三

Through Friedel-Crafts reaction, We have prepared highly purified triphenylphosphine sulfide by using benzene, phosphorus trichloride, sulfur, and aluminum trichloride, which is desulfurized with metal powder to produce triphenylphosphine.

实验方法为以苯、三氯化磷、硫和三氯化铝为原料，利用Friedel-Crafts反应，合成三苯基硫膦，收率为79.4％；然后用金属将三苯基硫膦还原制得三苯基膦，收率为80％。

The prevention and countermeasure of Nitrogen Trichloride fire explosion were discussed from the fire explosion fatalness,the harm,the reason of forming and gathering in the chlorin and alkali producing of Nitrogen Trichloride in the article.

赵秋德，三氯化氮火灾爆炸防治对策研究从三氯化氮的火灾爆炸危险性，三氯化氮的危害，三氯化氮在氯碱生产中生成和富集原因等方面入手，论述了三氯化氮火灾爆炸事故的防治对策。

In this study, genetic analyses were conducted to determine the genetic basis in an elite resistant inbred line Siyi with complete resistance to maize dwarf mosaic. A new genetic model, two dominant complementary genes conditioning the resistance, were found by Mendelian genetic analysis based on parents, F1, F2 and backcrosses in three successive years' field trails. The two genes were further mapped near the centromere of chromosome 3 and 6, respectively by tightly linked microsatellite markers using 242 plants from F2 generation. The resistance gene on chromosome 3 is 1.0 cM apart from the flanking markers phi053 and umc1527, respectively. Whereas the linkage distance between two flanking markers bnlg1600 and phi075 and resistance gene on chromosome 6 was 1.0 and 4.0 cM, respectively. Genotypic analysis of the plants from testcross and F3 populations supported the new genetic manners.

课题组通过连续三年的抗病鉴定，在国内种质资源中筛选出一份综合农艺性状优良、配合力较高的自交系四一，三年的表型遗传研究和两年的分子标记工作，发现四一中的玉米矮花叶病抗性是由两对显性互补基因控制的，进而利用F2作图群体，把发现的两个基因定位在第三和第六染色体的着丝点附近，并获得了双侧紧密连锁的分子标记连锁图谱，其中第三染色体上的分子标记UMC1527和phi053从抗病基因双侧逼近1 cM，而第六染色体上的分子标记phi075、bnlg1600从抗病基因双侧分别逼近4 cM和1 cM；利用B2群体、F2：3家系、BC3F1群体和带有第三、第六染色体抗病基因以及两个抗病基因的近等基因系，进一步证实了四一中成株期抗性是由两个显性互补基因控制的。

A three-dimensional simulation method based on Matlab was designed. Moreover its better simulation was verified by a contrast diagram from different fiber finesses and a figure after three dimensional mapping. Finally, the main applications and their development directions for the two methods were prospected on a simulation based on lines and a three-dimensional map.

论述了基于Matlab的三维纱线模型的建立方法，并通过不同细度纤维构成纱线对比效果图和三维映射后三维纱的模拟图，验证了该法可以模拟出真实感较强的三维纱线，指出线性模拟和三维映射2种方法的主要用途和发展方向。

The average percent value of G C (49.3%) was less than that of A T (50.7%), there was a bias of the content of G, T in the third codon; The number of transition G-A and T-C were 22, 15 respectively, which were higher than that of transition A-G and C-T, the number of tranversion C-A, T-G is 2 respectively, and other tranversion patterns didnt occur; the probability of transition was higher than that of tranversion , Ts/Tv = 9.5-19, there was the highest number of transition in the third codon. The gamma parameter a of the lst,nd and 3rd codon positions were 0.00572,0.01237 and 1.05239 respectively, they showed that there was adifferent substitution rate at different codon position. Frequences of synonymous codon usage were relatively biased. The average rates of synonymous and nonsynonymous substitution were 0.0787, 0.0011 respectively, there was a significant difference between dS and dN (Z = 4.713, p.01), and the low ratio( CD = 0.0284 .3) of dN/dS ratio impled that there were selective constraints against the nonsynonymous sites in cyt-b gene, The distribution of nonsynonymous codon substitution pattern related to Grantharm distance indicated that the purified selection at 2nd codon positions was more intensive than that at 1st codon positions. The phylogenetic trees supported the view of the double origin of Chinese goose, which means that domestic Chinese goose was derived from Anser cygnoides and domestic European goose, and Yili was derived from Anser anser.

碱基含量分析可知，序列的G C含量(49.3％)＜A T含量(50.7％)，密码子第三位点的G、T含量都有较强的偏倚性；序列间G→A和T→C的转换数(22次和15次)高于A→G和C→T的转换数(10次和9次)，C→A、T→G颠换数均为2次，其余颠换模式均未发生；转换数明显高于颠换数，Ts／Tv=9.5～19，密码子第三位点的转换数最高，呈现了相当强烈的转换偏倚性；密码子第一、二和三位点的gamma分布参数α值分别为0.00572、0.01237和1.05239，表明密码子第一位点的替换速率变异最大，第二位点次之，第三位点的替换速率变异相对较小；编码同一氨基酸的同义密码子并非随机使用，表现出一定程度的使用偏倚性；同义替换速率和非同义替换速率分别为0.0787和0.0011，dS与dN值间的差异极显著(Z=4.713，p＜0.01)，而ω=0.0284，明显小于0.3，表明雁属鹅细胞色素b基因序列经历了中度净化选择作用；单步非同义替换(Sing-step nonsymonymous codon substitution，SSNCS)分布模式与Grantharm距离之间的关系说明密码子的三个位点所受的净化选择强度不同；构建的最大简约树与邻接树拓扑结构一致，支持中国家鹅的双起源学说，即除伊犁鹅外的其它中国鹅品种起源于鸿雁，伊犁鹅和欧洲的郎德鹅、莱茵鹅起源于灰雁。

In this paper, the stable Au complexes are classified according to the coordination atoms and their characteristic structure. The recent development of the researches on the antitumor activity of Au complexes including the structure-activity relationship, biological targets and the mechanisms of action are reviewed. The structure of the coordination ligand and the leaving group have great impact on the in vitro cytotoxicity of the Au complex. Many physical and biological methods are introduced to study the interaction between the Au complexes and the suspected bio-target, such as DNA, protein, mitochondrion, thio-containing biomolecules, etc. The interaction modes (intercalating, electrostatic interaction, covalent bonding, etc.) are focused to illustrate the reason for the antitumor activity of Au complexes.

本文按配位原子的不同总结了稳定三价金配合物的结构特征，按其生物活性的构效关系、生物靶点和作用机制综述了三价金配合物抗肿瘤活性研究的最新成果：配体的结构特点以及离去基团对三价金配合物的体外细胞毒性影响较大；介绍了用于检测三价金配合物与可能的生物靶分子之间的相互作用的多种物理和生物学方法，重点关注了相互作用的模式，如嵌入/静电吸引/共价结合等，并解释了三价金配合物抗肿瘤活性的原因。

In this paper, the stable Au complexes are classified according to the coordination atoms and their structural characteristics. The recent development of the researches on the antitumor activity of Au complexes including the structure-activity relationships, biological targets and the mechanisms of action are reviewed. The structure of the coordination ligand and the leaving group have great impact on the in vitro cytotoxicity of the Au complex. Many physical and biological methods are introduced to study the interaction between the Au complexe and the suspected bio-target, such as DNA, protein, mitochondrion, thio-containing biomolecules, etc. The interaction modes (intercalating, electrostatic interaction, covalent bonding, etc.) are focused to illustrate the reason for the antitumor activity of Au complexes.

本文按配位原子的不同总结了稳定三价金配合物的结构特征，按其生物活性的构效关系、生物靶点和作用机制综述了三价金配合物抗肿瘤活性研究的最新成果：配体的结构特点以及离去基团对三价金配合物的体外细胞毒性影响较大；介绍了用于检测三价金配合物与可能的生物靶分子之间相互作用的多种物理和生物学方法，重点关注了相互作用的模式，如嵌入/静电吸引/共价结合等，并解释了三价金配合物抗肿瘤活性的原因。

3D-CTM (Coupled Thermo-Mechanical Forming Simulation) software for precision forging process of aero-engine blade was developed. The key technologies of 3D coupled rigid-viscoplastic thermo-mechanical FEM simulation of blade forging process were studied systematically. By using the remeshing method of contracting from the boundary to the inner, new mesh system from old distorted mesh system can be obtained. A method of modifying the position of nodes touching on the die according to its original normal was proposed to avoid "dead lock" problem due to uncontinuity of normal of scatted die meshes. The pseudo-static iterative algorithm was used to simplify the coupled thermo-mechanical computation. In particular, formulations to determine relaxation factor β was established for rigid viscoplastic FEM adopting penalty function method, and an improved cubic factor rapid algorithm derived from these formulations was proposed by combining with the advantage of advance and retreat search method.

采用基于边界构形的内缩法，实现了三维畸变网格的重新划分；提出了初矢修正法对触模节点的位置进行修正，解决了由于离散的模具网格的法矢不连续造成的&死锁&问题；采用准静态迭代法简化了速度场和温度场耦合计算过程；特别是针对减速因子β的选取，建立了适用于三维复杂成形过程刚粘塑性罚函数法有限元三次因子法的计算公式，并结合进退搜索法提出了改进的三次因子快速算法，提高了模拟计算效率和稳定性，在此基础之上，开发了面向叶片精锻过程的三维刚粘塑性热力耦合有限元模拟分析系统(3D-CTM)，系统的可靠性得到了圆柱体镦粗的验证。

This problem is also important and valuable in Nonlinear Optics. It will be very helpful to understand how the aberrations affect the course of three- wave mixing, such as the change of conversion efficiency, the distribution of intensity and phase.Small signal solution of aberrated second harmonic generation is deduced from three-dimension three wave coupling functions. The numerical work gives out lot of results of different aberrations. The effects of the fundamental waves aberrations, which will change the conversion efficiency, distribution of intensity and phase in the frequency conversion, is analyzed. It shows that when walk-off and diffraction effects could be ignored approximately estimation of the phase distribution of second-harmonic wave could be done. The far field divergent angle and second moment radius of harmonic wave will vary with the aberration of fundamental wave, but the far field divergent angle will be obviously smaller than that of fundamental wave. The phase distribution of both fundamental and harmonic wave is measured using Hartmann-Shack wave front sensor in the experiment with 1064nm and 790nm lasers, respectively. Results are given.

首次从三维三波相互作用方程组推导得到了位相畸变光束倍频的小信号解；通过建立国防科学技术人学研究生院学位论文三维数值模型，编写相应仿真程序，首次得到了位相畸变光束倍频过程的大量计算结果，深入细致地研究了位相畸变光束经非线性光学频率变换后谐波的转换效率、光强分布、位相分布以及影响它们的各种因素；得出谐波的远场发散角和光斑二阶矩的变化规律会因为基波像差的不同而不同，但谐波的远场发散角明显地比相应基波的小的结论；得到了在走离效应和衍射效应等影响许多因素可以忽略的情况下，位相畸变传递到二次谐波的估算式；举例分析了KDP三倍频方案中，基波位相畸变对二次谐波和三次谐波的影响；实验工作中，用哈特曼一夏克传感器分别对IO64nm倍频过程和790飞秒超短脉冲倍频过程中的基波和谐波的位相分布进行了测量，给出了相应结果。

Small signal solution of aberrated second harmonic generation is deduced from three-dimension three wave coupling functions. The numerical work gives out lot of results of different aberrations. The effects of the fundamental wave's aberrations, which will change the conversion efficiency, distribution of intensity and phase in the frequency conversion, is analyzed. It shows that when walk-off and diffraction effects could be ignored approximately estimation of the phase distribution of second-harmonic wave could be done. The far field divergent angle and second moment radius of harmonic wave will vary with the aberration of fundamental wave, but the far field divergent angle will be obviously smaller than that of fundamental wave. The phase distribution of both fundamental and harmonic wave is measured using Hartmann-Shack wave front sensor in the experiment with 1064nm and 790nm lasers, respectively. Results are given.

首次从三维三波相互作用方程组推导得到了位相畸变光束倍频的小信号解；通过建立三维数值模型，编写相应仿真程序，首次得到了位相畸变光束倍频过程的大量计算结果，深入细致地研究了位相畸变光束经非线性光学频率变换后谐波的转换效率、光强分布、位相分布以及影响它们的各种因素；得出谐波的远场发散角和光斑二阶矩的变化规律会因为基波像差的不同而不同，但谐波的远场发散角明显地比相应基波的小的结论；得到了在走离效应和衍射效应等影响许多因素可以忽略的情况下，位相畸变传递到二次谐波的估算式；举例分析了KDP三倍频方案中，基波位相畸变对二次谐波和三次谐波的影响；实验工作中，用哈特曼-夏克传感器分别对1064nm倍频过程和790飞秒超短脉冲倍频过程中的基波和谐波的位相分布进行了测量，给出了相应结果。

According to the clear water experiment, aeration performance of the new equipment is good with high total oxygen transfer coefficient and oxygen utilization ratio.

曝气设备的动力效率在叶轮转速为120rpm～150rpm时取得最大值，此时氧利用率和充氧能力也具有较高值。

The environmental stability of that world - including its crushing pressures and icy darkness - means that some of its most famous inhabitants have survived for eons as evolutionary throwbacks, their bodies undergoing little change.

稳定的海底环境─包括能把人压扁的压力和冰冷的黑暗─意谓海底某些最知名的栖居生物已以演化返祖的样态活了万世，形体几无变化。