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On the same catalyst, the adsorption velocity and quantity between the isobutane and butene has great differences, which results in the very low isobutane/butene adsorption ratio in the micro-pore of the catalyst, especially at higher temperature.

利用原位红外对异烷和烯的吸附和反应历程研究结果表明,异烷和烯在催化剂不同活性位上的吸附反应过程差别很大。

Selective oxidation of isobutylene to methacrolein is a key step in the production of methyl methacrylate from isobutylene.

烯选择氧化制备甲基丙烯醛是异烯法制备甲基丙烯酸甲酯的关键步骤。

Effects of reaction temperature, volume ratio of water to isobutylene and linear flowrate of Ca raffinate on activity of the catalyst were studied.

试验结果表明,异烯催化逆流水合制叔醇的适宜操作条件为:反应温度80~90℃,水油体积比为4~5,抽余C4烃的流速为0.45~0.55mm/s。

The experimental results showed that: the adsorption of methanol and isobutylene conform to Elovich equation. The adsorption quantity of methanol was bigger than that of isobutylene, but the adsorption rate was slower.

采用过渡应答技术对甲醇和异烯在改性b分子筛上的吸附行为进行了研究,研究结果表明:异烯和甲醇在改性b分子筛上符合先快吸附后慢吸附的Elovich吸附规律。

In the part of preparing HMT, the thesis did research on the preparing process of using isobutylene , 2,3-dimethyl-butene-l , 2,3-dimethyl-butene-2 as the materials respectively .

在中间体合成部分,本文分别对新己烯、2,3—二甲基—烯—1、2,3—二甲基—烯—2为原料合成HMT的工艺进行了研究,然后利用GC-MS对三种原料合成HMT的主要副产物分别进行了分析。

In the part of preparing HMT, the thesis did research on the preparing process of using isobutylene , 2,3-dimethyl-butene-l , 2,3-dimethyl-butene-2 as the materials respectively .Then using GC-MS , the main outgrowths in each reaction systems were analyzed.

在中间体合成部分,本文分别对新己烯、2,3—二甲基—烯—1、2,3—二甲基—烯—2为原料合成HMT的工艺进行了研究,然后利用GC-MS对三种原料合成HMT的主要副产物分别进行了分析。

Through mechanism analyzing on the process of producing HMT , it was known that because the resistance of isobutylene was small ,the yield of outgrowth in such a reaction system was little and the yield of reaction was as high as 86%. 2,3-dimethyI-butene-2 had the biggest resistance and lowest yield of reaction of 18%. 2,3-dimethyl-butene-l had bigger resistance than isobutylene and more outgrowth than isobutyles but its yield of reaction could reach 70%.

通过对上述三种烯烃合成HMT的研究可知,由于新己烯位阻小,反应中副反应少,收率高达86%:而2,3—二甲基—烯—2的位阻最大,反应中副反应最多,反应收率最高仅为18%;2,3—二甲基—烯—1的位阻比新己烯大,反应副产物比新己烯多,但反应收率仍可达70%。

The progress of catalysts, which include composite-oxides catalysts and heteropoly compounds catalysts, for selective oxidation of isobutylene to methacrolein were summarized, the mechanism of this reaction on Mo-Bi catalysts was discussed.

本文综述了异烯选择氧化生成甲基丙烯醛催化剂,其中包括复合氧化物催化剂和杂多化合物催化剂等的研究现状,讨论了在Mo-Bi催化剂上异烯选择氧化生成甲基丙烯醛的反应机理。

The behaviors of methanol and isobutylene adsorbed over a modified-b zeolite catalyst were studied by the transient response method in a chromatogram-reactor. The experimental results showed that: the adsorption of methanol and isobutylene conform to Elovich equation.

摘 要:采用过渡应答技术对甲醇和异烯在改性b分子筛上的吸附行为进行了研究,研究结果表明:异烯和甲醇在改性b分子筛上符合先快吸附后慢吸附的Elovich吸附规律。

Antioxidant 2,2′-methylene-bis(4-ethyl-6-tert-butylphenol) is synthesized by condensation of formalin and 4-ethyl-2-tert-butylphenol which is prepared by alkylation of p-ethylphenol with isobutylene in the presence of phosphoric acid or ion-exchange resin as catalysts.

研究了以对乙基苯酚、叔醇为原料,在酸性条件下,进行烷基化反应,合成2 叔基 4 乙基苯酚,再进一步缩合成抗氧剂425的工艺条件。

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