dialkyl-α-(2-deoxy-D-glucoamino)-p-methyl benzylidene phosphonates were prepared. The 〓 and〓 spectra of Ⅰ-Ⅴ compounds indicated clearly that each of Ⅰ-Ⅴ compounds contains two diastereo-isomers.

我们对非对映异构体的分离方法进行了研究,并分离得到了五个单一构型的异构体〓、〓、〓、〓和〓,培养出了〓、〓和〓三个异构体的单晶,通过X-射线衍射分析,确定了〓、〓和〓三个异构体的绝对构型,反应过程中引入的手性原子的构型均为R构型。

The number of chromosomes was varied in the progeny of the triploids.There were diploids and various aneuploids with chromos...

除了三体_(11)和二倍体相似,其它11个初级三体都有明显不同的形态学特点,可依照这些特点互相区别。

For the performance research of trimaran sailing in shallow waters, some advanced countries have put some efforts, in contrast with little made in our country.

三体船作为一种高性能的新船型近年来已引起造船界的兴趣,一些造船先进国家为开展这方面的研究投入了大量的人力和物力,我国在这发面起步比较晚,在该方面也开展了一定的工作并取得了一定的进展,但和先进国家还有一定的差距,尤其在三体船的性能研究方面与国外的差距更大,在浅水域三体船方面国外做了一些研究,我国在这方面的研究比较少。

Each time after putting to (the instrument with the set of Yamshidi-Nadel provided by Kypho of America for injection of bone cement into the vertebrae; each putting could contain about 1.5 mL bone cement) inject bone cement into the vertebrae, the pressure P was not very high, with 500 kPa bar below for majority and the effect caused showed a significant statistical difference (P.01). Whereas, the pressure within the area of the vertebral P value was not high either, the majority was 10.00 Unit lower, which also led to the effects of significant difference (P.01). Both two states showed partial distribution. After making the statistical analysis to the casual two puttings between the first, second, third and fourth putting of each vertebrae, there existed the general differences. The differences were also found between other puttings (a.0083) on the statistics basis apart from between the first and second and between the third and fourth.

结果 每个椎体的椎体成形术均达到临床评价要求,每次推杆(美国Kypho公司提供标准椎体成形术中Yamshi-Nadel套系中推注骨水泥入椎体的器具,每具推杆可容纳骨水泥约1.5mL)推注骨水泥入椎体时所产生的椎体内的压力P不是很高,多数在0.50 bar以下,其所导致的效应具有显著的统计学差异(P.01),而每次推杆推注骨水泥入椎体时的椎体内压力面积值P也不是很高,多数在10.00 Unit以下,其所导致的效应具有显著的统计学差异(P.01),两者均呈偏态分布;而且,对每例椎体的第一、二、三、四杆之间两两予以统计学上的分析,在总体存在差异有统计学意义的基础上还发现除第一和二杆、第三和四杆之间外,其他各杆之间存在着差异(a.0083)。

A seven-node difference scheme of the diffusion equation was proposed to study the behaviors of transient electromagnetic field in complicated 3-D geoelectric body. Models of roadway and anomaly body were set up for simulating the transient field excited by a vertical magnetic dipole source. The result of numerical simulation shows that the presence of low resistive conductor leads to noticeable distortion of isolines for the "smoke ring" field, whereas the distortion is not so obvious where the roadway and the poor conductor are located.

为了探讨复杂三维地电体中瞬变电磁场的响应特征,推导了三维扩散方程的七点差分格式,建立了巷道和异常体模型,并对垂直磁偶源激发的瞬变场进行了数值模拟,观察到早期&烟圈&场在低阻体处等值线发生的明显畸变,在巷道和高阻体处的畸变较弱,随着时间的增加异常体的影响逐渐减弱。

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The basic concept of FOP can be summarized as to further optimize effective prescription according to the standard of curative effects and with the aid of modern science and technology and theories of traditional Chinese medicine.

其基本内涵可概括为:以确有疗效的中药复方为研究对象,以现代科学技术和传统中医药理论为技术支持,以该复方所治病证的药效响应为评价标准,以优化重组疗效更优的新复方为研究目的。

Ever since our world has been a world, native forests have been indiscriminately exploited by man.

自从我们的世界一直是世界原生森林被任意剥削人。

I don't… don't know. He's unconscious.

我不……我不知道他休克了。