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丁二烯

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The Polyether Polyurethane elastomer were prepared from hydroxyle-terminated polybutadiene, isophorone diisocyanate, 1,4-butylcne glycol, stannous octoate and SiO_2 in direction.

以端羟基聚丁二烯、异佛尔酮二异氰酸酯、1,4-丁二醇、白碳黑、辛酸亚锡等为原料,采用一步法制备了聚烯烃型聚氨酯弹性体材料。

In this article, star-high vinyl content polybutadiene was prepared using a multi-functional organolithium anionic initiator by " one-step " process. On the basis of 250ml glassware experiment ,we improved the experiment in 2L metal kettle. The polymerization condition was got as follows: polymerization temperature : 50-60 ℃, monomer content : 8-llg/100ml, polymerization time : 3~4 hours.Chracterizations were carried out by 'H-NMR, IR and GPC.

本文首次采用多官能团有机锂引发剂一步法合成出了星型高乙烯基聚丁二烯,在250ml玻璃瓶的基础上,进行2L金属斧的扩大实验,确定了以下聚合工艺参数:聚合反应温度:50~60℃,单体浓度:8~11g/100ml,聚合反应时间:3~4小时。

Hydrogenated poly (styrene-b-butadiene) copolymer/organophilic montmorillonite nanocomposites were prepared by a solution approach.

采用溶液混合方法制备了氢化苯乙烯/丁二烯三元嵌段共聚物/有机蒙脱土纳米复合材料。

The main pollutants from this chemical plant is perchloroethane, pentachloroethane, hexachlorobutadiene and HCB, and such pollutants are present in the soil with high densities, some as high as 1%- 95%, of which the perchloroethane is near the purity of the corresponding product, and especially this part of the soil contains comparatively high-density persistent organic pollutant HCB, which makes it suitable to be disposed of together with other soils. Therefore it is suggest that this part of soil should be separately dug out and transported outside of the site.

化工厂的主要污染物质是六氯乙烷、五氯乙烷、六氯丁二烯和六氯苯,土壤中上述污染物的浓度非常高,有些达到1%至95%,其中六氯乙烷接近相应的产品的纯度,特别是这一部分含有较高浓度的持久性有机污染物六氯苯,不利于与其它土壤混合处理,建议将这一部分单独开挖出来并运出场外。

In addition,the activity of the putadiene polymerization catalyzed by SAAC.Nd.Fe-AlEt Cl-Al in the presence of phenanthroline and the relationship bet-ween the polybutadiene microstructure obtained with the content of Fe in SAAC.Nd.Fe were studied.

此外,初步考察了在邻啡绕啉存在下SAAC·Nd·Fe体系聚合丁二烯的活性以及所得产物的微观结构与络合物SAAC·Nd·Fe中Fe的含量关系。

Substituent effect of pyrazoles was also investigated by DNMR and DFT.We successfully synthesized these intermediates with exclusively-conformations in a mild condition. X-ray results show that substituents in the pyrazolyl ring affect greatly on the structures of products, especially theπdelocation of the fragment 1-metal-butadiene.

本文以取代吡唑和1-炔基Fischer卡宾化合物的Michael加成反应合成了12个-型β-吡唑基烯基卡宾化合物,反应条件温和。X-ray晶体衍射显示吡唑上取代基对产物结构,特别是1-M-丁二烯的共轭程度具有较大的影响。

The conditions of solution polymerization of butadiene with raffinate oil as solvent in nickel catalyst system were studied based on the researches of laboratory and industry.

采用镍催化体系,以抽余油为溶剂,研究了丁二烯溶液聚合的聚合条件。

In the process of extractive distillation o f butadiene,thequality of the byproduct butane-butene raffinate are rel ated to many process para meters, which are coupling and with noises.

丁二烯萃取精馏过程中,副产品抽余液的质量和很多工艺参数有关,工艺参数之间又是相互关联、耦合的,并具有噪声。

The liner for double-based propellant was prepared from HTPB,toluene diisocyanate,diisooctyl sebacate,1,4-butanediol and mica.

以端羟基聚丁二烯、癸二酸二异辛酯、1,4 丁二醇、绢云母、甲苯二异氰酸酯等为原材料,制备了双基药柱用包覆层。

The density, binding energy and radical distribution function of HTPB/plasticizers blends and binder hydroxyl-terminated polybutadiene, and plasticizer dioctyl sebacate, dioctyl adipate, dibutyl phthalate, dioctylphthalate were calculated by molecular dynamics simulation for evaluating compatibility of HTPB and plasticizers.

为评价端羟基聚丁二烯与增塑剂相容性的优劣,采用分子动力学模拟方法对纯HTPB、增塑剂癸二酸二辛酯、己二酸二辛酯、邻苯二甲酸二丁酯、邻苯二甲酸二辛酯及HTPB与增塑剂组成的共混物的密度、结合能和径向分布函数等进行了计算。

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