查询词典 zirconium

052 Describes and claims a body of polycrystalline dielectric ceramic material having a lead zirconate--lead titanate--lead stannate composition falling within the area A B C E F of the triaxial diagram 1d of the drawings accompanying this specification and containing at least one substitutional additive ingredient selected from the group consisting of elements having respective ionic radii sufficiently close to the ionic radius of one of the elements lead, tin, titanium, zirconium and oxygen to permit of substitution, and a valence state differing from that of said one element by less than three units, the aggregate quantity of additive ingredient amounting to from 0.1 to 5 percent of the replaced ion on an atom basis, each additive ingredient present in said material being in ionic form and substituting for a finite percentage of the ions of a particular one of the elements lead, tin, titanium, zirconium and oxygen with respect to which it conforms with regard to ionic radius and valence state, said additive ingredient replacing a quantity of said elements having in the aggregate an equal number of valence units.

参考译文：第 1012052 号专利说明书介绍一种含有锆酸铅，钛酸铅，锡酸铅的多晶陶瓷介质材料，其组成在说明书附图 ld 三元相图中处于 A B C E F 区域内，该组成至少还含有一种置换添加物，这种添加物从一组离子半径分别接近于铅，锡，钛，锆，氧的元素中选出，以利于互相置换，而与上述一种元素化合价之差应小于三价。该添加物的总量为被置换离子的 0.1%~5%克原子。上述材料中的每种添加物是以离子形式存在的，它以一定的百分数置换铅，锡，钛，锆，氧中的某一元素的离子。添加物在离子半径和价数上必须类似于上述任一元素，并且置换添加物的量与被置换的元素在总体上具有相等的化合价数。本句由两个简单句构成，一个主句，另一个是定语从句。

The mechanism, thermodynamics and kinetics of ion-exchange reactions between alkali, alkaline-earth and transition metal ions and zirconium phosphate and its derivatives are reviewed, progress in ion-exchange reaction between luminescent metal complex and zirconium phosphate is also discussed.

本文综述了碱金属、碱土金属、过渡金属离子等与磷酸锆及其衍生物的离子交换反应机理、热力学和动力学特性，另外也讨论了发光金属配合物与磷酸锆的离子交换反应研究进展。

The influence of different assembled condition such as assembly method, concentration of zirconium source and pH value on the effectiveness of assembly were evaluated via DSC-TG, FT-IR, Uv-vis and SAXRD et al. It showed that the assembly effectivness of uncalcined 3 Si/Zr_10# sample was best.c The optical characteristic, which including light-conduction in infrared band and polarity in visible band, of dip-coating film and membrane assembled zirconia after processing parameters of assembly optimized were observed via FT-IR and Uv-vis. The polarity was characterized by polarizing angle through calculation from light-transmittance, light-reflectance and fresnel coefficient. qualitative analysis showed that the polarity of Si/Zr_10 # dip-coating film assembled was best.d Adopting zirconium oxychloride as zirconium source, CTAB as template, employing different CTAB adding sequence, two mesoporous zirconia samples were prepared. The template effect of two samples was discussed. It showed that the effect of the sample which CTAB adding sequence was same as mesoporous silica film was better. The light-conduction in infrared band of these samples was also studied, which offered comparison to the polarity of zirconium dioxide assembled within mesopore.

结果显示：组装条件优化后的uncalcined 3 Si/Zr_10#厚膜样组装效果最好，其组装液对应的pH值最利于该锆源离子模板交换组装； c选用FT-IR、Uv-vis对组装条件优化后纳米氧化锆/介孔氧化硅厚膜、纳米氧化锆/介孔氧化硅薄膜包括红外导光性、可见光区内的偏光性在内的光学特性进行了分析，其中偏光性以膜层透光性、反光性及菲涅耳系数计算出的偏振角即布儒斯特角表征，定性分析显示，Si/Zr_10#ZrO_2/介孔氧化硅厚膜偏光性最好； d以氧氯化锆ZrOCl_2·8H_2O为锆源，CTAB为模板剂，采用不同的模板剂加入顺序，探索性地制备两介孔氧化锆样，分析了两介孔氧化锆样的模板效果，得出模板剂加入顺序同介孔氧化硅薄膜时介孔氧化锆样的模板效果较好，并分析了所得样品的导光性，为锆氧粒子引起的附加光学特性分析提供了参考和对比。

In the preparation method, zirconium is mixed with benzenephosphonic acid according to the molar ratio of 1:2 to 1:4, and Alpha-zirconium phenyl phosphonate is produced by centrifugal washing after one to five days of crystallization under the temperature of 50 DEG C to 100 DEG C; deionized water is added in order to prepare Alpha-zirconium serosity, the solid content of which is 4 percent to 8 percent; the Alpha-zirconium serosity is granulated and dried by a rotary spray dryer, the feeding speed of the Alpha-zirconium serosity imported into an atomizer is controlled between 20ml/min and 80ml/min, and the temperature of a hot air inlet is controlled between 120 DEG C and 200 DEG C.

本发明涉及一种大比孔容微球α-苯膦酸锆及其制备方法，其颗粒尺寸为10～100μm，比孔容为0.908cc/g，比表面积为125.8m 2 /g；其制备方法是将锆和苯膦酸以摩尔比1∶2～1∶4混合，在50～100℃温度条件下晶化1～5天，离心洗涤得到α-苯膦酸锆；加入去离子水配制α-苯膦酸锆浆液，其固含量为4-8％；将α-苯膦酸锆浆液用旋转式喷雾干燥器进行造粒、干燥，控制α-苯膦酸锆浆液输入雾化器的进料速度为20～80ml/min，控制热风进风口温度为120～200℃；该方法具有操作简单、合成条件温和，对环境污染小等特点，该材料应用于催化、催化剂载体、吸附、离子交换等方面。

Zirconium and its compounds,with the exception of zirconium lakes, salts and pigments of colouring

锆和它的化合物表6中着色剂的锆色淀，盐和颜料除外

Zirconium containing MCM-41 molecular sieves with high surface area, good crystallinity and Si / Zr ratio from 20 -∞ were synthesized in a near neutral condition by using a sodium silicate as silicon source and a zirconyl nitrite as zirconium source.

MCM - 41与传统分子筛比较，最突出的特点是具有 1～ 5nm直径的孔道和 1 0 0 0m2 ·g- 1 左右的比表面，如此宽孔道尺寸的固体材料对于大分子的吸附和催化具有潜在的应用前景[1 - 3] 。

Undecanedioic acid, dodecanedioic acid, brassylic acid, tetradecanedioic acid, pentadecanedioic acid, nylon 1212 resin, nylon 1212 salt, nylon 1212 powder, pa 1212 adhesives and sealants, zirconium dioxide, zirconium dioxide powder, zirconium oxychloride, 1,10-decanediol, 1,12-dodecanediol, dimethyl sebacate, dodecanedioic acid dimethyl ester, dodecane diamine etc.

十一碳二元酸，十二碳二元酸，十三碳二元酸，十四碳二元酸，十五碳二元酸，十二碳二元胺，十二碳二元醇，癸二醇，癸二酸二甲酯，十二碳二酸二甲酯，PA尼龙1212型高档热熔胶；以及二氧化锆，氧氯化锆等。

The zirconium film withoul zirconia wasprePared and the removing technology of the zirconia on the zirconium suthees wasNned.The method of high temPeratUr vacuum hydrOgenization Which was firstlystudied was used tO remove the okide film of zirconium on the sdses.

本文针对这种情况，首次进行了以下几方面的研究：首次采用电化学法研究了锆膜基材表面氧化层的去除技术，制得去除了表面氧化膜的锆基材膜，获得了锆膜基材表面氧化层的去除工艺。

A chromium free conversion coating at least equivalent in corrosion protective quality to conventional chromate conversion coatings can be formed on metals, particularly cold rolled steel, by a dry-in-place aqueous acidic liquid comprising: a component of anions, each of said anions consisting of at least four fluorine atoms and at least one atom of an element selected from the group consisting of titanium, zirconium, hafnium, silicon, and boron, and, optionally, ionizable hydrogen atoms, and optionally, one or more oxygen atoms; a component of cations of elements selected from the group consisting of cobalt, magnesium, manganese, zinc, nickel, tin, zirconium, iron, and copper; the ratio of the total number of cations of this component to the total number of anions of component being at least 1:5; sufficient free acid to give the composition a pH in the range from 0.5 to 5.0; a component selected from the group consisting of phosphorus-containing inorganic oxyanions and phosphonate anions; and a component selected from the group consisting of water-soluble and water-dispersible organic polymers and polymer-forming resins and, preferably, also including a component selected from the group consisting of tungstate, molybdate, silicotungstate, and silicomolybdate anions.

通过对包含以下成分的含水酸性液体进行干燥，可以在金属上形成无铬的转换涂层，该涂层与普通铬酸盐转换涂层相比，至少在抗腐蚀质量上等效：$_一种阴离子成分，所述各个阴离子包括至少4个氟原子，至少选自钛、锆、铪、硅与硼元素中的1个原子。任选地可离解的氢原子，任选地1个或多个氧原子；$_一种选自钴、镁、锰、锌、镍、锡、锆、铁与铜元素的阳离子成分，上述成分的阳离子总数与成分内的阴离子总数之比至少为1∶5；$_足够的游离酸以使该组合物的pH值在0.5～5.0的范围内；$_一种选自含磷的无机含氧阴离子与膦酸盐阴离子的成分；$一种选自水溶性与水可分散性有机聚合物与聚合物形成的树脂的成分，优选还包括一种选自钨酸盐、钼酸盐、钨硅酸盐与钼硅酸盐阴离子的成分。

All the ligands and complexes have been characterized with ~1H-NMR, MS and EA.X-Ray single crystal diffraction reveals that zirconium complex containing the tert-butyl substituted N_2O_2 ligand is an oxo- and hydroxyl-bridged dinuclear structure, which is possibly formed by partial hydrolysis of chlorides at one of the zirconium centers. A tetranuclear zirconium complex has been obtained and chacaterized, which is formed by complete hydrolysis of the chlorides at the zirconium centers.

通过研究配合物的单晶结构，我们发现叔丁基取代的不对称N_2O_2配体与ZrCl_4反应生成的锆配合物为氧桥和羟基桥连接的双核锆配合物，中间过程涉及单核锆配合物中氯原子部分水解，并得到氯原子部分水解的双核锆配合物和全部水(来源：8e6eAB67C论文网www.abclunwen.com)解的四核锆配合物的晶体结构，在晶体培养过程中发现双核锆配合物能够以手性自发拆分结晶析出。

By the time of its fall, most of the prisoners were writers who had written against the corruptions of the government.

到它被攻陷的时候，里面多数的犯人是写了反对政府贪污文章的作家。

The most obvious variation to ovum morphological character was that the color was changed from light green to sepiaceous in embryonic development, and all the ovums were almost hatched after 96h.

在胚胎发育过程中卵的形态特征最明显的变化是颜色从淡绿到深褐色，卵在发育96h后卵基本全部孵化。