丁基

Imino-1, 3-thiazetidines is the basic structure of a kind ofbioactive herbicide and insecticide. Our method has advantage in synthesis highly substituted2-imino-1, 3-thiazetidines, therefore it has practical value to some extent. We also researched the reactions catalyze by active zinc dust.

提供了成四员噻吖丁啶杂环衍生物的方法。2-亚胺基-1，3-噻吖丁啶是一类具有生物活性的除草剂及杀虫剂的核心结构，我们的方法在合成多取代的2-亚胺基-1，3-噻吖丁啶方面有一定的优越性，从而具有一定的实用价值本文另一部分的工作是探讨锌粉催化的反应。

Hrough copolymerization of styrene with few quantity of methacrylic acid, maleic anhydrate or 4-vinyl pyridine respectively and of butyl methacrylate with maleic anhydrate, the functional groups carboxyl, simple anhydride and pyridyl have been introduced respectively to the chain of PS or PBma.

通过苯乙烯与少量的甲基丙烯酸、马来酸酐或4—乙烯基吡啶的共聚及甲基丙烯酸正丁酯与马来酸酐的共聚，可在聚苯乙烯及聚甲基丙烯酸丁酯链上分别引入功能基因羧基、酸酐基和吡啶基对共聚物进行了红外光谱、酸碱滴定、元素分析、玻璃化转变温度、粘度及紫外光谱的测定。

Water,c12-20 acid peg-8 ester,octyldodecanol,cetearyl isononanoate,butylene glycol,biosaccaride gum-1,peg-40 hydrogenated caster oil,ethylhexyl menthoxycinnamate,phenoxyethanol,potassium cetyl phosphate,macadamia ternifolia seed oil,dimethicone,carbomer,propylene glycol,glyceryl stearate,cocoglycerides,butyrospermum parkii,c12-13 alkyl lactate,methylparaben,benzophenone-3,pentadecalactone,sorbic acid,citrus aurantium dulcis oil,sodium hydroxyde,tocopheryl acetate,disodium edta,iris germanica root extract,retinyl palmitate,equisetum arvense extract,butylparaben,peg-8,propylparaben,ethylparaben,sodium hyaluronate,chlorhexidine digluconate,citrus aurantium amaraoil,tocopherol,ascorbyl palmitate,citric acid,ascorbic acid,limonene,linalool

水，c12-20 acid peg-8 ester，辛基十二烷醇，鲸蜡硬脂醇异壬酸酯，丁烯二醇，多醣物质，PEG-40氢化蓖麻油，4-甲氧基肉桂酸-2-乙基己基酯，苯氧乙醇，十六烷基磷酸钾，澳洲胡桃子油，地美司康，卡波姆，丙烯乙二醇，甘油硬脂酸，椰油脂酸甘油酯类，牛油果，c12-13烷醇乳酸酯，对羟基苯甲酸甲酯，二苯甲酮-3 ，环十五内酯，山梨酸，甜橙油，氢氧化钠，维生素E醋酸酯，乙二胺四乙酸二钠，鸢尾花萃取，维他命A酯，问荆萃取，对羟基苯甲酸丁酯，聚乙二醇- 8，羟苯丙酯，羟苯乙酯，透明质酸钠，洗必泰葡萄糖酸盐，苦橙油，维生素E ，维生素C棕榈酸酯，柠檬酸，抗坏血酸，柠檬精油，沉香醇水：几乎所有护肤品成分第一位都是水。辛基十二烷醇：界面活性剂、乳化剂、稠化剂，有一定刺激性

However, the first one enzyme 1-deoxy-D-xylulose 5-phosphate synthase gene and the second one enzyme 1-deoxy-D-xylulose 5-phosphate reductoisomerase gene in MEP pathway had been reported and expressed in the latex of rubber tree, indicating that MEP pathway may be involved in rubber biosynthesis.4 - hydroxy -3 - methyl -2 -- butenyl -4 - phosphate reductaseis the last enzyme that catalytic 4 - hydroxy -3 - methyl -(2E)- butenyl -4 - phosphate to generate isopentenyl pyrophosphate.

然而已有报道MEP途径中第1个酶1-脱氧-D-木酮糖-5-磷酸合成酶（1-deoxy-D-xylulose 5-phosphate synthase，DXS）基因和第2个酶1-脱氧-D-木酮糖-5-磷酸还原酶（1-deoxy-D-xylulose 5-phosphate reductoisomerase ，DXR）基因在橡胶树胶乳中的表达，这表明MEP途径可能参与橡胶的生物合成。4-羟基-3-甲基-2--丁烯基-4-磷酸还原酶（4-hydroxy -3-methyl-2--butenyl-4-diphosphate reductase，HDR）是异戊烯基焦磷酸合成途径之一甲基赤藓糖磷酸（methylerythritol phosphate，MEP）途径中的最后一个酶，催化4-羟基-3-甲基-(2E)-丁烯基-4-磷酸生成异戊烯基焦磷酸。

The results showed that the degree of butyryl substitution of CAB increased and the degree of acetyl substitution of CAB decreased as the activation time increased. The degree of substitution of CAB changed slightly after the esterification went along about 2h.

随着活化时间的增加，CAB的丁酯取代度会逐渐增大，乙酯取代度会逐渐减小；酯化反应2h后，CAB取代度变化不大；CAB的丁酯取代度随着反应体系中丁酰基摩尔分数的增加而增大，而乙酯取代度则随着丁酰基摩尔分数的增加而减小。

A process for preparingp-fluo-2-(2-methyl-3-propionyl)-4-oxy-N,3-diphenyl-phenylbutylamide includes such steps as Friedle-Craft acylating of newly prepared phenylacetyl chloride and fluorobenzene under catalysis of AlCl3 to obtain 4-fluoro-phenylbenzyl ketone, brominating at carbonyl alpha position under catalysis of less AlCl3 to obtain alpha-bromo-4-fluo-phenylbenzyl ketone, and condensing with isobutyryl acetanilide under action of sodium ethoxide.

本发明涉及一种制备对氟－2－(2－甲基－3－氧丙基)－4－氧－N，3－二苯基－苯丁酰胺(1)的方法，其包括以下步骤：新制的苯乙酰氯与氟苯在AlCl3催化下进行Friedle－Craft酰化反应，得到对4－氟－苯基苄基酮(4)；化合物(4)在少量AlCl3催化下进行羰基α位溴化，得到α－溴－4－氟－苯基苄基酮(5)；然后(3)异丁酰乙酰苯胺在乙醇钠作用下与化合物(5)进行缩合。

The one is-2-isopropylidene-3-[1-(3,4-dimethoxyphenyl)ethyl-idene] succinic anhydride, the other is-2-isopropylidene-3-[1-(3,4-methylenedioxyphenyl)- ethylidene] succinic anhydride.

合成了三种苯基俘精酸酐，其中具有给电子基的3-(3，4-二甲氧基苯基)亚乙基(2-亚丙基)丁二酸酐与3-(3，4-亚甲二氧基苯基)亚乙基(2-亚丙基)丁二酸酐是新化合物。

In this work, isobutyl isobutyrate was prepared by the condensation of two molecular isobutyraldehyde in the presence of aluminium isobutoxide catalyst system.

依据间歇反应所得一系列数据，确定了异丁醛连续缩合反应工艺流程；考察了以异丁醛为原料，在 5～10℃，停留时间 1 5～ 2h ，在异丁氧基铝催化体系作用下，两分子异丁醛缩合成一分子异丁酸异丁酯；脱除催化剂后，粗产品精制得到纯度≥ 99 5 %的异丁酸异丁酯，异丁醛的转化率≥ 98 5 %，异丁酸异丁酯的选择性≥95 %。

Chiral 3 methy 1,4 butanediol and its derivatives are the important intermediate of synthesis of chiral smectic liquid crystal polyesters and chiral natrual products with biological activity. In the paper, a new efficient route of 3 methyl 1,4 butanediol and its two derivatives, 2 methyl 4 tetrapyranyloxy 1 butanol and 2 methyl 4 tetrapyranylbutanal, was described, and the target products were synthesized by employing asymmetric hydroboration oxidation improved.

手性2－甲基－1，4－丁二醇及其衍生物是合成各种手性近晶型液晶材料以及手性天然生物活性物质的重要中间体，以3－甲基－3－丁烯－1－醇为原料利用改进的不对称硼氢化－氧化反应，成功地合成了－2－甲基－1，4－丁二醇以及其2种手性衍生物：－2－甲基－4－四氢吡喃氧基－1－醇和－2－甲基－4－四氢吡喃氧基丁醛。

In the second part, quantum chemical AM1 methods were employedto theoretically investigate the electronic structures of maleic anhydride in ground- and excited-states. On basis of the frontier orbital theoryand three bonding principles, the possibility of reaction of active α-hydroxysuccinic anhydride carbanion and active α-hydroxy-succinic anhydride radical on polymerization process of MArespectively by alkali catalyst and by hydroxyl radical was discussed. Theanionic and radical polymerization of MA discussed also. Theoreticalstudies show that both polymerization products of MA are in the chainstructures, corresponding to the experimental findings.

第二部分用量子化学AM1方法，计算研究了马来酸酐的基态和激发态电子结构；应用前线轨道理论和成键三原则分别探讨了碱催化条件下和羟基自由基引发下马来酸酐均聚合过程中α-羟基丁二酸酐碳阴离子和α-羟基丁二酸酐碳自由基活性中间体参与反应的可能性及由它们引发的马来酸酐阴离子聚合反应机理和自由基引发聚合反应机理；理论研究表明马来酸酐的均聚合产物均为链式结构，与实验事实相相符。

The labia have now been sutured together almost completely.The drains and the Foley catheter come out at the top.

此刻阴唇已经几乎完全的缝在一起了，排除多余淤血体液的管子和Foley导管从顶端冒出来。

To get the business done, I suggest we split the difference in price.

为了做成这笔生意，我建议我们在价格上大家各让一半。