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三乙胺

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Methods 4-Hydroxy- benzonitrile was treated with sodium hydrogen sulfide and anhydrous magnesium chloride in dimethyl formamide to give thioamide, which was then directly cyclized with ethyl 2-chloroacetoacetate without separation to give ethyl 2-(4-hydroxyphenyl)-4-methylthiazole-5-carboxylate(2) in one-pot; then 2 was formylated with Duff reaction adopting hexamethylenetetramine in trifluoroacetic acid to give ethyl 2-(3-formyl-4-hydroxyphenyl)-4-methylthiazole-5-carboxylate(3); finally, the target compound was obtained by the treatment of 3 with hydroxylamine hydrochloride and sodium formate in formic acid.

采用"一勺烩"方法,以4-羟基苯甲腈为起始原料,首先与硫氢化钠和无水氯化镁在N,N-二甲基甲酰胺中反应,所得中间体不经分离,直接加入2-氯乙酰乙酸乙酯进行环合反应,得到2-(4-羟基)苯基-4-甲基-5-噻唑甲酸乙酯(2);然后通过六亚甲基四胺/三氟乙酸进行Duff反应,得到2-(3-甲酰基-4-羟基)苯基-4-甲基-5-噻唑甲酸乙酯(3);再经盐酸羟胺/甲酸/甲酸钠体系脱水得到目标化合物。

Uranium solution is obtained electrolytically by reducing uranyl ion on mercury cathode. The effect of the addition of various aminopolycarboxylic acids (such as EDTA, DTPA, CyDTA and TTHA) and organic water-miscible solvents (such as CH3OH, C2H5OH and CH3COCH3) on the stability of ura-nium in air has been investigated. The absorption spectra of uraniumand uraniumin 1 mol/l and 9mol/l hydrochloric acid solutions are examined.

本文采用汞阴极电解还原法制备了铀溶液,研究了在盐酸介质中各种氨羧络合剂乙二胺四乙酸二钠、二乙三胺五乙酸、1,2-环已烷二胺四乙酸、三乙基四胺六乙酸和水溶性有机溶剂甲醇、乙醇和丙酮的存在对铀稳定性影响,测定了在不同盐酸浓度中铀和铀的吸收光谱。

In this paper six kinds of alkyl polyamine polymers which were polyethylene glycol of molecular weight of 400, 600 and 1,000 modified with ethylenediamine or diethylenetriamine were synthesized, and the effects on ink absorption speed, definition and image quality of ink-jetprinting coating layer were studied. At the same time, the better coating formula were found.

本论文合成了六种烷基多胺——乙二胺和二乙三胺改性分子量为400,600以及1000的聚乙二醇所得到的产物,并且研究了它们对喷墨打印材料吸墨涂层的吸墨速度、清晰度及影像质量的影响,最后找出比较理想的涂层配方。

According to the compared analysis of prevention sulfur deposition during the production of high sour gas well, the key of prevent sulfur deposition and to control sulfur blocking is choose right element sulfur, carry out some research on the selection of sulfur solution, remix the triethylenetetramine, diethylenetriamine and monoethanolamine in different ratios, finally formed LJ-1 compounding which is best fit the production of north Sichuan province.

对比分析了多种硫沉积防治方法,防治的关键在于溶硫剂的合理选择,通过溶硫剂优选室内评价实验研究筛选出三乙烯四胺、二乙烯三胺和乙醇胺等三种单剂,按照不同的比例与现场使用的防冻剂乙二醇进行复配,最终形成了适合川东地区高含硫气井的溶硫剂LJ-1合理配方,性能评价实验表明溶硫剂LJ-1溶硫速率快、溶解度高、腐蚀小。

The detectable group, biotin-ε-aminocaproic acid N-hydroxysuccinimide ester, is attached to the remaining amino group. A series of multiamine compouds, i. e. ethylendiamine, 1, 6-hexandediamine, triethylenetetramine, tetraethylenepentamine, and synthetic polyarylamide are used inlabelling, it is found that linker arms and steric hindrance effect the detection sensitivity. The probes labeled by 1, 6-hexandediamine and triethylenetetramine can detect 0.1-0.5pg target DNA in dot blot hybridization, and their sensitivities are better than the others.

本文详细考察了乙二胺、己二胺、二乙烯三胺、三乙烯四胺、四乙烯五胺及合成的聚乙烯胺化合物对λDNA探针的标记和检测的影响,发现胺化物链长和空间位阻影响探针的杂交和检测,用己二胺和三乙烯四胺标记的生物素探针在杂交24小时、显色8小时后检测灵敏度达0.1-0.5pg,超过其它胺化物标记的探针。

Ingredients: Water,Lauric Acid,Myristic Acid,Stearic Acid,Propylene Glocol,Potassium Hydroxide,Cocamidopropyl Betaine,Starch Hydroxypropyltrimnium Chloride,Sodium Laureth Sulfate,Glycol Distearate,Lavandula Angustifolia Oil,Creatine,Tetrasodium Edta,Perfume,Dmdm Hydantoin.

成分: 去离子水,月桂酸,肉豆蔻酸,硬脂酸,丙二醇,氢氧化钾,椰油酰胺丙基甜菜碱,淀粉羟丙基三甲基氯化铵,月桂醇聚醚硫酸钠,乙二醇双硬脂酸酯,薰衣草精油,肌酸,乙二胺四乙酸四钠,香精,DMDM 乙内酰脲。

These salts can beprepared on treatment of phosphinimines with trifluoroaceticanhydride. After addition-elimination, triflromethylated β-enaminoesters and β-iminoesters were synthesized by thereaction of the above salts with organozinc reagents.

通过膦亚胺和三氟乙酸酐反应制备了N-三氟乙酰基氨基膦盐,该膦盐和锌试剂发生加成-消除反应后,合成了含有三氟甲基的β-烯胺酯和β-亚胺酯。

Huapai products:pchlorophenol,ochlorophenol,2,4dichlorophenol,2,6dichlorophenol,2,4,5trichlorophenol,2,4,6trichlorophenol,4chloro2benzyl phenol,pbromophenol,2,4,6tribromophenol,1chloro4(1,1dimethyl ethyl) benzene ether,3bromoanisole,mbromofluorobenzene,2tetra hydrofuran,αbromo4chloro acetophenone,αbromo4methoxy acetophenone,4chloro benzophenone,4chloro2methylaniline,n(2hydroxyethyl)ethane diamine; n(2aminoethyl)ethanolamine,2,3dibromopropionyl chloride,4bromo benzene sulphonyl chloride,terephthaloyl chloride,isophthaloyl chloride,nchlorosuccinimide,nbromosuccinimide,pchloranil;tetrachloro1,4benzoquinone,5chloroisatin.

华派公司产品:对氯苯酚,邻氯苯酚,2,4二氯苯酚,2,6二氯苯酚,2,4,5三氯苯酚,2,4,6三氯苯酚,4氯2苄基苯酚,对溴苯酚,2,4,6三溴苯酚,对氯苯基叔丁基醚,间溴苯甲醚,间溴氟苯,α溴甲基四氢呋喃,α溴代4氯苯乙酮,α溴4甲氧基苯乙酮,4氯二苯甲酮,4氯2甲基苯胺,N(2羟乙基)乙二胺, 2,3二溴丙酰氯,对溴苯磺酰氯,对苯二甲酰氯,间苯二甲酰氯,N氯代丁二酰亚胺,N溴代丁二酰亚胺,四氯苯醌,5氯靛红。

Methods 4-Hydroxy- benzonitrile was treated with sodium hydrogen sulfide and anhydrous magnesium chloride in dimethyl formamide to give thioamide, which was then directly cyclized with ethyl 2-chloroacetoacetate without separation to give ethyl 2-(4-hydroxyphenyl)-4-methylthiazole-5-carboxylate(2) in one-pot; then 2 was formylated with Duff reaction adopting hexamethylenetetramine in trifluoroacetic acid to give ethyl 2-(3-formyl-4-hydroxyphenyl)-4-methylthiazole-5-carboxylate(3); finally, the target compound was obtained by the treatment of 3 with hydroxylamine hydrochloride and sodium formate in formic acid.

采用&一勺烩&方法,以4-羟基苯甲腈为起始原料,首先与硫氢化钠和无水氯化镁在N,N-二甲基甲酰胺中反应,所得中间体不经分离,直接加入2-氯乙酰乙酸乙酯进行环合反应,得到2-(4-羟基)苯基-4-甲基-5-噻唑甲酸乙酯(2);然后通过六亚甲基四胺/三氟乙酸进行Duff反应,得到2-(3-甲酰基-4-羟基)苯基-4-甲基-5-噻唑甲酸乙酯(3);再经盐酸羟胺/甲酸/甲酸钠体系脱水得到目标化合物。

In this paper, the improvement of synthetic method of 2-acetylaminotropone is introduced. 3-Acetyltropolone reacted with low concen-tration methylamine solution and solvent was directly evaporated in reduce pres-sure to give 2-acetyl-7 -methylaminotropone in good yield. The compound reacted with phenyltrimethylammonium tribromide to give two new compounds.

本文介绍2-乙酰基-7-甲胺基酮合成方法的改进——用挥发性小的低浓度甲胺溶液与3-乙酰基酚酮反应;和采用直接减压蒸除溶剂法分离产品,得到较好产率的2-乙酰基-7-甲胺基酮;用化合物与三溴化苯基三甲铵反应,得到两种至今未见文献报道的新化合物。

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