丁二酰

The acylation of 2,3-dimethyl-2-butene by acetic anhydride in the presence of H3PO4 was investigated.

在H3PO4存在下进行了2，3-二甲基-2-丁烯与乙酐的酰化反应。

It was found that H3PO4 is an effective catalyst for the acylation of 2,3-dimethyl-2-butene by acetic anhydride at room temperature.

结果表明，H3PO4是室温下催化2，3-二甲基-2-丁烯与乙酐酰化反应的有效催化剂。

Grafting of crotonic acid, undecylenic acid, oleic acid, and acrylic acid onto ABS was initiated by benzoyl peroxide in 1, 2-dichloroethane solution.

以过氧化二苯甲酰为引发剂，在1，2-二氯乙烷溶液中进行反式丁烯酸、10-十一烯酸、油酸、丙烯酸接枝ABS树脂。

Hydrogels based on n -alkyl methacrylate esters,acrylic acid and acrylamide cross-linked with 4,4′-diazobenzene were preparared,and their deswelling kinetics was studied.

研究了甲基丙烯酸十二烷或丁酯、甲基丙烯酰胺及丙烯酸与4 ，4′-二偶氮苯交联共聚凝胶的消溶胀动力学。

Utilizing 6 and several kinds of diazides prepared in our lab, polys containing 1,2,3-triazolyl and perfluorocyclobutane units were synthesized by "Click chemistry". Utilizing the polycondensation reaction between 6 and several commercially available aromatic diphenol or copolymerization reaction after adding another active aromatic dichloride, fluorinated polys containing phenylphosphine oxide units were synthesized. Utilizing the polycondensation reaction between 6 and several commercially available aromatic dianhydride, fluorinated polys containing PPO units were synthesized.Secondly, structure characterization of fluorinated polys.

利用化合物6同各种自制的二叠氮化合物，通过&Click chemistry&，合成了具有1，2，3-三唑环结构单元的全氟环丁基类聚芳醚；利用化合物22同各种商业化的芳香二元酚类化合物进行缩聚反应或者再加入另外一种活性芳香二氯代物进行三元共聚反应，制备了具有苯基氧膦结构单元的含氟聚芳醚；通过化合物25同各种商业化的芳香二元酸酐类化合物进行缩聚反应，得到了具有PPO结构单元的含氟聚醚酰亚胺。

In order to carry out the separation of the azeotropic mixture dipropyl ether + 1-propyl alcohol by extractive distillation, we are studied the influence on the phase equilibria behavior four different solvent: 1-pentanol [2], butyl propionate [3], N,Ndimethylformamide [4] and 2-ethoxyethanol.

为了用萃取性蒸馏法分离二丙醚和1－丙醇组成的共沸混合物，我们正在研究4种不同溶剂对相平衡行为的影响：1-戊醇[2]、丙酸丁酯[3]、N，N－二甲基甲酰胺[4]和2-乙氧基乙醇。

As can be seen in Fig. 5, dipropyl ether will be recovered in the distillate using 1-pentanol, N,N-dimethylformamide and 2-ethoxyethanol as entrainers and butyl propionate is the only entrainer studied that inverts the volatility of the azeotropic mixture.

从图 5可以看出，使用1-戊醇、N，N-二甲基甲酰胺和2-乙氧基乙醇作为共溶剂时二丙醚将在馏分中回收，丙酸丁酯是唯一与共沸混合物挥发性相反的共溶剂。

A GC headspace injection method for the determination of residual organic solvents such as methanol, ethanol, acetonitrile, dichloromethane, ethylacetate, 4 methyl 2 pentanone, toluene, DMF, chloroform and tetrahydrofuran in tazobactam was established.

建立了气相色谱顶空进样法测定三唑巴坦中甲醇、乙醇、乙腈、二氯甲烷、乙酸乙酯、甲基异丁基酮、甲苯、N ，N′-二甲基甲酰胺、氯仿和四氢呋喃等有机溶剂的残留量。

The optimal reaction conditions were as follows:chloroform was used as the reaction solvent,3,5-propionyl acid 0.02 mol,sulphoxide diloride 0.054 mol,the reaction temperature 50℃ and the reaction time 5 h. Under these conditions,the yield of product was 98.9%.

对酰氯合成条件进行了研究，得出优惠反应条件为：以氯仿作溶剂、β-（3，5-二叔丁基-4-羟基苯基）丙酸0.02 mol、二氯亚砜0.054 mol、反应温度50℃、反应时间5 h，优惠条件下产品的收率为98.9％。

In order to obtain versatile ulitity of host molecules, three new chiral calix [4] crown ethers containing aza, thio atoms bearing two chiral sites provided by -cysteine ester were synthesized by the condensation of calix [4] arene diacid dichloride with oligoethylene glycol bridged bis-amino acid methyl ester. All new compounds were characterized by NMR, MS and elemental analysis.

以-半胱氨酸为手性源，利用多甘醇二氯醚在碱性条件下对半胱氨酸巯基进行烷基化反应，成功地合成了多甘醇醚链桥联的半胱氨酸衍生物，醚化反应后，在高度稀释条件下与对叔丁基杯[4]芳烃二乙酰氯进行双功能基缩合反应成功地合成了新型的手性杯[4]含氮、硫杂冠醚，并利用〓H NMR、MS等谱图手段对其结构进行了表征。

The split between the two groups can hardly be papered over.

这两个团体间的分歧难以掩饰。

This approach not only encourages a greater number of responses, but minimizes the likelihood of stale groupthink.

这种做法不仅鼓励了更多的反应，而且减少跟风的可能性。