三乙胺

Effects on the reaction of factors such as reactant ratio, reaction time, and reaction temperature were investigated, and optimum reaction conditions were determined as follows: mole ratio of cyanuric chloride to ethylamine to sodium hydroxide to sodium methyl mercaptide was 1:2.1:2.0:1.7, and the temperature and time of the first, second, and third substitution reactions were -2, 0, and 82℃ and 30, 60, and 180 min, respectively.

讨论了原料配比、反应时间和反应温度等因素对反应的影响，获得了较佳的反应条件。较佳反应条件为三聚氯氰：乙胺：氢氧化钠：甲硫醇钠＝l：2.1：2.0：1.7，第一、第二、第三取代反应的反应温度和反应时间分别为-2℃、0℃、82℃和30、60、180min。

Project Background and Conditions: The company started research new chemical products in 1998. After two years of efforts, a series of pharmaceutical intermediate sulfathiazole leave instructions, including : 3- methyl sulfathiazole leave instructions, 2- sulfathiazole leave instructions ethanoic acid, 2- acetyl sulfathiazole leave instructions, 2-thiofuran amino ethane ,2-thiofuran acetic, 3,4,5- tighter nitrobenzene have been successfully developed. 2-thiofuran amino ethane are the precursors raw materials of series antibiotic analgesic.

二、项目建设背景及条件：1998年公司开始研究开发高新精细化工产品，经过两年的努力，已成功研制出噻吩系列医药中间体，包括：3-甲基噻吩、2-噻吩乙酸、2-乙酰噻吩、2-噻吩乙胺、2-噻吩乙醇、3，4，5-三氯硝基苯等。2-噻吩乙胺系列噻吩产品使用于血小板及血栓有关的心脏血管病及消炎镇痛等如氯吡格雷、兴孢噻吩钠、兴孢西丁、噻吩洛酸等十几种新药的前体原料，是国家政策鼓励发展和有自主知识产权的项目。

Using ethyl cyanoacetate , triethyl orthoformate and methylhydrazine as main raw materials, the herbicide pyrazosulfuron was prepared through the reactions of substitution, amination, cylclization, diazotization and chlorosulfonation.

以氰乙酸乙酯、原甲酸三乙酯和甲肼等为主要原料，通过取代、胺化、环化、重氮化和氯磺化等反应制得了除草剂吡嘧磺隆原料药。

To synthesize the octreotide, Phe-Leu-Glu-Glu-Leu and C_(15)H_(31)-CO-Lys-Thr -Thr-Lys-Ser peptides, the strategies are as followings: Fmoc- group as protective group for α-NH_2; TBTU, DIEA and HOBt as coupling reagent; and ethanedithiol -phenol - thioanisole - H_2O - TFA ( 2.5:5:5:5:82.5 , V/V ) as cleaving solution.

采用Fmoc固相合成法，以苯并三哗四甲基脲四氟硼酸盐、二异丙基乙胺和1-羟基苯骈三氮唑为缩合剂；苯酚—乙二硫醇—苯甲硫醚—水—三氟乙酸(5：5：2.5：5：82.5，V/V)为切割试剂，合成了奥曲肽、Phe-Leu-Glu-Glu-Leu及C_(15)H_(31)-CO-Lys-Thr-Thr-Lys-Ser三种小分子多肽，并对奥曲肽的合成规模进行了放大。

The key intermediate 3-methylaminopiperidine was synthesized from 3-methylaminopyridine by two methods,formylation and lithium aluminium hydride reduction or condensation with triethyl orthoformate and sodium borohydride reduction,and then hydr...

以3-氨基吡啶为原料，分别通过甲酰化反应、氢化铝锂还原和原甲酸三乙酯缩合、硼氢化钠还原两种方法得到3-甲胺基吡啶，最后经催化氢化得到中间体3-甲胺基哌啶。

The key intermediate 3- methylaminopiperidine was synthesized from 3-methylaminopyridine by two methods, formylation and lithium aluminium hydride reduction or condensation with triethyl orthoformate and sodium borohydride reduction, and then hydrolysis.

以3-氨基吡啶为原料，分别通过甲酰化反应、氢化铝锂还原和原甲酸三乙酯缩合、硼氢化钠还原两种方法得到3-甲胺基吡啶，最后经催化氢化得到中间体3-甲胺基哌啶。

At room temperature, solution's pH=11, mole proportion of solution are 1:3 (ammonium sulfate and diethyl amine),1 :2.5(ammonium sulfate and diethylene triamine) and 1:2 (ammonium sulfate and triethylene tetramine).

在室温下，固定剂溶液pH=11，溶液物质的量配比分别为硫酸铵与二乙胺1：3、硫酸铵与二乙烯三胺1：2.5和硫酸铵与三乙烯四胺1：2。

The structural assignment of Ⅱwas supported by spectral data and was confirmed by the identification of the compound as the product obtained by synthesis from triethyl orthoacetate and 2- cyanot hioacetamide.

结构的指定得到由光谱数据的支持，确认结构是通过原乙酸三乙酯和2-氰基-硫代乙酰胺合成得到的化合物。

The composition and fluorescence property of 2,2,2-amine tri acetyl-benzylamine with ligand of tripod type were studied through Molar conductivity, infrared spectrum, NMR, elemental analysis, thermal analysis, and UTA-TG analysis.

方法］通过摩尔电导率、红外光谱、核磁共振波谱、元素分析、差热－热重分析，研究三脚架型配体2，2，2-胺三乙酰－苄胺及其稀土配合物的组成、荧光性质。

It is made generally with mixed salt of triethanolamine and ammonium hydroxide, twelve-acid isopropyl alcohol amides, for malde-hyde, polyvinyl chloride, wool oil, spice, pigment and water as raw materials.

一般采用硫酸脂肪醇的乙三醇胺与氢氧化胺的混合盐、十二酸异丙醇酰胺、甲醛、聚氧乙烯、羊毛脂、香料、色料和水作为原料。

I am accused of being overreligious," she said in her quiet, frank manner,"but that does not prevent me thinking the children very cruel who obstinately commit such suicide.""

客人们在卡罗利娜·埃凯家里，举止就文雅一些，因为卡罗利娜的母亲治家很严厉。

Designed by French fashion house Herm è s, this elegant uniform was manufactured in our home, Hong Kong, and was the first without a hat.

由著名品牌 Herm è s 设计，这件高贵的制服是香港本土制造，是我们第一套不配帽子的制服。