丁烯

Catalytic effect of ionic liquids to isobutane and butene alkylate reaction was studied,composition of ionic liquids,isobutane and butene mole compares factors to the alkylate reaction influence was reviewed.

研究了离子液体对异丁烷与正丁烯烷基化反应的催化作用，考察了离子液体组成、异丁烷与正丁烯物质的量比等因素对烷基化反应的影响。

The industrial manufacturing technique, the trend of development of neohexene ,and the characteristics of these production technique were reviewed and analyzed in the paper, particularlyabout the selective dimerization of isobutylene and metathesis of βdiisobutylene with ethylene were introduced.

对新己烯生产技术的现状和今后的发展趋势进行了综述，分析了由异丁烯和乙烯生产新己烯的技术特征，讨论了烯烃二聚工艺和催化剂、烯烃复分解工艺及相应的催化剂，指出了各种工艺的优势和不足。

In the part of preparing HMT, the thesis did research on the preparing process of using isobutylene , 2,3-dimethyl-butene-l , 2,3-dimethyl-butene-2 as the materials respectively .

在中间体合成部分，本文分别对新己烯、2，3—二甲基—丁烯—1、2，3—二甲基—丁烯—2为原料合成HMT的工艺进行了研究，然后利用GC-MS对三种原料合成HMT的主要副产物分别进行了分析。

In the part of preparing HMT, the thesis did research on the preparing process of using isobutylene , 2,3-dimethyl-butene-l , 2,3-dimethyl-butene-2 as the materials respectively .Then using GC-MS , the main outgrowths in each reaction systems were analyzed.

在中间体合成部分，本文分别对新己烯、2，3—二甲基—丁烯—1、2，3—二甲基—丁烯—2为原料合成HMT的工艺进行了研究，然后利用GC-MS对三种原料合成HMT的主要副产物分别进行了分析。

The obtained activation barrier of β-scission of 1-butene is 217 kJmol^(-1) in the reverse reaction of ethene dimerization.

反应的逆过程也就是1-丁烯在酸性分子筛表面的1-丁基烷氧化合物发生B分裂反应，计算所得相应的l-丁烯B分裂反应的能垒为217kJmol^(-1)，远高于相应的乙烯二聚反应能垒。

This item plans to construct 5 thousand t/y Tert - butylamine production equipment which uses internally developed independently isobutene cyanide process for the production of raw materials for pure isobutylene, purity of 99.5% of the domestic production of tert - butylamine.

该装置采用国内自主开发的异丁烯氰化法生产工艺，以纯异丁烯为原料，生产纯度为99.5％的叔丁胺产品。

The results show that isobutene oligomerization is fast liquid-solid reaction. Under the temperature of 80 ℃～120 ℃ and pressure of 2.0 MPa, the products of oligomerization are mainly dimers and trimers of isobutene. The yield of trimers is higher than that of dimers and the mass fraction of trimers decreases with reaction temperature increasing. The yield of tetramers is much lower than that of dimmers and trimers. The tetramers are formed by reaction of isooctenes and C8 carbonium ion.

结果表明，异丁烯齐聚反应为快速液固相催化反应，在80 ℃～120 ℃，2.0 MPa的实验条件下，反应产物主要是异丁烯的二聚物和三聚物，且三聚物的收率远高于二聚物，两者的浓度比值随反应温度的升高而下降；少量四聚物的生成主要源于碳八烯烃与碳八正碳离子的反应。

Niobic acid; catalytic synthesis; di-2-ethylhexyl phthalate; di-n-octyl phthalate; di-2-ethylhexylmaleate; di-n-octyl maleate; cyclohexene; modification of catalyst; dynamics of esterification

工程科技I，化学，有机化学铌酸；催化合成：邻苯二甲酸二辛酷；邻苯二甲酸二异辛酯；顺丁烯二酸二辛酯：顺丁烯二酸二异辛酯：环己烯；改性；动力学

M treatment materials, and also tartaric acid and no maleic acid detected in G. v treatment materials. Inoculation also increased the content of organic acid secretion (increased by 19.80～56.87 mg/kg) of trifoliate root, and the application of AlPO4 greatly increased organic acid content (increased by 20.06～21.84 mg/kg); uninoculated plant root secreted a bit of organic acid; Mycorrhizal poncirus trifoliata seedlings excreted malic acid (42.87%), citric acid (39.22%) and oxalic acid (12.06%).

接种AM真菌的根系分泌的有机酸种类与对照有所不同，未接种处理枳分泌的有机酸有草酸、苹果酸、乳酸、乙酸、顺丁烯二酸和柠檬酸等6种，而接种G.m的则检测到草酸、酒石酸、苹果酸、乳酸、乙酸、柠檬酸、丁二酸等7种，G.v处理的检测到酒石酸，接种处理均未检测到顺丁烯二酸；接种丛枝菌根真菌增加了枳根系分泌有机酸的量比未接种处理增加19.80～56.87 mg/kg，且施用AlPO4后有机酸含量显著增加(增加20.06～21.84 mg/kg；未接种植株根系仅分泌少量有机酸；接种植株根系分泌的有机酸以苹果酸(42.87%)、柠檬酸(39.22%)和草酸(12.06%)为主。

The catalyst for IB dimerization, reactive site, reactive mechanism and dynamics research date was reviewed in this paper and try to explain the mechanism of selectivity enhancing by adding Tertiary butyl alcohol during IB dimerization and provide reference for the study of dimerization afterwards.

本文对异丁烯二聚催化剂、反应活性位、机理及动力学研究成果进行了综述，试图解释在异丁烯二聚时，加入的叔丁醇对二聚反应选择性提高的作用机理，为今后二聚反应的研究提供参考。

For a big chunk of credit-card losses; the number of filings (and thus charge-off rates) would be rising again, whether

年美国个人破产法的一个改动使得破产登记急速下降，而后引起了信用卡大规模的亏损。

Eph. 4:23 And that you be renewed in the spirit of your mind

弗四23 而在你们心思的灵里得以更新