丁醛

Acetaldehyde generated from the 2 - butene aldehyde carbonyl and the reaction is the condensation of methylene ...

由乙醛生成2－丁烯醛的反应是羰基与亚甲基发生缩合的。。。

Anisaldehyde was synthesized from p-hydroxybenzaldehyde with dimethyl carbonate by microwave irradiation under phase transfer catalyst tetrabutylammonium bromide, The effect of power, time, solvent and catalyst of reaction on yield were researched.

以四丁基溴化铵为相转移催化剂，采用对羟基苯甲醛和碳酸二甲酯为原料，微波辐射下合成大茴香醛。考察了反应溶剂、功率、时间和催化剂对反应产率的影响。

UV 254nm, 366nm and anisaldehyde as a chromogenic agent were used for detecting compounds of these strains. Results indicate that the metabolites of these strains were the most abundant when these strains were fermented in No.1 and No.4 media, and only few in No.2 and No.3. Metabolites of each strain were different in different media.

实验结果表明，用1号和4号培养基发酵产生的次生代谢产物的种类最丰富，2号和3号培养基产生的较少；用II号展层系统(氯仿∶甲醇=4∶1)和III号展层系统(正丁醇∶乙酸∶水=4∶1∶5)作TLC层析，检测到的产物最多；3种检测方法以茴香醛检测到的代谢产物最丰富。

Firstly, 24 chiral Schiff base ligands were prepared and evaluated for theasymmetric HDA reaction between Brassard diene with benzaldehyde. Theresults revealed that the ligand derived from 3,5-di-tert-butylsalicylaldehydewith (1R,2S)-2-amino-1,2-diphenyl-1-ethanol shows an excellent chiralinduction in the reaction.

首先合成了 24 个手性三齿席夫碱配体，并应用于 Brassard 二烯与苯甲醛的不对称 Hetero-Diels-Alder 反应，结果表明，3，5-二叔丁基水杨醛与(1R，2S)-1，2-二苯基-2-氨基-乙醇生成的单席夫碱显示出优秀的手性诱导能力。

Herein, we report the enantioselective total syntheses of slagenins A-C and their antipodes. Starting from readily available ethyl -4-chloro-3-hydroxy-butanonate, elongation of the carbon chain with diazomethane, followed by oxidation of the given α-diazoketone using distilled DMD, afforded a key intermediate α-ketoaldehyde .

本文从方便易得的-4-氯-3-羟基-丁酸乙酯出发，经重氮甲烷延伸碳连、DMD氧化相应的α-重氮酮，制得α-酮醛；该化合物与尿素在氢氟酸作用下，以协同方式非对映选择性的直接构建了cis-四氢呋喃并[2，3-d]咪唑啉-2-酮双环结构，进而合成了天然产物slagenins A、B、和C的对映体。

Experimental process: jing and 3- methyl -2- methyl ethyl ketonesynthesizes by the benzene zong; Again the glacial acetic acidcatalysis produces 2, 3, 3 - trimethyl - 3H - yinduo; Again has thealkylate response production yinduo iodide after the methyl iodide;The iodide takes off molecular HI under NaOH to become freejier thealkali; Adds 5 - nitryls salicylic aldehydes in the ethyl alcohol forthe solvent under if to respond finally produces 6 '- the nitryl yinduolin spiral benzene and pinan; Through the infrared spectrum andthe ultimate analysis irrevocably proved its structure, and studiedthe annulus with to open the annulus the light to send changes colorthe performance, explained in different solvent medium ultravioletabsorption spectrometry solvent effect, and the comparisondiscoloration the response speed number difference, finally mixed itadds to the methyl methacrylate, the peroxidation benzoin formyl in the plexiglass, tested 6 '- the nitryl yinduolin spiralbenzene and pinan in the glass fatigue resistance, thethermostability.

实验过程：由苯肼和3-甲基-2-丁酮合成腙；再冰醋酸催化生成2 ，3 ，3—三甲基—3H—吲哚；再经过碘甲烷发生烷基化反应生成吲哚碘化物；碘化物在NaOH下脱去一分子HI成为费歇尔碱；在乙醇为溶剂下加5－硝基水杨醛与其反应最后生成6'—硝基吲哚啉螺苯并吡喃；通过红外光谱和元素分析确证其结构，并研究了环体与开环体的光致变色性能，解释了在不同溶剂介质中紫外吸收光谱的溶剂效应，并比较褪色反应速率数的差异，最后将其掺加到甲基丙烯酸甲酯，过氧化二苯甲酰有机玻璃中，测试6'—硝基吲哚啉螺苯并吡喃在玻璃中的抗疲劳性、热稳定性。

In continuation of previous experiments ,the reaction of aromatic aldehydes with t-butyl hypochlorite was studied.

在前一试验的继续中，有t-丁基次氯酸盐was的芳香的醛的反应学习。

The catalyst on calcination temperature of 400℃ had the highest conversion of isobutylene and the catalyst on calcination temperature of 500℃ had the highest selectivity of methacrolein .

焙烧温度为400℃的催化剂异丁烯的转化率最高，焙烧温度为500℃的催化剂甲基丙烯醛的选择性最高。

The molybdenum-based multiphasic oxide catalysts were prepared and tested in the selective oxidation of isobutylene to methacrolein reaction.

研究了添加不同助剂对钼基复合氧化物催化剂对异丁烯选择性氧化制备甲基丙烯醛反应的影响。

It is indicated by the results that using butanol,butanol residue and octene aldehyde residue as the extracting agent,the treatment of butanol wastewater will get a good result with the COD removed to be 83%～94%,u...

实验结果表明：以辛醇、辛醇残液和辛烯醛残液作为萃取剂，在废水pH值为1~3、萃取剂与废水的体积比为1∶(1~12)、温度为25~60℃条件下，对丁辛醇废水进行萃取处理，均可得到较好的处理效果，COD去除率可达83%~94%。

Do you know, i need you to come back

你知道吗，我需要你回来

Yang yinshu、Wang xiangsheng、Li decang,The first discovery of haemaphysalis conicinna.

1〕 杨银书，王祥生，李德昌。安徽省首次发现嗜群血蜱。