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The molybdenum-based multiphasic oxide catalysts were prepared and tested in the selective oxidation of isobutylene to methacrolein reaction.

研究了添加不同助剂对钼基复合氧化物催化剂对异丁烯选择性氧化制备甲基丙烯醛反应的影响。

The processing route, technology and characteristics of the MTBE unit in Harbin Refinery are presented. The main operation factors, such as catalyst packing and performance, reaction temperature and pressure, and the effects of alcohol/alkene ratio on isobutylene conversion and MTBE quality, are discussed. The problems occurred during production and their solutions are also summarized.

介绍了哈尔滨炼油厂MTBE装置的工艺路线、新技术的应用及特点;催化剂的装填及应用情况;总结了生产过程中遇到的一系列问题及解决办法;探索了平稳生产的新徐径,以保证装置安全、平稳、长周期运行;同时对反应器操作温度、催化蒸馏塔操作压力、原料中醇烯比等因素对异丁烯转化率及MTBE产品的影响做了简单的总结。

In the coupling reaction of 4 with 2-methyl-1-buten-3-yne the four- membered ring ligand is transferred to enyne to give the substituted eta3-butadienyl complex 5 containing the cyclobutenonyl group.

在4与2-甲基-3-炔-1-丁烯进行偶合反应后,四环结构仍然稳固存在,并转移到烯缺上形成一个含有四环结构的错合物5。

The catalytic performance of complex 41 has been investigated.Complex 41 proves to be an excellent catalyst for cross metathesis reaction of 1-butenewith isomerized octadecene.

研究了配合物41催化的1-丁烯与异构化后十八烯的交叉交互置换反应,证明配合物41是性能优良的催化剂。

The overall activation energies of crotonic acid, undecylenic acid and oleic acid systems are 118, 122 and 134 kJ/mol, respectively.

反式丁烯酸、10-十一烯酸、油酸接枝ABS树脂的反应活化能分别为:118、122、134kJ/mol。

In this paper, grafting of crotonic acid, undecylenic acid, oleic acid, and acrylic acid onto acrylonitrile-butadiene-styrene terpolymer were studied. Experimental factors influencing grafting, kinetics and mechanism of grafting, the reactivity of grafted polymer, and the compatibilization effects of grafted ABS on ABS blends were investigated.

本文主要研究反式丁烯酸、10-十一烯酸、油酸、丙烯酸接枝ABS树脂的影响因素、接枝反应机理和动力学、接枝物的反应活性,以及接枝物对ABS共混物的增容作用。

Grafting degree increased with increasing monomer concentration in acrylic acid and crotonic acid systems. In undecylenic acid and oleic acid systems, grafting degree increased with monomer concentration initially but decreased after monomer concentration reaching at 0.30 mol/L.

丙烯酸、反式丁烯酸体系的接枝率随单体浓度的增加而增大。10-十一烯酸、油酸体系的接枝率初始时随单体浓度的增加而增大,单体浓度超过0.30mol/L后,接枝率降低。

Grafting of crotonic acid, undecylenic acid, oleic acid, and acrylic acid onto ABS was initiated by benzoyl peroxide in 1, 2-dichloroethane solution.

以过氧化二苯甲酰为引发剂,在1,2-二氯乙烷溶液中进行反式丁烯酸、10-十一烯酸、油酸、丙烯酸接枝ABS树脂。

OH radicals produced by ultrasound in aqueous solution attack phenolic cycle at adjacent or para position of the hydroxyl on phenol so that phenol is changed into small organic molecules such as muconic acid, maleic acid and ethane diacid. These small organic molecules will be oxidized to form carbon dioxide and water by.

苯酚超声降解的作用机理是,超声空化在水溶液中产生的·OH自由基进攻苯酚苯环上羟基的邻位或对位而使苯环断裂生成己二烯酸、顺式丁烯二酸和乙二酸小分子有机物而使苯酚得以降解,这些小分子有机物在·OH自由基的进一步作用下最终被氧化成CO〓和H〓O。

Use the method that the article determines to authority is worth, methylic to synthesis acrylic acid the course of two kinds of chemical industry of armour ester, namely different butene law (I-C4) and propylene law (C3) undertook green spends evaluation and analysis, make clear I-C4 law course more green.

采用本文确定权值的方法,对合成甲基丙烯酸甲酯的两种化工路线,即异丁烯法(i-C4)和丙烯法(C3)进行了绿色度评价和分析,表明i-C4法路线更为绿色。

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