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The studies segmented polyester polyurethaneurea elastomers based on 4,4'-diphenylmethane diisocyanate, ethylene diamine and polybutylene adipate (M. W. 1975 and M. W. 1228) were studied by means of IR spectrascopy.

用红外光谱法对基於4,4'-二苯基甲烷二异氰酸酯、乙二胺和聚己二酸丁二醇酯(分子量分别为1975和1228)的嵌段聚脲氨酯弹性体进行了研究。

Hydrogen bonding in hard segment domains of segmented polyester polyurethaneurea based on 4,4'-diphenylmethane diisocyanate, ethylene diamine and polybutylene adipate(M. W. 1975 and M. W. 1228) was studied by means of IR spectroscopy.

用红外光谱法对基於4,4'-二苯基甲烷二异氰酸酯、乙二胺和聚己二酸丁二醇酯(分子量分别为1975和1228)的两系列嵌段聚酯型聚脲氨酯硬段微区中的氢键化进行了研究。

Water,c12-20 acid peg-8 ester,octyldodecanol,propylene glycol,coco-caprylate/caprate,cetearyl isononanoate,prunus amygdalus dulcisoil,biosaccharide gum-1,phenoxyethanol,ethylhexyl methoxycinnamate,potassium cetyl phosphate,simmondsia chinensisseed oil,carbomer,glyceryl polymethacrylate,malva sylvestrisextract,glyceryl stearate,cetearyl alcohol,cetyl palmitate,cocoglycerides,c12-13 alkyl lactate,methylparaben,sorbic acid,disodium edta,sodium hydroxide,tocopheryl acetate,benzophenone-3,iris germanica root extract,retinyl palmitate,butylparaben,peg-8,propylparaben,ethylparaben,sodium hyaluronate,chlorhexidine digluconate,tocopherol,ascorbyl palmitate,citric acid,ascorbic acid

水, c12-20 acid peg-8 ester,辛基十二烷醇,丙二醇,coco-caprylate/caprate,鲸蜡硬脂醇异壬酸酯,甜杏仁油,多醣物质,苯氧乙醇,4-甲氧基肉桂酸-2-乙基己基酯,十六烷基磷酸钾,西蒙得木籽油,卡波姆,甘油聚甲基丙烯酸酯,锦葵萃取,甘油硬脂酸,棕榈醇,十六烷基棕榈酸酯,椰油脂酸甘油酯类,c12-13烷醇乳酸酯,对羟基苯甲酸甲酯,山梨酸,乙二胺四乙酸二钠,氢氧化钠,维生素E醋酸酯,二苯甲酮-3,鸢尾花萃取,维他命A酯,对羟基苯甲酸丁酯,聚乙二醇-8,羟苯丙酯,羟苯乙酯,透明质酸钠,洗必泰葡萄糖酸盐,维生素E ,维生素C棕榈酸酯,柠檬酸,抗坏血酸

Based on the problem of various types of catalyst and according to the features of carbonylation catalysts reactions, our team has been designed a series of new metal complexes of benimidazoles, which can be used for carbonylation catalyst of industry. Seven new benzimidazole derivatives were prepared by the o-phenylenediamine、oxalic acid、glycolic acid、monomethyl monopotassium malonate、ethyl cyanoacetate、succinic anhydride. The structures of them were confirmed by IR、Elemental analsis. The crystal structures of d and e were determined by X-ray single crystal diffraction of Germanic Bruker Smart APEX II CCD. The catalysis of them was tested by carbonylation reactions.

本文设计以邻苯二胺和草酸、羟基乙酸、丙二酸单甲酯、氰基乙酸乙酯、丁二酸单甲酯为原料采用PPA催化和无机酸催化法,合成了4种苯并咪唑-2-羧酸衍生物并进行了表征;培养了2个化合物d、e的晶体并测定和讨论了晶体结构;制备了3种未见报道的苯并咪唑金属配合物,对配合物在羰基化法制醋酐-醋酸反应的催化作用进行了初步试验。

A series of polyether based polyurethaneurea aqueous dispersions with well-defined hard segments were prepared by fractional steps with polyether polyol, 4,4'-diphenylmethane diisocyanate, dimethylolpropionic acid, 1,4-butanediol, isophorone diisocyanate and ethylenediamine.

以二苯基甲烷二异氰酸酯、二羟甲基丙酸、1,4-丁二醇、异佛尔酮二异氰酸酯和乙二胺为硬段,聚醚多元醇为软段,通过分子设计采用分步合成法,制备了具有规整硬段和良好分散性能的聚醚型聚氨酯脲水分散液。

A series of polyether based polyurethaneurea aqueous dispersions with well-defined hard segment s were prepared by fractional steps with polyether polyol, 4,4′-diphenylmethane diisocyanate,dimethylolpropionic acid,1,4-butanediol,isophorone diisocyanate and ethylenediamine.

以二苯基甲烷二异氰酸酯、二羟甲基丙酸、1,4-丁二醇、异佛尔酮二异氰酸酯和乙二胺为硬段,聚醚多元醇为软段,通过分子设计采用分步合成法,制备了具有规整硬段和良好分散性能的聚醚型聚氨酯脲水分散液。

Long-chain branched polyethylene was obtained using a homogeneous bianary catalyst system composed of late and early transition metal complexes,namely a mixture of bis(α-naphthalidine)-2,3-butanediimine NiBr2 and Cp* TiCl3,as catalyst precursors in the presence of MAO.

合成了一种后过渡金属镍化合物 [二- N ,N′--2 ,3-丁二亚胺镍二溴化物 ][C10H7—NC(CH3)C(CH3)N—C10H7]NiBr2,此化合物在MAO活化下催化乙烯聚合能得到含有末端双键的低分子量聚乙烯,即长链α-烯烃。

Chloroacetic acid,chloromethyl ether,acetone,mphenylenediamine,butyl acetate,ethyl acetate,methylene chloride,ethylene dichloride,dioxane.

氯乙酸,氯甲醚,丙酮,间苯二胺,醋酸丁酯,醋酸乙酯,二氯甲烷,二氯乙烷,二氧六环。

Segmented polyester polyurethaneurea based n 4, 4'-disphenylmethane diisocyanate, ethylene diamine and polybutylene adipate elastomers and their deuterated polymers were studied by means of IR spectroscopy.

用红外光谱法对基於4,4'-二苯基甲烷二异氰酸酯、乙二胺和聚己二酸丁二醇酯的嵌段聚酯型聚脲氨酯弹性体及其氘化產物进行了研究。

Two types of haptens, the earboxylated propyl amino derivative of the acid moiety (HCA1) that is the hydrolyzed product of cyhalothrin, and the carboxylated ethyl carbonyl derivative of the alcohol moiety (HCB2) were synthesized, and conjugated with the carrier proteins bovine serum albumin and ovalbumin respectively by the active ester method and the mixed anhydride method. The polyclonal antibodies were obtained after immuning to the New Zealand rabbits.

通过对氯氟氰菊酯分子结构中的酸部分接4-氨基丁酸(HCA1)和醇部分接丁二酸酐(HCB2),合成两种不同的半抗原,并通过碳二亚胺法将HCA1和HCB2分别与牛血清蛋白偶联制备了人工抗原HCA1-BSA和HCB2-BSA,通过活泼酯法将HCA1、HCAS和HCB2分别与卵清蛋白偶联制备包被抗原,两种人工抗原通过免疫新西兰大白兔来制备相应的多克隆抗体。

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