丁醛

The author has studied the kinetics of hydrogenation of a,β-unsaturated aldehydes andketones such as cinnamaldehyde and 2-butylene cyclopentanone,β-ionone over amorphousalloy NiB catalyst at atmospheric pressure of H2 as well as effects of reaction conditions onthe kinetics.

作者以肉桂醛和2-亚丁基环戊酮、β-紫罗兰酮为代表重点研究了非晶态NiB催化α，β-不饱和醛酮常压下选择加氢的反应动力学。常压下该反应是准一级反应。

The invention discloses a method for synthesizing acetyl tributyl citrate, which uses tributyl citrate and acetic anhydride as reaction articles, uses naphthalenesulfonic acid methylal as the catalyst during the ester synthesis process, filtering the catalyst from reacted articles after reaction, water-washing, alkaline-washing, distilling the filtrate to obatin acetyl tributyl citrate.

本发明公开了一种合成乙酰柠檬酸三丁酯的方法，它以柠檬酸三丁酯、乙酸酐为反应物，在酯合成过程中用萘磺酸甲缩醛作催化剂，反应结束后，将催化剂从反应后的物料中过滤出来，滤液经水洗、碱洗、蒸馏获得乙酰柠檬酸三丁酯。

In the synthesis process of ligands and their rare earth complexes, metal lithium is used to substitute for n-butyllithium, such as the synthesis of fluorenyl lithium, piperonal dimethyl acetal lithium, and bis (9-fluorenyl) silylene lithium.

合成配体和配合物的中间体均采用金属锂代替正丁基锂，如芴锂、溴代胡椒醛二甲基缩醛基锂盐、甲基苯基双芴基硅烷双锂盐的制备，方法简单，操作简便，副反应少，且锂盐的浓度和用量易于控制。

We used the reported chiral ligand QD-4 derived from quinidine to catalyze the reaction of aldehydes and methyl vinyl ketone in the presence of various additives and found that the highest e.

用喹尼叮衍生物QD-4分别催化醛和丁烯酮以及醛和丙烯酸-萘酚酯的不对称Baylis-Hillman反应，通过改变添加剂和优化反应条件，最终分别取得了最高为49％和70％的e.e值。

The results showed that there were 8 kinds of aliphatic, 5 kinds of esters, 2 kinds of aldehydes, 2 kinds of nitrogen sulfur heterocyclic rings and one kind of hydrocarbon, alcoholics, ketone, lactones respectively in the analyzed 21 kinds of aroma components, and the content of furfural,β-methyl valeric acid, palmitic acid, nicotine, neohytadiene were higher, next were acetyl ethyl propionate, caleric acid, phenyl ethyl acetate, hydroxylic diethyl succinate.

结果表明，在分析出的21种香气成分中，分别有脂肪酸类8种，酯类5种，醛类2种，氮硫杂环类2种，烃类、醇类、酮类、内酯类各l种，其中相对含量较高的物质成分是糠醛、β-甲基戊酸、十六碳酸、烟碱、新植二烯，其次是乙酰丙酸乙酯、异戊酸、苯乙酸乙酯、羟基丁二酸二乙酯等。

Methods for calculating the acetalization degree and the ratio of 1,2-and 1,4-additions according to the results of chemical analysis have also been suggested.

还提出了根据化学分析结果计算聚乙烯醇缩丁烯醛的缩醛度以及这两种加成方式的分率的方法。

The increasing of crosslinking extent in polyvinyl butenal had more contribution to adhesive strength of its aqueous solution than enhance of the acetalization degree.

在聚乙烯醇缩丁烯醛中发现，交联程度的提高比缩醛度的提高对其水溶液粘接强度的影响更大。

This mechanism is different from that for the acetalization reaction of polyvinyl alcohol with saturated aldehydes,which has only 1,2-addition.Crosslinking in polyvinyl butenal was mainly resulted from the 1,4-addition.

此机理不同于只有1，2-加成方式的聚乙烯醇缩饱和醛化反应。1，4-加成主要导致聚乙烯醇缩丁烯醛的交联。

Water,butylene glycol,biosaccharide gum-1,ppg-26-buteth-26,panthenol,peg-40 hydrogenated caster oil,hydroxyethylcellulose,imidazolidinyl urea,saccharide isomerate,benzophenone-4,phenoxyethanol,triethanolamine,citrus aurantium dulcisoil,pentadecalactone,methylparaben,sodium hyaluronate,citric acid,butylparaben,ethylparaben,citrus aurantium amaraoil,propylparaben,methylchloroisothiazolinone,methylisothiazolinone,red 4,yellow 5,red 33,limonene,linalool

水，丁二醇，多醣物质，PPG-26-丁醇聚醚-26，维生素B5，PEG-40氢化蓖麻油，羟乙基纤维素，尿素醛，天然异构寡糖，二苯甲酮- 4，苯氧乙醇，三乙醇胺，甜橙油，环十五内酯，羟苯甲酯，透明质酸钠，柠檬酸，羟苯丁酯，羟苯乙酯，苦橙油，羟苯丙酯，甲基氯异塞唑晽酮，甲基异噻唑啉酮，红4，黄5，红33，柠檬精油，芳樟醇

When there were two kinds of active sites with different properties, isobutene were formed on one kind of active site, and then, spilled over to the other active sites, reacting to MAL, isobutene forming as the final product was restrained, and the oxygenates yield was increased.

当催化剂表面存在相邻的两种化学性质不同活性位时，异丁烷在一种活性位上生成异丁烯后，异丁烯可能在催化剂表面迁移到另一种活性位上，继续反应生成甲基丙烯醛或甲基丙烯酸，这抑制了异丁烯作为产物从反应器中流出，并提高含氧有机物收率。

Do you know, i need you to come back

你知道吗，我需要你回来

Yang yinshu、Wang xiangsheng、Li decang,The first discovery of haemaphysalis conicinna.

1〕 杨银书，王祥生，李德昌。安徽省首次发现嗜群血蜱。