丁烷

The one electron oxidative splitting reaction mechanism between 9,10-anthraquinone-2-sulfonate and cyclobutane dimethylthymine dimer was acquired.

研究了蒽醌-2-磺酸盐与环丁烷型二甲基胸腺嘧啶二聚体发生的单电子氧化裂解反应机理。

DATA SYNTHESIS: With the increase of ultraviolet radiation caused by environmental pollution, DNA in human epidermal cells is damaged. Cyclobutane pyrimidine dimmer and 6-4 photoproducts are the main forms of DNA lesions.

资料综合：环境污染使得紫外辐射增强，而紫外线辐射对机体表皮细胞的DNA具有损害作用，可导致环丁烷嘧啶二聚体和6-4光产物的形成。

Cyclobutane exists predominantly in a "butterfly" conformation .

环丁烷主要成&蝶式&构象存在。

For Teflon PCB, pyrolysis gas contained high concentration of octafluoro- cyclobutane and low concentration of small molecular fluorocarbon-hydrogen compounds.

Teflon热解气体产物主要为八氟环丁烷以及其他小分子碳氟氢烷烃化合物。

Objective To observe the production and removal of photo-product, cyclobutane pyrimidine dimers, in HaCaT cells induced by UVB irradiation and intervention effect of ligustrazine, and to investigate its photo-protective mechanisms on HaCaT cells damaged from UVB irradiation.

目的观察中波紫外线辐射后永生化角质形成细胞株中光产物环丁烷嘧啶二聚体的产生和清除情况，观察川芎嗪对UVB辐射后细胞光产物的影响并探讨其保护作用机制。

UV-B radiation during the cell cycle induced accumulation of cyclobutane pyrimidine dimers.

单细胞凝胶电泳检测结果表明，UV-B辐射引起拟南芥根尖细胞内积累大量的环丁烷嘧啶二聚体。

Ozone College depletion in stratosphere has led to the increase of solar UV-B radiation reaching to the earth surface, which would damage DNA of plant epidermal cells and produce cyclobutane pyrimidine dimmers (CPD and 6-4 photoproducts.

臭氧衰减导致地表紫外辐射增强，而紫外线辐射对植物表皮细胞的DNA具有损害作用，可导致环丁烷嘧啶二聚体和6，4-光产物的形成。

R-1,c-2, t-3, t-4-1,3-bis(4-biphenyl)-2,4-di(4-pyridyl)cyclobutane was obtained in diluted sulfuric acid by photodimerization reaction.

通过反-1-(4-联苯基)-2-(4-吡啶基)乙烯在稀硫酸中的光二聚反应合成了r-1，c-2，t-3，t-4-1，3-双(4-联苯基)-2，4-二(4-吡啶基)环丁烷。

Photoinduced Electron Transfer [2+2] Cycloaddition Reactions ofBenzannelated Isoquinolin-1-ones with Electron Deficient Alkenes Photoinduced [2+2] cycloaddition reactions of 11H-benzoxazolo[3,2-b]isoquinolin-11-one 8 and 11H-benzothiazolo[3,2-b]isoquinolin-11-one 13 with electron deficient alkenessuch as acrylonitrile, methyl acrylate, dimethyl fumarate and dimethyl maleate afforded a group of polycyclic isoquinoline derivatives bearing cyclobutane moieties ingood to excellent yields and resulted in the Schenck isomerization of the alkenes.

3苯并增环异喹啉-1-酮与缺电子烯烃的光诱导电子转移[2+2]环加成反应 11H-苯并恶唑[3，2-b]异喹啉-11-酮8和11H-苯并噻唑[3，2-b]异喹啉-11-酮13与缺电子烯烃如丙烯腈，丙烯酸甲酯，富马酸二甲酯及马来酸二甲酯的光诱导[2+2]环加成反应以高产率给出一系列含有环丁烷结构单元的多环异喹啉衍生物并导致烯烃的Schenck异构化作用。

This dissertation is mainly focused on the reactivity of methylenecyclopropanes and comprises six parts. 1 The reactions of methylenecyclopropanes with phenylsulfenyl chloride, phenylselenyl chloride and diphenyl diselenide; 2 The coupling reactions of the ring-opening products derivated from methylenecyclopropanes; 3 The palladium-catalyzed ring-enlargement of mono-aryl group substituted methylenecyclopropanes to cyclobutenes. 4 The gold-catalyzed domino ring-opening and ring-closing hydroamination of methylenecyclopropanes with sulfonamides; 5 The Lewis acid-catalyzed reactions of mono-aryl group substituted methylenecyclopropanes with diethyl ketomalonate in the presence of water; 6 The iodobenzene diacetate mediated novel 1,3-dipolar cycloaddition of methylenecyclopropanes, vinylidenecyclopropanes, and methylenecyclobutane with phthalhydrazine.

本论文主要研究了亚甲基环丙烷类化合物的一些化学反应性能，共由以下六部分组成：1、亚甲基环丙烷类化合物与苯硫氯、苯硒氯及二苯基二硒的反应；2、亚甲基环丙烷类化合物开环产物的偶联反应；3、单芳基取代的亚甲基环丙烷类化合物在钯催化剂作用下的扩环反应；4、金化合物催化磺酰胺对亚甲基环丙烷类化合物的串联开环关环氨氢化反应；5、路易斯酸催化亚甲基环丙烷类化合物与丙酮二羧酸二乙酯在有水存在下的反应；6、醋酸碘苯促进的亚甲基环丙烷类化合物、亚乙烯基环丙烷类化合物及亚甲基环丁烷类化合物与邻苯二甲酰肼的新型1，3-偶极环加成反应。

I didn't watch TV last night, because it .

昨晚我没有看电视，因为电视机坏了。

Since this year, in a lot of villages of Beijing, TV of elevator liquid crystal was removed.

今年以来，在北京的很多小区里，电梯液晶电视被撤了下来。