丁烷

A series of dissymmetric Gemini surfactants with the structure ofC_(12H_(25)CH_(3_(2)N~CH_(2_(4)N~CH_(3_(2)C_mH_(2m+1),denoted as C_(12)-4-C_m(m is 14,16,18),have been synthesized with N,N-dimethylalkylamine and 1,4-dibromobutane as the initial reagents.

以N，N-二甲基脂肪胺和1，4-二溴丁烷为原料，合成了一系列具有不同疏水链的不对称Gemini表面活性剂C12H25(CH3)2N+(CH2)4N+(CH3)2CmH2m+1(C12-4-Cm，m=12，14，16，18)，并通过1H NMR、MS和元素分析等方法鉴定其结构。

Progress in dissymmetric Gemini surfactants;2. A series of dissymmetric Gemini surfactants with the structure ofC_(12H_(25)CH_(3_(2)N~CH_(2_(4)N~CH_(3_(2)C_mH_(2m+1),denoted as C_(12)-4-C_m(m is 14,16,18),have been synthesized with N,N-dimethylalkylamine and 1,4-dibromobutane as the initial reagents.

以N，N-二甲基脂肪胺和1，4-二溴丁烷为原料，合成了一系列具有不同疏水链的不对称Gemini表面活性剂C12H25(CH3)2N+(CH2)4N+(CH3)2CmH2m+1(C12-4-Cm，m=12，14，16，18)，并通过1H NMR、MS和元素分析等方法鉴定其结构。

The thermal behaviors of CL-20 mixed with three binders (NC+NC, PET and PBT at 160-200℃ were investigated by NBK LAWA gasometric measuring system. The thermal behaviors were described from the changes of evolved gases and decomposition kinetics. Results show that the apparent activation energies of CL-20 and its mixed systems with, PET and PBT are 176.68, 176.31, 136.12 and 127.0 kJmol^(-1), respectively.

用NBK型&拉瓦&量气测试系统研究了较高温度(160~200℃)下六硝基六氮杂异伍兹烷(CL-20)与硝化棉和硝化甘油双基吸收药、环氧乙烷与四氢呋喃共聚醚、3，3-双叠氮甲基氧杂环丁烷与四氢呋喃共聚物三种黏合剂的全分解过程，从放气规律和动力学的变化阐述了CL-20及其与三种黏合剂混合体系的热行为。

Research on the Over critical and Overflow at Variable Conditions of Marine Steam Turbine;2. Strongly total domination edge critical graphs;3. This paper measures the critical energy of detonation of hydrocarbon fuel(butane,naphtha,pentene,hexene,JC5) and air mixtures using Bruceton method in the rectangular shock tube.

该文在矩形激波管内采用布鲁塞顿法测定了丁烷、石脑油、戊烯、己烯、JC5等碳氢燃料与空气混合物形成爆轰时所需的临界起爆能，并根据所测定的临界起爆能的大小，分析比较了这几种碳氢燃料的相对爆轰敏感度及相应的安全性能，最后讨论了分子量，分子中键的饱和度和分子结构等因素对碳氢燃料临界起爆能及相应的安全性能的影响。

This paper measures the critical energy of detonation of hydrocarbon fuel(butane,naphtha,pentene,hexene,JC5) and air mixtures using Bruceton method in the rectangular shock tube.

该文在矩形激波管内采用布鲁塞顿法测定了丁烷、石脑油、戊烯、己烯、JC5等碳氢燃料与空气混合物形成爆轰时所需的临界起爆能，并根据所测定的临界起爆能的大小，分析比较了这几种碳氢燃料的相对爆轰敏感度及相应的安全性能，最后讨论了分子量，分子中键的饱和度和分子结构等因素对碳氢燃料临界起爆能及相应的安全性能的影响。

These compounds are of substantial interest both inviewpoints of theory and practical applications, mainlyunder the stimulus to achieve synthetic models either foractive sites of iron-sulfur proteins or for transitionmetal catalysts. This thesis describes the synthesis, structures andconformations of 51 new iron-sulfur cluster complexes,which have been characterized by elemental analysis andstandard spectroscopic methods. In addition, single-crystalX-ray diffraction analyses were performed for 4 representa-tive new compounds. Reactivities of μ-〓 with mono- and di- Grig-nard reagents derived intermediates toward various organicelectrophilic substrates were studied, along with complexa-tion of arynyl-containing iron-sulfur clusters by 〓Thus, several bridged, non-bridged, monomeric, dimeric,homonuclear, heteronuclear iron-sullfur and iron-sulfur co-balt-carbon cluster complexes were synthesized. A novelreaction and convenient route for the synthesis in highyield of tetranuclear iron complexes 〓 containing atetracoordinated sulfur atom was discovered, whereas aplausible mechanism based on experimental results was propo-sed for the formation of the new cluster type.

鉴于有机铁硫原子簇化学在基础理论发展和应用方面的重要意义，因此我们开展了这一课题的研究，并取得以下主要成果： 1、本文共合成了51个新有机铁硫及含钴碳簇基的有机铁硫原子簇配合物，除用元素分析，NMR，IR，MS法表征其结构和构象外，还用X-光衍射技术测得四个代表性配合物的单晶结构和构象； 2、我们业已发现炔基Grignard试剂同〓可形成一种&开环&与&闭环&中间物的平衡混合物，研究该平衡混合物同各种亲电试剂的反应； 3、研究发现了一种可高产率地形成〓含〓四配位硫挛合簇的新化学反应并对此反应提出了—种有趣的反应机理； 4、首次由1，4-二溴丁烷双Grignard试剂与〓制得一种新型铁硫簇双硫阴离子活性中间体，并进而研究了它的亲核反应性能； 5、找到了通过〓的光化学反应来合成簇合物〓-〓的一条有实用价值的新路线。

Butyl bromide was synthesized from hydrobromic acid(48%) and 2-butylalcohol by adding concentrated sulfuric acid.

以质量分数为48%的氢溴酸水溶液、仲丁醇为反应原料，浓硫酸为催化剂合成仲溴丁烷，考察了反应原料和催化剂用量以及反应时间对产率的影响。

N-butanol was prepared with bromine and hydrobromic acid in the laboratory.

实验室制备正溴丁烷是用正丁醇与氢溴酸反应制备。

Adsorption isotherms of propane, butane, propane and liquified petroleum gas on the quartz beads were determined respectively by means of the method of vacuum weighing , and the relationship between the isosteric adsorption enthalpy change and adsorbance was also reported.

用石英玻璃微珠模拟了HP－1，HP－20M，HP－17毛细管色谱柱内壁，用真空重量法测定了丙烷、丁烷、丙烯、液化石油气样品在3种模拟毛细管内壁表面的吸附等温线，并计算了等量吸附热随吸附量的变化关系。

The heptanal butyl mercaptal was synthesized with heptanal, sodium thiosuifate and 1bromobutane as raw materials.

以正庚醛、硫代硫酸钠和溴代正丁烷为原料，合成了正庚醛正丁硫醇缩醛。

The concept of equivalent rotationally rigidity is offered and the formula of rotationally rigidity is obtained.

主要做了如下几个方面的工作：对伸臂位于顶部的单层框架—筒体模型进行分析，提出了等效转动约束的概念和转动约束刚度的表达式。

Male cats normally do not need aftercare with the exception of the night after the anesthetic.

男猫通常不需要善后除了晚上的麻醉。