查询词典 x ray diffraction

This could be a fascinating method for the practical syntheses of chiral synthons as valuable building blocks and important medicinal intermediates.3.Series of novel optical pureγ-aryl-1H-1,2,4-triazole derivatives were designed and synthesized by using the chiral auxiliary(Oppolzer\'s sultam),and all these target compounds were structurally characterized by ~1H NMR,~(13)C NMR,MS and elemental analysis,at the same time,some representative compounds have been elucidated by X-ray diffraction analysis.

应用手性辅剂樟脑磺内酰胺的手性诱导作用，设计合成了一系列光学纯的γ-芳基-1H-1，2，4-三唑类衍生物，所有目标化合物都采用了~1H NMR、~(13)C NMR、MS和元素分析进行了结构表征，同时也获得了部分代表性化合物的晶体结构，进一步确证了化合物的结构。

1H-imidazolyl)-1H-imidazolium chloride-4-aminobenzoic acid, 2,2-bi-1H-imidazolium bis(3,4,5-trihydroxy benzoate) tetrahydrate and bis2-(2-1H-imidazolyl-1H-imidazolium 3-carboxy-4-hydroxybenzene-sulfonate monohydrate have been synthesized and characterized by X-ray diffraction methods.

在化合物中，晶体结构中的基本单元是一个通过氢键模式R_2~2(9)和R_2~1(7)构成的氢键三聚体PABA…H_3biim~+…Cl~-，这个三聚体基本单元又通过N-H…Cl氢键相互作用形成了一维带状结构。

These complexes are structurally identified by single-crystal X-ray diffraction to show a variety of metal nuclearity from mononuclear to tetranuclear and dimensionality from 1-D to 3-D.

单晶结构分析表明这些化合物具有多种金属核数（从1到4）以及多种结构维数。

X-ray diffraction, scanning electron microscope, energy dispersive spectrum and laser Raman spectrum analysis were used to identify thaumasite in paste sample stored in 10% of MgSO_(4) solution at different temperatures .

钙矾石型和石膏型等硫酸盐侵蚀破坏机理已得到广泛研究与认同，然而另一种硫酸盐破坏类型———碳硫硅钙石型却没有受到应有重视。

CH3OH has been designed, synthesized and characterized by X-ray diffraction analysis. In this dinuclear complex, it is worthy of notice that the source of tridentate chelate atoms (1N2O) of IDA is different from that of the reported complex.

合成过程中，我们还首次得到了与1，10-邻菲咯啉及亚氨基二乙酸络合的铜的不对称双核配合物晶体。

In this thesis, on the one hand, two new tripodal ligands and twenty-three of their lanthanide complexes were synthesized, and their fluorescence properties were investigated, on the other hand, nine new copper and silver complexes with six kinds of tripodal ligands were synthesized and their crystal and molecular structures were determined by X-ray diffraction analysis.

本论文一方面合成了两个新三脚架配体的23个稀土配合物，并对它们的发光性能进行了探讨；另一方面得到了涉及六种三脚架配体的9个铜、银配合物，并测定了它们的晶体结构。

The CoFe2O4/TiO2 magnetic nano-photocatalysts has fairly good magnetic property. The X-ray diffraction, transmission electron microscopy and ultraviolet-visible technique were used to analyze the phase structure, size and spectrum response scope of the samples. The XRD indicated the anatase TiO2 was formed when TCF modified by plasma. The size of CoFe2O4 particles was about 20 nm. The diameter of CoFe2O4/TiO2 particles is in the range of 30~40 nm. So the shell of TiO2 enwraps closely around the core and the thickness is in the range of 10~20 nm.

运用VSM技术对样品磁性能进行研究，结果表明：等离子体修饰后的复合材料仍具有较高的饱和磁化强度，可在外加磁场作用下实现催化剂在水中的分离与回收；样品的XRD、TEM和UV-Vis分析测试结果表明：等离子体修饰后的复合材料有锐钛矿型TiO2存在；TEM谱图显示磁核CoFe2O4的平均粒径约为20 nm，TCF复合粒子的粒径约为30~40 nm，TiO2包覆层的厚度为10~20 nm。

Differential scanning calorimeter,X-ray diffraction and scanning electron microscopy were used to study the effect of nucleating agent ZrO_2 on crystallization behavior and microstructures of the glass system.

采用DSC、XRD、SEM等分析测试方法研究了氧化锆含量对锗酸盐玻璃的析晶行为与显微结构的影响。

The crystal structures have been determined by X-ray diffraction method, which show that the new complex [Co2-Co(2)(0H2)s] belongs to the bridging binuclear complex and the system of monoclinic with space group P211~,unit cell parameters a8.3850(10)A, b=27.386(4) A, c=9.610(2) A,~=98.280(10)~,V=2 183.8(6) A3 , Z=4, Dc=l.746Mg/m3,~i =l.597mm, F(000)=1168, Final R=O.0253 and wR=O.0610 S1.009 ,The two Co2~ are in distorted octahedrons. The part of [2Co] possess an approximate D2d symmetry, while the part of [OCo(2)(0H2)5] has an approximate C2 symmetry.

结构分析表明配合物(1)[Co1，(DPC2-Co(2)(OH2)5]是一个未见报导的桥联双核配合物，属单斜晶系，空间群为P2_1／c，晶胞参数：a=8.3850(10)A，b=27.386(4)A，c=9.610(2)A，β=98.280(10)A，V=2183.8(6)A~3，Dc=1.746Mg／m3，Z=4，μ=1.597mm-1，F(000)=1168，结构偏离因子R=0.0253和ωR=0.0610，吻合因子S=1.009，Co_(1)和Co_(2)的配位多面体皆为扭曲正八面体，[_2Co_(1)]部分具有近似D_(2d)对称性，[OCo(2)(OH_2)5]部分具有近似C_2对称性。

Ultra-high strength 23Co 14Ni 12Cr3MoE steel was shot peened and the surface residual stress of shot-peened specimens was determined during rotating bending fatigue by X-ray diffraction method.The surface residual stress decreases greatly in the first 10 cycles and it is steady alter 100 cycles.

工件表面的残余应力，对其疲劳性能具有重要的影响，喷丸强化工艺主要利用的就是在表层产生一定数值大小的残余压应力以提高疲劳抗力，但喷丸残余压应力在疲劳过程中并不是稳定的，在一定外力或/和温度的单独或共同作用下，残余应力可发生松弛['一5]。

According to the clear water experiment, aeration performance of the new equipment is good with high total oxygen transfer coefficient and oxygen utilization ratio.

曝气设备的动力效率在叶轮转速为120rpm～150rpm时取得最大值，此时氧利用率和充氧能力也具有较高值。

The environmental stability of that world - including its crushing pressures and icy darkness - means that some of its most famous inhabitants have survived for eons as evolutionary throwbacks, their bodies undergoing little change.

稳定的海底环境─包括能把人压扁的压力和冰冷的黑暗─意谓海底某些最知名的栖居生物已以演化返祖的样态活了万世，形体几无变化。