一氯乙酸

Mainly engaged in: Hydrogen-imide hydrochloride, o-chlorophenyl cyclopentanone, 3.4 dimethoxy ethyl benzene, butyn single potassium acid, potassium ethyl malonyl, Ding amide, amide isobutyraldehyde , allyl chloroacetate, isopropyl chloroacetate Benzyl aluminum, cyclopentene, cyanide-o-chlorophenyl, o-methyl chloride, sulfuric acid chloride, p-chlorophenol, imidazole, Pinacolone, one chlorine Pinacolone.

主要经营：盐酸氢亚胺、邻氯苯基环戊酮、3.4二甲氧基苯乙酯、丁炔二酸单钾盐、丙二酸单乙酯钾盐、丁酰胺、异丁酰胺、氯乙酸烯丙酯、氯乙酸苄酯异丙醇铝、环戊烯、邻氯苯氰、邻氯苯甲酯氯、硫酸氯、对氯苯酚、咪唑、频呐酮、一氯频呐酮。

P chlorophenoxyacetic sodium was synthesized by p chlorophenol with 2 chloroacetic acid in the 20% hydroxide sodium aqueous solution.

采用一步法由氯乙酸与对氯苯酚在氢氧化钠质量分数为 0 2的水溶液中的反应制得。

Chapter two 4-Hydroxybenzoic acid is connected with PEG6000 through defoliant DCC at rooom temperature, then the product is refluxed with chloroacetic acid in acetone to afford PEG-bound phenyloxyacetic acid, which is reacted with thionyl chloride, ammonium thiocyanate and arylamines in turn to give PEG-bound disubstituded thioureas. After the cleavage with sodium methoxide in methanol, the eleven disubstituted thioureas are obtained.

第二章 利用PEG6000作载体，通过脱水剂DCC在室温下将对羟基苯甲酸以酯键连接在PEG6000上，再与氯乙酸在较温和的条件下生成PEG6000支载的芳氧乙酸，然后，依次与亚硫酰氯、硫氰酸铵、芳胺反应，生成PEG6000支载的硫脲，最后用甲醇钠的甲醇溶液切割PEG，得到了十一种1，3-二取代硫脲。

New ruthenium benzylidene complexes benzylidene[1,3-bis(2,6-dimethylphenyl)-4,5-dihydroimidazol-2-ylidene] [k~2-diphenylphosphinoacetato] monochlororuthenium (46), benzylidene[1,3-bis(2,6-dimethylphenyl)-4,5-dihydroimidazol-2-ylidene][k~2-3-propionato]monochlororuthenium (47), benzylidene[1,3-bis(2,6-dimethylphenyl)-4,5-dihydroimidazol-2-ylidene] [k~2-2-benzonato]monochlororuthenium (48) featured five-membered, flexible six-membered and rigidsix-membered chelating rings respectively are prepared by reactions of complex 41 withcorresponding sodium phosphino-carboxylates. It is confirmed by X-ray crystallographicanalysis that the coordination geometries of complexes 46 and 47 are distorted squarepyramids with phosphino-carboxylate ligands chelating to ruthenium, and the coordinationbetween ruthenium and benzylidene ligands are strengthened.

用二苯基瞵乙酸盐、二苯基膦丙酸盐、二苯基膦苯甲酸盐与钌卡宾配合物41反应合成了三个新的钌卡宾配合物：含五元膦-氧螯合环的1，3-二-(2，6-二甲苯基)-4，5-二氢咪唑基1-苯亚甲基--一氯合钌(46)、含六元柔性膦-氧螯合环的[1，3-二-(2，6-二甲苯基)-4，5-二氢咪唑基1-苯亚甲基--一氯合钌(47)及含六元刚性膦-氧螯合环的[1，3-二-(2，6-二甲苯基)-4，5-二氢咪唑基]-苯亚甲基--一氯合钌(48)。X射线单晶衍射分析证明，配合物46、47都为变形的四方锥构型，膦-氧与钌形成螯合配位，其中苯亚甲基与钌的配位得以加强。

Ethyl phenoxyacetate has been synthesised by the reaction of phenol with ethyl chloroacetate under the condition of solid-liquid phase transfer catalysis using PEG-400 as the catalyst.

于固一液相转移催化条件下，以PEG-400为催化剂，通过苯酚与氯乙酸乙酯反应合成了苯氧基乙酸乙酯。与85％的水合肼作用得到相应的酰肼。

DCA, or dichloroacetic acid, is an analogue of acetic acid in which chlorine atoms replace two of the three hydrogen atoms on the methyl group.

DCA也叫二氯乙酸或二氯醋酸，是一种类似乙酸的化合物，但乙基团上有两个氢原子被氯原子所取代。

This study developed a new method on the determination of carcinogenic disinfection by-products-trace dichloroacetic acid and trichloroacetic acid in tap water by ion chromatography-electrospray-tandem mass spectrometry(IC-ESI-MS/MS).

建立了一种采用离子色谱-串联电喷雾四级杆质谱联用技术检测自来水中可致癌的饮用水消毒副产物二氯乙酸和三氯乙酸的方法。

The rather amount of dichloroacetic acid not only enhances consumption of raw materials, but also increases the cost, with the difficulty to separate it from the product later the quality of products drops. Dichloroacetic acid is of a few uses causing the huge waste of the fund and equipments.To control the dichloroacetic acid coming out and decrease the consumption o

通过大量实验，对反应精馏技术的原理进行了理论研究，从中探索得出反应精馏法合成氯化节、氯乙酸等有机氯化物的工艺路线，为氯化节和氯乙酸的生产提供了一条新的生产工艺，为反应精馏技术应用的理论研究拓展了新的内容，并为工程设计提供了基本数据。

Monochloroacetic acid is a rather important chemical raw material and organic intermediate product, which is mainly manufactured by chloride of acetic acid using sulfur and anhydride acetic acid as catalyst.

氯乙酸是一种及其重要的化工原料和有机中间体，目前氯乙酸主要以硫磺或醋酐为催化剂进行乙酸氯化生产而得。

In the present dissertation, the principles and application of the reaction rectification techology in the syntheses of benzyl chloride, chloroacetic acid, monochloroacetone were approached.

本论文采用反应精馏技术氯化苄的合成、氯乙酸的合成进行了认真的研究，并且对一氯丙酮、氯苄系列产品进行了反应精馏研究，都得到了理想的结果。

The split between the two groups can hardly be papered over.

这两个团体间的分歧难以掩饰。

This approach not only encourages a greater number of responses, but minimizes the likelihood of stale groupthink.

这种做法不仅鼓励了更多的反应，而且减少跟风的可能性。