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The effects of reaction time, mole ratio of reactants and amount of catalyst on yield of ketal were investigated by using the [SO3H-bPy] [H2PO4] ionic liquid as catalyst. Results show that the ionic liquid was an efficient catalyst for the ketalization with high conversion and selectivity in mild conditions.
以磺酸基功能化的吡啶磷酸类离子液体[SO3H-bPy][H2PO4]为催化剂,系统考察了反应时间、酮与醇的配比、催化剂的用量及催化剂重复使用、不同阴离子、阳离子等因素对反应的影响,优化了反应条件。
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The ketalization of cyclohexanone and 1,4-butanediol catalyzed by the Hβ zeolite was studied.Effects of reaction time,mole ratio of reactants and amount of catalyst on the yield of ketal were studied.Results showed that the Hβ zeolite was an efficient catalyst for the synthesis of ketal.
研究了Hβ分子筛催化1,4-丁二醇与环己酮的缩合生成新型七元环缩酮的反应,考察了反应时间、酮与醇的配比、催化剂用量、催化剂重复使用等因素对醛与醇缩合反应的影响。
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The results showed that molar ratio of cyclohexanone to ethylene glycol was 1∶1.4, the amount of catalyst was 2% cyclohexanone, amount of cyclohexane was 10 mL, the reaction time 2 h, the yield of cyclohexanone ethylene ketal reached 99.6% under the optimum condition.
通过正交实验得出了最佳反应条件:n∶n=1∶1.4、催化剂用量为环己酮质量的2%、带水剂环己烷用量10.0 mL、反应时间2 h,缩酮产率可达99.6%。
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The quantity of catalyst was equal to 0.6% of feedstocks,the reaction temperature was 78~110 ℃,and the reaction time was 45 min. The test results have shown thatH_4SiW_(12-O_(40)/MCM-48 is an excellent catalyst for synthesizing butanone 1,2-propanediol ketal with its yield reaching over 91.9%.
实验表明:H4SiW12O40/MCM-48是合成丁酮-1,2-丙二醇缩酮的良好催化剂,在n∶n(1,2-丙二醇)=1∶1.6,催化剂用量为反应物料总质量的0.6%,环己烷为带水剂,反应时间45 min的优化条件下,丁酮-1,2-丙二醇缩酮的收率可达91.9%。
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The results show that calix[6] arene-bismetalloporphyrins possess much higher catalytic activity than the corresponding metalloporphyrin while displaying the sam eselectivity by giving rise to acetophenone as the ketonic component in excellent yield.
研究了杯[6]芳烃-双金属卟啉在氧化异丙苯中的催化行为,结果表明杯[6]芳烃-双金属卟啉比之相应的金属卟啉具有更高的催化活性,并表现同样的选择性,生成苯乙酮和醇组份。
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The results show that trametes versicolor has a strong ability to yield laccase and can effectively degrade cotton stalk.
结果表明,Trametes versicolor有强的产漆酶能力,能对棉秆有效降解。
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Results The density of the total flavone of Leonurus was X=0.4099mg/ml and the rate of recovery was 101.6%,which had a highly purity and yield rate.
结果 测得样品中总黄酮的含量X=0.4099mg/ml,回收率为101.6%,其纯度和产率均较高。
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Result For leonurus hetreophyllus, theexperimental results show that the hightest extraction yield can be obtained when microwave irradiation time is 5 minutes under the condition of the 640 power, the ratio of sample weight to solvent volume is 1 to 40, the immersion in water for 60 minutes.
结果 鱼腥草用微波火力640w、微波作用时间5 min、固液比1:40(g/ml及浸泡时间60 min,鱼腥草中总黄酮的提取效果最佳。
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The results indicate that different molecular weight of dextran could be obtained by direct fermentation,and the acid hydrolyzing in the old technology be avoided.The yield reached the maximum by controlling the pH value to be 8.0,and the inorganic salt could promote the growth of the Leuconostoc mesenteriodes with the effect of promotion being Mn2++Ca2+>Mn2+>Ca2+.
结果表明:通过定向发酵技术可得到符合要求的不同分子量的右旋糖酐,避免了老工艺中酸水解工艺;控制发酵培养基pH值为8.0,可使产率最大;无机盐离子Mn2+和Ca2+能促进L.M菌的生长,其促进菌生长的程度大小依次为:Mn2++Ca2+>Mn2+>Ca2+。
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This thesis consists of four chapters:Chapter 1: Michael addition of chalcones with active methylene compounds such as diethyl malonate, ethyl acetoacetate and nitromethane catalyzed by potassium hydroxide in anhydrous ethanol results Michael adducts in 72-98% yield under ultrasound irradiation in 25-150min.
第一章:研究了超声辐射下,氢氧化钾催化的查耳酮与活泼亚甲基化合物如丙二酸二乙酯、乙酰乙酸乙酯和硝基甲烷的迈克尔反应。
- 推荐网络例句
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They weren't aggressive, but I yelled and threw a rock in their direction to get them off the trail and away from me, just in case.
他们没有侵略性,但我大喊,并在他们的方向扔石头让他们过的线索,远离我,以防万一。
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In slot 2 in your bag put wrapping paper, quantity does not matter in this case.
在你的书包里槽2把包装纸、数量无关紧要。
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Store this product in a sealed, lightproof, dry and cool place.
密封,遮光,置阴凉干燥处。