丁醛

The main object of this research is to investigate synthesis of Cu23Cl Cu and CuO nanoparticles through electrospinning and heat-treated method The research is mainly focused on preparative parameter and the change of heat-treated temperature to form the nanoparticles inlaid in silicon fibers the shape and color change are dicussed First of all to prepare the Polyvinyl butyral and silica dioxide complex nanofiber by electrospinning and then to investigate different heat-treated temperature and reactive time to being an influence on the products The results detected by SEM XRD TEM EDS FTIR combined sol-gel process and electrospinning can prepare Polyvinyl butyral and silica complex nanofiber The experimental result is found when heat-treated temperature is 100~4750C it can produce Cu23Cl nanoparticles; Above 4750C~ 4900C it can produce Cu nanoparticles; Above 450~7000C it can produce CuO nanoparticles And the viscosity is lain between 20~40cp and the sol-gel process time is 3hr it can produce the thinner fibers The average diameter of the fibers are 107 88±21 01nm;Due to the nanoparticles inlaid in the silica fibers the thinner fibers can be inlaid the smaller nanoparticles so this is the result that the experiment is expected To calcine the complex fibers is to produce surface silica fibers contain Cu23Cl Cu and CuO nanoparticles due to surface plasma resonance it make the color of the fibers become yellowish green from light white green turn into the red nuclear finally As the experimental result to utilize sol-gel process combine electrospinning can produce porous silica fibers contain Cu23Cl Cu and CuO nanoparticles

本研究旨在探讨「利用放电纺丝和热处理法来合成Cu23Cl、Cu和CuO奈米粒」之研究，实验著重在制备参数与热处理温度变化对所形成的奈米粒镶嵌在二氧化矽纤维中的形态与颜色变化探讨。首先，利用放电纺丝法制备出聚乙烯醇缩丁醛及二氧化矽之奈米纤维，比较不同的热处理温度与反应时间的改变对产物生成产生影响，进而研究不同热处理温度和时间对生成奈米粒的影响。产物经由SEM、XRD、TEM、EDS和FTIR等仪器分析结果显示，结合溶胶-凝胶法(sol-gel process)和放电纺丝法可产生聚乙烯醇缩丁醛及二氧化矽复合奈米纤维。实验结果发现，若热处理温度在100~4750C下可得到Cu23Cl奈米粒，475~4900C 可得Cu奈米粒，450~7000C以上可得 CuO奈米粒。而黏度介於20~40cp间和溶胶-凝胶时间为3hr时，可产生直径比较细的纤维，纤维直径为107 88±21 01nm；且由於奈米金属颗粒镶嵌在二氧化矽纤维中，直径比较细的纤维，可以得到比较小的奈米金属颗粒，这与实验预期相符。而锻烧此复合物产生多孔的二氧化矽纤维并包含Cu23Cl、Cu和CuO奈米微粒时，由於表面电浆子共震关系，而使纤维颜色由淡白黄绿色变成黄绿色，再变红褐色。由实验结果得知，利用溶胶-凝胶法(sol-gel process)结合放电纺丝法和不同热处理温度，可产生Cu23Cl、Cu和CuO奈米粒镶嵌在二氧化矽纤维。

It is show that the concentration of n butyraldehyde, neptunium, uranium and HNO 3, ratio of phases effect the stripping of Np in the cascade, i.e.

串级实验结果表明，镎在 1BP中的比例小于 10 %；第二级加入正丁醛时，正丁醛和镎在各级的分布较合理，能兼顾镎的去污与反萃。

Through research, we find that the non-uniform dispersion of butyraldehyde in PVA solution is the main reason of PVB agglomeration. Adding butyraldehyde to the PVA solution at the temperature of 40-60℃can ensure the uniform dispersion of butaraldehyde in PVA solution.

通过改变工艺条件，在40-60℃的条件下，将正丁醛加入PVA溶液中，可保证正丁醛分散均匀，降至适当温度后，再滴加盐酸，这样在不加任何乳化剂的条件下也得到了粉末状的PVB产品。

This basic research is armed to find out and to predict SCF particularity, which are very important for the SCF application. Firstly the densities of the binary mixtures of CO2—methanol, CO2—ethanol, CO2—n— butyraldehyde and CO2—i—butyraldehyde were measured from 313.5K to 323.5K under the pressure range from 7 to 14MPa.

本文首先在313.5～323.5K、7～14MPa范围内测定了CO2及CO2—甲醇、CO2—乙醇、CO2—正丁醛、CO2—异丁醛二元混合流体的表观密度，讨论了压力、第2组分的种类和加入量对CO2表观密度的影响，在此基础上计算了溶质的偏摩尔体积，讨论了温度、压力和第2组分的性质对溶质偏摩尔体积的影响规律。

In this study, the constant volume visual method is used to measure the critical point properties of CO 2+toluene, CO 2+cyclohexane, CO 2+ n butyraldehyde, CO 2+ i butyraldehyde, CO 2+methanol and CO 2+ethanol binary systems.

采用固定体积可视观察法测定了 CO2 +甲苯、CO2 +环己烷、CO2 +正丁醛、CO2 +异丁醛、CO2 +甲醇及 CO2 +乙醇二元体系的临界点性质，为超临界萃取和化学反应提供基础数据。

The auxiliary can be recovered in high yield (81%) only by filtering and recrystallization. Besides, some other aldehydes have been chosen to test the enantioselectivity of N,N\'-dibenzyl tartamide, in comparison with two other allylaborates reagents developed previously by Roush and Brown, respectively. The results show that %e.e. of homoallylic alcohol is superior to that of the former, and approaches the Brown reagent.

产物经S_N2反应得瑞格列萘中间体-甲基烯丙基-2-氯苯基-叠氮甲烷(17)；同时，将筛选出的新型手性配体N-苄基酒石酸二酰胺用于其他几种醛(正丁醛，异戊醛和环己醛)的不对称烯丙基化反应，并与广泛应用的Roush配体(22)和Brown配体(27)相比较，发现其立体选择性优于Roush配体，并接近Brown配体，但明显具有可回收利用的优势。

The preparation of 2,2-dimethyl-3-hydroxy propanal from the condensation of formaldehyde and i-butyraldehyde by using triethylamine as catalyst was studied.

以异丁醛和甲醛为原料，三乙胺为催化剂，羟醛缩合法合成了2，2-二甲基－3-羟基丙醛。

Furthermore, the main volatiles rom Hippophae rhamnoides included Nonane, Octane, 3-methyl-1-Butanol, Pentanal, 2-methyl- Butanal, 2-Hexen-1-ol, 2-Hexenyl benzoate in close natural state.

在近自然状态下，壬烷、辛烷、3-甲基丁醇、戊醛、2-甲基丁醛、2-壬烯醇、2-苯甲酸叶醇酯为沙棘枝叶主要挥发物组分。

The conversion of isobutyraldehyde and the selectivity to 2,4,6-triisopropyl-1,3,5-trioxane were 91.1% and 99.8% respectively under optimum reaction condition isobutyraldehyde 25.0 g, [Et3NH]Cl/FeCl3 ( x (FeCl3)＝0.62 1.0 g, 25 ℃ for 1 h .

在最佳的反应条件下（异丁醛25.0 g， [Et3NH]Cl/FeCl3 x (FeCl3=0.62 1.0 g， 25 °C，N2保护下反应1 h，异丁醛的转化率为91.1%，对2，4，6-三异丙基-1，3，5-三氧噁烷的选择性达99.8%。

Chiral 3 methy 1,4 butanediol and its derivatives are the important intermediate of synthesis of chiral smectic liquid crystal polyesters and chiral natrual products with biological activity. In the paper, a new efficient route of 3 methyl 1,4 butanediol and its two derivatives, 2 methyl 4 tetrapyranyloxy 1 butanol and 2 methyl 4 tetrapyranylbutanal, was described, and the target products were synthesized by employing asymmetric hydroboration oxidation improved.

手性2－甲基－1，4－丁二醇及其衍生物是合成各种手性近晶型液晶材料以及手性天然生物活性物质的重要中间体，以3－甲基－3－丁烯－1－醇为原料利用改进的不对称硼氢化－氧化反应，成功地合成了－2－甲基－1，4－丁二醇以及其2种手性衍生物：－2－甲基－4－四氢吡喃氧基－1－醇和－2－甲基－4－四氢吡喃氧基丁醛。

I can not make it blossom and suits me

我不能让树为我开花

When temperatures are above approximately 80 °C discolouration of the raceways or rolling elements is a frequent feature.

当温度高于 80 °C 左右时，滚道或滚动元件褪色是很常见的特征。