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Ab initio and density functional theory (B3LYP) in G98 were employed to study the following four direct aldol reactions between acetone and isobutyraldehyde or 3,3-dimethylbutyric aldehyde or benzaldehyde or 4-bromo-phenyl aldehyde catalyzed by-proline .

中文摘要:本文采用G98程序包中的从头计算方法和密度泛函方法计算研究了-脯氨酸催化丙酮与异醛、3,3-二甲基醛、苯甲醛及对溴苯甲醛的不对称直接羟醛缩合反应,共计四个反应体系。

The hybrid composite PW11Co/PAMAM was characterized by FT-IR, UV-Vis diffuse reflectance spectra, XPS, XRD and TG/DTA, indicating that the PW11Co was chemically anchored to PAMAM. The morphologies of the title composite were characterized by scanning electron microscopy and transmission electron microscopy. The catalytic activity was evaluated by oxidation of isobutyraldehyde to isobutyric acid in MeCN under mild conditions (20 ℃, ambient pressure), showing that the title compound is a more effective and recoverable catalyst than corresponding PW11Co.

通过FT-IR、DR-UV-Vis、XRD、TEM、SEM、TG/DTA等手段对其进行了表征,并考察了其对异醛转化异酸的催化活性,实验结果表明,多金属氧酸盐通过配位键与聚酰胺-胺作用形成的无机-有机复合物可望成为一种催化活性高且易于分离和重复使用的多相催化剂。

Several routes for synthesizing methyl isopropyl ketone were introduced, including the main methods based on isobutyl aldehyde-acetic acid, isobutyric acid -acetic acid, methyl ethyl ketone-formaldehyde and isoprene.

介绍了甲基异丙酮的多种合成路线,主要有异醛-乙酸法、异酸-乙酸法、甲基乙基酮-甲醛法和异戊二烯法。

Using potassium bisulfate as the heterogeneous catalyst,isovaleric acid and n-butanol reacted to form flavor butyl isovalerate.

以异戊酸和正醇为原料,采用不溶于反应物系的硫酸氢钾为非均相催化剂合成了食用香料异戊酸酯。

The styrene-acrylic emulsion was synthesized using monomer styrene,butyl acrylate,2-hydroxy propylacrylate and monobutyl itaconate.

采用苯乙烯、丙烯酸酯及丙烯酸-2-羟基丙酯作主单体,衣康酸单酯作功能单体合成了苯丙乳液,比较了功能单体MB I及丙烯酸对苯丙乳液性能(包括耐水性、表面张力、钙离子稳定性等)的影响,用透射电镜观察了乳胶粒子形态。

The quantity of catalyst was equal to 0.6% of feedstocks,the reaction temperature was 78~110 ℃,and the reaction time was 45 min. The test results have shown thatH_4SiW_(12-O_(40)/MCM-48 is an excellent catalyst for synthesizing butanone 1,2-propanediol ketal with its yield reaching over 91.9%.

实验表明:H4SiW12O40/MCM-48是合成酮-1,2-丙二醇缩酮的良好催化剂,在n∶n(1,2-丙二醇)=1∶1.6,催化剂用量为反应物料总质量的0.6%,环己烷为带水剂,反应时间45 min的优化条件下,酮-1,2-丙二醇缩酮的收率可达91.9%。

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There was me,that is Alex,and my three droogs,that is Pete,Georgie,and Dim being really dim,and we sat in the Korova Milkbar making up our rassoodocks what to do with the evening,a flip dark chill winter bastard though dry.

一伙子人里面有我,名叫亚历克斯?,另有三个哥们,分别是彼得、乔治和姆?,姆真的很笨。大家坐在柯罗瓦奶吧的店堂里,议论着今晚究竟要干些什么。

Two kinds of cross-linked polyacrylate latices with relatively narrow distribution of particle diameters, which are abbreviated to P and P/P, were synthesized by seeded emulsion co-polymerization, respectively. Butyl acrylate and 2-ethylhexy! acrylate were used as comonomers of ACR core, styrene and methyl methacrylate were employed as comonomers of ACR shell, and 1,4-butanediol diacrylate was used as cross-linking agent.

采用丙烯酸酯和丙烯酸2-乙基己酯(2-EHA)为核层单体、苯乙烯和甲基丙烯酸甲酯为壳层单体、1,4-二醇二丙烯酸酯为交联剂,通过多步种子乳液聚合方法合成了P、P/P两种具有窄粒径分布的共聚丙烯酸酯胶乳。

The synthesis of butyl laurate by lauric acid and butyl alcohol as raw materials and nanometer H3PW12O40 / SiO2 as catalyst was studied.

以纳米型复合杂多酸H3PW12O40/SiO2为催化剂,月桂酸和醇为原料,合成月桂酸酯。

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