丁胺

In this thesis, we developed chiral proton N-O type ligands and employed them in the enantioselective addition of diethylzinc to N-diphenylphosphinoyl imines. The relationship between the structure of the ligands and the enantioselectivity was systematically studied. Furthermore, enantioselective butylation of N-diphenylphosphinoyl imines withBu〓Zn and enantioselective diphenylzinc addition to imine were also examined.

本文致力于亚胺的不对称催化有机锌试剂加成反应的研究：以手性质子型N-O配体为促进剂，对N-二苯基次膦酰亚胺进行不对称乙基锌加成反应而展开研究工作，系统地考查了手性配体的结构对反应的影响；另外，对N-二苯基次膦酰亚胺的不对称催化丁基锌加成进行了研究，并首次对亚胺的不对称苯基锌加成反应进行了初步探索。

The hybrid composite PW11Co/PAMAM was characterized by FT-IR, UV-Vis diffuse reflectance spectra, XPS, XRD and TG/DTA, indicating that the PW11Co was chemically anchored to PAMAM. The morphologies of the title composite were characterized by scanning electron microscopy and transmission electron microscopy. The catalytic activity was evaluated by oxidation of isobutyraldehyde to isobutyric acid in MeCN under mild conditions (20 ℃, ambient pressure), showing that the title compound is a more effective and recoverable catalyst than corresponding PW11Co.

通过FT-IR、DR-UV-Vis、XRD、TEM、SEM、TG/DTA等手段对其进行了表征，并考察了其对异丁醛转化异丁酸的催化活性，实验结果表明，多金属氧酸盐通过配位键与聚酰胺-胺作用形成的无机-有机复合物可望成为一种催化活性高且易于分离和重复使用的多相催化剂。

N,N '- ditertbutyl nitroxyl radical, 2, 2,6,6- tetramethyl-4 - hydroxyl piperdinehy droxylamine and its nitroxyl radical, as inhibitors of the BPO- initiated copolymerization of styrene (M 1 ) with acrylonitrile (M2 ), at 60℃,has been studied.

研究了二叔丁基羟胺，二叔丁基氮氧自由基，2，2，6，6－四甲基－4－羟基哌啶羟胺和2，2，6，6－四甲基－4－羟基哌啶－1－氧自由基对过氧化苯甲酰60℃引发的苯乙烯（M1）－丙烯腈（M2）共聚合的阻聚行为。

Poly（p-vinylbenzyl succinimide） resin,which can be abbreviated to succinimide resin,was prepared by the reaction of chloromethylated polystyrene with succinimide in the presence of base. The succinimide resin was characterized by diffuse reflectance infrared Fourier transform spectrometry and elemental analysis.

摘 要：在碱性条件下，氯甲基化聚苯乙烯与丁二酰亚胺反应合成了聚（对乙烯基苄基丁二酰亚胺）树脂，采用元素分析、红外光谱对合成树脂的组成进行了表征。

But the electrochemical results show that complexes exhibitcompletely irreversible redox behaviour which is different from thatfound in diiron proteins. 1.3 To obtain the diiron species which are stable to elec-trochemical reduction, a series of new tetranuclear cage ironspecies containing two 〓 cores, with using hexadentatepolybenzimidazole ligands, were synthesized and characterized by vari-ous spectroscopic methods. Their physical properties have been investi-gated. The crystal structures of 〓〓tetrakis (benzimidazol-2-ylmethyl)-1, 4-diaminobutane and 〓,〓-tetrakis ( N-ethylbenzimidazol-2-ylmethyl )-1, 4-diaminobutane were determined. They contain two 〓 cores which arelinked to each other by -〓-chain in the ligands.

1.3为了获得电化学还原稳定双核氧桥联Fe化合物，使用六齿配体合成了一系列含有两个〓单元四核笼状化合物，并用各种谱学手段表征了它们，还研究了它们的物理化学性质确定了〓L=N，N，N'，N'-四(苯骈咪唑基-1，4-丁二胺和〓，〓四-1，4-丁二胺化合物的晶体结构，它们含有两个〓单元，其中两个〓单元是通过配体的〓链桥联成四核笼状结构。

According to the synergistic effects of weed control and the inhibited availability to ammonifying becteria and actinomycetes while herbicides were used with urea mixture, that has formulated a wettable powder of butachlor+londax and a granular of butachlor + londax + urea.

根据除草剂和尿素混用的杀草增效作用和对氨化细菌和放线菌的抑制作用，创制了丁草胺+农得时可湿性粉剂和丁草胺+农得时+尿素颗粒剂。

Two series of polyurethane acrylate grafted acrylic resins (Acr-g-TPU-PETA and Acr-gPPU-PETA) self-emulsifying systems are obtained by grafting -NCO group modified polyurethane acrylates with acrylic copolymer prepared from n-butyl acrylate, styrene,βhydroxyethyl methacrylate and acrylic acid The self-emulsifying systems showed Newtonian fluidity with viscosity closed to that of water, the solid contents were around 30% The T〓 of 15～4℃ for dried film before photocuring favored film formation at room temperature DSC and DMA results showed that PU-PETA is compatible with acrylic resin in the grafted resin The TG and dTG curves for Acr-g-PU-PETA samples were substantially different from the corresponding blends, and the brodened dTG peaks for photocured grafted resin suggest that there might be multiple interactions among chain segments The photocued film of the grafted resins self-emulsifying system exhibited good overall properties with polyurethane acrylate grafts ranging from 30% to 50%, and Acr-g-TPU-PETA series showed better properties than Acr-gPPU-PETA series The adhesion of the photocured film was 1～2 grade, impact strength was 50kg-cm and flexibility was 1mm The Shore hardness and the adhesion of the film decreased markedly if PETA was replaced by HEMA as photoactive group due to the lower C=C double bond content in the grafted resin The polyhydroxy amine-linked thioxanthones photoinitiators can be evenly dispersed in self-emulsifying system without color spot appearing in the dried film The films photocured with IV〓～IV〓 generally exhibited higher Shore hardness, gloss and solventresistance than that cured with Irgacure 2959 and did not induce the rusting of the iron substrate Pigmenting with titanium oxide had no effect on the photocuring The polyhydroxy amine-linked thioxanthone IV〓 and IV〓 can be new candidates for the formulation of titanium oxide pigmented photocurable water-borne coatings for their pale-yellow appearance and slight interference with the color of the coatings WB 4759 with high water-solubility coalesced and separated from the dried resin film, and even induced the rusting of iron substrate.

以丙烯酸丁酯，甲基丙烯酸-β-羟乙酯，丙烯酸及苯乙烯合成厂丙烯酸共聚树脂，并与含-NCO端基的聚氨酯丙烯酸酯接枝反应，经水性化后，得到两个系列（Acr-g-TPU-PETA和Acr-g-PPU-PETA）各5个不同配比的丙烯酸树脂接枝聚氨酯丙烯酸酯自乳化体系，粘度与水相近，为牛顿流体，固含量30％左右。光固化前干燥涂膜的玻璃化转变温度在-15℃～4℃之间，有利于室温下成膜。DSC及DMA谱表明两种树脂基本相容。Acr-g-PU-PETA的热失重行为明显不同于共混材料，接枝样dTG峰明显宽化，表明接枝样中链段之间的相互作刚有多重性，丙烯酸树脂与聚氨酯之间有一定的相容性。接枝树脂自乳化体系光固化涂层的综合性能以聚氨酯丙烯酸酯成分为50％～30％者相对较好，且以Acr-g-TPU-PETA系列更理想。光固化膜的附着力为1～2级，冲击强度为50kg·cm，柔软性多为1mm。以HEMA代替PETA作为接枝树脂的活性基团，碳—碳双键密度太低，光固化膜交联点太少，硬度和附着力均较差。多羟基胺连硫杂蒽酮光引发剂能均匀分散于树脂自乳化体系和接枝树脂干膜中，不出现色斑，光固化膜肖氏硬度一般高于以Irgacure 2959为光引发剂的光固化膜，光泽度及耐丁酮溶剂性能均有所提高，不会诱导铁基生锈，钛白着色对光固化结果几乎没有影响。本论文所合成的多羟基胺连硫杂蒽酮光引发剂IV〓与IV〓为浅黄色，对光固化涂层的颜色干扰较小，为配制钛白着色光固化水性涂料提供了新的光引发剂。水溶性太强的WB 4759在干膜中易聚结析出，且对所附着的铁基有诱导锈蚀作用。

Ethambutol is the key intermediate of ethambutol hydrochloride which is used as a chiral antituberculosis agent.

对手性抗结核药物盐酸乙胺丁醇的关键中间体———乙胺丁醇的合成进行了系统研究。

Conclusions］There is a significant difference at protein level between untreated and ethambutol treated mc2155 cells. It suggests that the differential expression analysis of proteomes may be useful for further study on microbiostatic mechanism of ethambutol and search for new targets toward anti-TB drug development.

结论］乙胺丁醇处理前后耻垢分枝杆菌mc2155细胞的蛋白质组具有差异，这种蛋白质组的差异分析有助于进一步研究乙胺丁醇抑制分枝杆菌生长的作用机制并为寻找新的抗结核药物作用靶标奠定基础。

［Objective］To investigate the microbiostatic mechanism of ethambutol, proteomic methods were used to find differential expression proteins in Mycobacterium smegmatis mc2155 cells treated with ethambutol.

［目的］利用蛋白质组学方法，识别乙胺丁醇处理前后耻垢分枝杆菌mc2155细胞后差异表达的蛋白质，为进一步探讨乙胺丁醇抑制分枝杆菌生长的作用机制及寻找新的抗结核药物作用靶标奠定基础。

By the time of its fall, most of the prisoners were writers who had written against the corruptions of the government.

到它被攻陷的时候，里面多数的犯人是写了反对政府贪污文章的作家。

The most obvious variation to ovum morphological character was that the color was changed from light green to sepiaceous in embryonic development, and all the ovums were almost hatched after 96h.

在胚胎发育过程中卵的形态特征最明显的变化是颜色从淡绿到深褐色，卵在发育96h后卵基本全部孵化。