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Whenpyridine was used as reductive decomposing agent, the expecting cholest-4-en-3,6-dione-22-al was obtained. However, when Zn/HOAc was used to decomposethe ozonide, C-4,5 double bond was further reduced to give cholest-3,6-dione-22-al as main product. 2 For the side-chain construction of compound (1), the solid-liquid phase-transfer Wittig reaction was used. When (3-methyl-2-oxobutyl)-triphenylarsonium bromide was used as reagent, the reaction can be carried out inmild reaction condition and the yield is higher than that when phosphorane wasused.

但使用Zn/HOAc作为分解剂时,却得到其氢化产物胆甾-3, 6-二酮-22-醛;2在甾体支链引入过程中,采用固-液相转移Wittig反应的方法,用(3-甲基)-2-氧丁基三苯基溴化胂作为试剂,反应在非常温和的条件下便可完成,而且产率比传统采用膦烷的方法更高;3在对某些甾酮化合物的选择性还原反应研究时,发现在〓还原体系中,当加入某些金属离子后,反应有更好的区域选择性和立体选择性。

II. construction scale: annual treatment capacity of 15 thousand tons castor seeds to extract 7 thousand tons oil, annual yield of 7 thousand tons methyl ricinoleate, 2 thousand tons nylon 11 and 3.5 thousand tons castor oil fatty alcohol; along with the following by-products: 1.4 thousand tons medicinal glycerol, and 5 thousand tons of heptaldehyde alcohol, mono-octyl sebacate and dibutyl sebacate respectively.

二、项目建设规模:年处理l.5万吨蓖麻籽、榨油0.7万吨、年产蓖麻酸甲酯0.7万吨、0.2万吨尼龙11和0.35万吨蓖麻油脂肪醇;副产品药用甘油0.14万吨、庚醛醇、癸二酸辛酯和癸二酸二丁酯各0.5万吨。

When SiO〓-NH〓-Rh-Co complex was used to catalyze the hydroformylation of methyl methacrylate, an optimal conversion of 93.4% and optimal selectivity of 84.4% for the normal aldehyde were both obtained at Rh/Co ratio of 2/1, which were both higher than that catalyzed by SiO〓-SiNH〓-Rh and SiO〓-Si-NH〓-Co momometallic catalysts. Clearly a synergistic action between Rh and Co atoms presented in the complex.

我们以SiO〓-Si-NH〓-Rh-Co催化甲基丙烯酸甲酯的醛化反应,当催化剂中Rh/Co比为2/1时,催化活性最高,可达93.4%,对正构产物β-甲酰异丁酸酯的选择性达到84.4%,都高于单金属催化剂,表明了金属间存在相互作用。

Experimental wastewater was composed of glucose and potassium sorbate wastewater.

废水的组成包括丁烯醛、山梨酸、山梨酸钾以及生产过程的载液、丙酮、醋酸、乙醇、甲醇等。

The effects of the food additive butylated hydroxyanisole and the antibiotic Norfloxacin on swordtail fish were measured by considering a number of parameters, including glutathione S\|transferase, catalase, 7-ethoxyresorufin-o-dealkylases and malondialdehyde contents.

研究了叔丁基对羟基茴香醚(butylated hydroxyanisole, BHA)和诺氟沙星(norfloxacin, NFLX)对剑尾鱼的急性毒性及其肝脏谷胱甘肽硫转移酶、丙二醛、过氧化氢酶及7-乙氧基异吩恶唑酮-脱乙基酶活性的影响。

Seven central depressants,including chloral hydrate,potassium bromide,sodium bromide,cal- cium bromide,alcohol,amytal and chloretone, were studied for their effects on the intraperito- neal toxicity of tartar emetic and sodium stibo- gluconate in mice.

1。关于吐酒石与葡萄糖酸锑 V 钠对小白鼠的致死作用,我们探索了一些中枢抑制药与兴奋药的影响。所试的抑制药有水合氯醛,溴化钾,溴化钠,溴化钙,酒精,安眠妥与三氯叔丁醇七种。兴奋药有苯甲酸钠咖啡硷与士的宁二种,以及溴咖合剂。2。

It shown that PDC does not only catalyze the production of acetaldehyde (PDC's main activity), but also catalyzes an aldoltype condensation reaction in which the hydroxyethyl-ThDP intermediate of enzyme is condensed with a second acetaldehyde to form acetoin.

在研究中发现PDC不仅能催化产生乙醛,还具有醛连接酶的活性。即将二个乙醛分子缩合成3-羟基丁酮,尽管这个活性比产生乙醛的活性低得多。

It manufactures heterocyclic, such as pyrazine, thiazole, furan, pyridine and sulf-compounds with their ramifications; and pharmaceutical intermediates such as veratraldehyde, isovanillin, sufurol, diacetyl, acetoin, and 2, 5-dimethyl pyrazine.

食用产品有吡嗪、噻唑、呋喃、吡啶等杂环系列及含硫系列的合成香料化合物。医药中间体产品有:藜芦醛、异香兰素、硫噻唑、丁二酮、乙偶姻、2,5-二甲基吡嗪等。

Methods:GroupⅠ:fresh bovine pericardium was acellularized with Courtman's method and fixed with glutaraldehyde;GroupⅡ:first treated as GroupⅠ,then was modified with2,3-butanediol.

方法Ⅰ组新鲜牛心包片经Courtuman法脱细胞后用戊二醛(GA固定;Ⅱ组脱细胞及固定方法同Ⅰ组,随后用2,3丁二醇改性。

With the increase of crotonaldehyde, the conversion and rapid of copolymerization decrease.

随丁烯醛在单体中比列的增加,共聚合反应转化率和聚合速率均下降。

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你知道吗,我需要你回来

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Chapter Three: Type classification of DE structure in Sino-Tibetan languages.

第三章汉藏语&的&字结构的类型划分。