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The dibutyltin arylcarboxylates not only displayed a good acaricidal activity, but also showed certain fungicidal activity.

1二丁基-锡羧酸酯具有较好的杀螨活性和一定的杀菌活性。

The products obtained by reacting titanium butoxide with acetylacetone were used as the titanium precursor.

采用钛酸丁酯和乙酰丙酮作用后的产物作为钛的前驱体,水热法一步合成出了 Ti-SBA-15分子筛。

The E-TOF will also be feasible and practical to assist chemists in screening the optimal reaction condition or evaluating the overall efficiency of different catalytic systems for a specific asymmetric reaction.4.For the first time,we explored chiralγ-hydroxy-α,β-acetylenic esters,which were prepared via asymmetric alkynylation,as key intermediates to the synthesis of chiralγ-butyrolactones. This convergent and enantioselective approach to chiralγ-butyrolactones is practical and easily handled with protecting group free.

这一概念包括反应产率、对映选择性、配体用量以及反应时间四个重要反应参数,不仅适用同一反应不同催化体系的横向综合性评价,而且适用于某一特定反应催化体系的优化过程,有助于研究人员选择最佳的反应条件。4、我们发展了以手性γ-羟基-α,β-炔酸酯为关键中间体完成了手性γ-丁内酯类天然产物的对映立体选择性全合成,该关键中间体能够以我们的催化体系方便的对映选择性合成,之后的官能团转换方法成熟,易于操作,无需进行繁琐的官能团保护和脱保护过程,绿色经济。

A method to synthsis a - methylene - r - butyrolactones was reported by the substituted (a - carbethoxyvinyl) cuprate intermediates, generated by the addition of higer order cuprate to acetylenic ester,traping with epoxides stereoselectively.

本文报道了通过以高序铜代替低序铜对炔酸酯加成得到的取代铜与端基或环状环氧化合物的立体选择性反应,较高产率的合成α,β-取代烯酯,进而可合成α-亚烷基-γ-丁内酯类衍生物。

The catalytic system composed of NHPI and transition metal ion can catalyze effectively ethane into acetic acid,cyclane into dicarboxylic acid,toluene into benzoic acid,alkene into epoxide,alkyne into acetylenic ketone,and amide into imide;NHPI used alone can catalyze adamantane to be carbonylated,hydrogen peroxide prepared by oxidization alcohol;NHPI combined with as...

NHPI与过渡金属离子组成的催化体系能高效地催化乙烷氧化为乙酸、环烷烃氧化为二元羧酸、甲苯氧化为苯甲酸、烯烃氧化为环氧化物、炔烃氧化为炔酮、酰胺氧化为酰亚胺;NHPI单独使用能催化金刚烷发生氧化羰基化反应、催化氧化醇制取过氧化氢;NHPI与有机助催化剂如偶氮二异丁腈、溴化季铵盐、蒽醌和醇等也能催化分子氧氧化反应。

The yield of succinic acid increases by 25 g/L and the strain Actinobacillus succinogenes HF-7 has good application of industrial fermentation.

代谢工艺的优化将丁二酸的产量提高了约25 g/L,使得菌株具有进一步的工业应用潜力。

Actinobacillus succinogenes is a promising candidate for the production of bio-based succinic acid.

琥珀酸放线杆菌是发酵生产有应用前景的生物基原料-丁二酸的微生物。

The effect of redox potential regulation on metabolite flux distribution of Actinobacillus succinogenes NJ113 was studied by using the metabolic flux analysis method.

利用代谢通量分析方法分析了氧化还原电位调控对产琥珀酸放线杆菌NJ113厌氧发酵产丁二酸过程的影响。

Alkenyl succinic acidas an anti-rust additive is generally used in steam turbine oil .

分别测定了含烯基丁二酸的汽轮机油/蒸馏水及汽轮机油/合成海水体系的界面张力、界面剪切粘度、油相粘度及乳状液稳定性。

The precursor solutions of titanium alkoxide with different amount of AcAc were characterized by DTA to study the chelating process of titanium alkoxide with AcAc.

对含有不同量乙酰丙酮的前驱体溶液做了热重分析,研究了钛酸丁酯与乙酰丙酮的螯合过程。

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