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Dealcoholization temperature markedly influences the surface area and porosity of the resultant MAO-supports. When the support was pretreated at lower or higher temperature, the corresponding MAO-support shows very low surface area;2.XRD and IR analyses indicate that MAO has reacted with the residual ethanol in the supports, which is an important manner to get MAO fixed on the carrier. Morever, XPS analyse indicates that MAO can also be coordinated with MgCl_2, which is another way to get MAO fixed on the support;3.ICP and EDX analyses indicate that dealcoholization temperature not only determined the element content on the solid catalyst, but also influences the element distribution on the carrier;4.The activities of the supported phenoxy-imine catalysts and the properties of resultant polymers are strongly dependent on the dealcoholization temperature. The support (MSP-5) obtained by treating MgCl_2·2.56C_2H_5OH at 160℃for 4 h, then modified by MAO is very effective for immobilizing complex 3, the resultant solid catalyst (MSPC-5) shows very high activity in ethylene polymerization, and its kinetics of polymerization is stable during the reaction process. Finally, PEs with spherical morphology and high bulk density (over 0.35g/ml) were obtained, without reactor fouling;5.In this work, polymerization conditions such as alkylaluminums, Al/Zr ratio, temperature and H_2 had a pronounced effect on the activity of MSPC-5 and properties of PE;(3). New MgCl_2-Supported Single-Site Catalysts for Ethylene PolymerizationIn this work, a kind of new MgCl_2 support was obtained by anhydrous MgCl_2 co-milled with solid MAO, and it is a creative contribution. Then some single-site catalysts were supported on the new MgCl_2 support, and the resulted solid catalysts were tested in ethylene polymerization, the results indicated that:1.XRD and IR analyses indicate that MAO does be coordinated with MgCl_2, which is in good agreement with the results obtained by XPS;2.co-mlling time had no obvious effect on the texture of support after 12 hours;3.In this work, MgCl_2 was co-milled with solid MAO for different hours, and then complex 3 was supported on these co-milled supports. It was found that co-milling time markedly influences the activity of solid catalysts, but it had negligible effect on the kinetic profile and the properties of resultant PE.
XPS研究结果表明,MAO不仅仅只和乙醇作用,MAO还与MgCl_2本身有一定的作用,这是一个极为重要的发现;3、通过ICP和EDX表征,发现载体的脱醇温度直接影响着元素在固体催化剂中的含量及分布;4、脱醇温度极大地影响着负载苯氧基亚胺类催化剂的活性和聚合物的性能,特别是原始载体经160℃活化4小时制备得到的固体催化剂MSPC-5的活性明显高于其他脱醇温度条件下制得的固体催化,并且催化剂寿命长,表现出稳定的动力学行为,最终获得了高堆密度(大于0.35g/ml)的球形聚乙烯颗粒;5、本文选择MSPC-5为研究对象,考察了聚合反应参数对催化剂的活性及其聚合物的影响,研究发现:不同的烷基铝对催化剂具有非常重要的影响,特别足TIBA对MSPC-5的助催化活性最高,烷基铝的加入量有一个较佳值,聚合温度为80度时活性最高,H_2的加入使催化剂的活性明显降低且聚合物的分子量也减小;、新型氯化镁载体负载单活性中心催化剂催化乙烯聚合本文创造性采用固体MAO与无水氯化镁直接进行共研磨,制备出了一种的新型的氯化镁载体,并将该载体用于多种单活性中心催化剂的负载化研究,研究表明:1、通过BET、XRD的表征,再次证实了MAO与MgCl_2之间具有直接作用,与XPS的研究结果相一致;2、当研磨时间高于12小时时,延长研磨时间对载体的结构没有显著的影响;3、将配合物3负载于共研磨时间不同的一系列载体上,乙烯聚合结果表明,尽管共研磨时间对负载催化剂的活性具有明显的影响,但是它对聚合物的性能以及催化剂的影响不明显。
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Dealcoholization temperature markedly influences the surface area and porosity of the resultant MAO-supports. When the support was pretreated at lower or higher temperature, the corresponding MAO-support shows very low surface area; 2.XRD and IR analyses indicate that MAO has reacted with the residual ethanol in the supports, which is an important manner to get MAO fixed on the carrier. Morever, XPS analyse indicates that MAO can also be coordinated with MgCl_2, which is another way to get MAO fixed on the support; 3.ICP and EDX analyses indicate that dealcoholization temperature not only determined the element content on the solid catalyst, but also influences the element distribution on the carrier; 4.The activities of the supported phenoxy-imine catalysts and the properties of resultant polymers are strongly dependent on the dealcoholization temperature. The support (MSP-5) obtained by treating MgCl_2·2.56C_2H_5OH at 160℃for 4 h, then modified by MAO is very effective for immobilizing complex 3, the resultant solid catalyst (MSPC-5) shows very high activity in ethylene polymerization, and its kinetics of polymerization is stable during the reaction process. Finally, PEs with spherical morphology and high bulk density (over 0.35g/ml) were obtained, without reactor fouling; 5.In this work, polymerization conditions such as alkylaluminums, Al/Zr ratio, temperature and H_2 had a pronounced effect on the activity of MSPC-5 and properties of PE;(3). New MgCl_2-Supported Single-Site Catalysts for Ethylene Polymerization In this work, a kind of new MgCl_2 support was obtained by anhydrous MgCl_2 co-milled with solid MAO, and it is a creative contribution. Then some single-site catalysts were supported on the new MgCl_2 support, and the resulted solid catalysts were tested in ethylene polymerization, the results indicated that: 1.XRD and IR analyses indicate that MAO does be coordinated with MgCl_2, which is in good agreement with the results obtained by XPS; 2.co-mlling time had no obvious effect on the texture of support after 12 hours; 3.In this work, MgCl_2 was co-milled with solid MAO for different hours, and then complex 3 was supported on these co-milled supports. It was found that co-milling time markedly influences the activity of solid catalysts, but it had negligible effect on the kinetic profile and the properties of resultant PE.
XPS研究结果表明,MAO不仅仅只和乙醇作用,MAO还与MgCl_2本身有一定的作用,这是一个极为重要的发现; 3、通过ICP和EDX表征,发现载体的脱醇温度直接影响着元素在固体催化剂中的含量及分布; 4、脱醇温度极大地影响着负载苯氧基亚胺类催化剂的活性和聚合物的性能,特别是原始载体经160℃活化4小时制备得到的固体催化剂MSPC-5的活性明显高于其他脱醇温度条件下制得的固体催化,并且催化剂寿命长,表现出稳定的动力学行为,最终获得了高堆密度(大于0.35g/ml)的球形聚乙烯颗粒; 5、本文选择MSPC-5为研究对象,考察了聚合反应参数对催化剂的活性及其聚合物的影响,研究发现:不同的烷基铝对催化剂具有非常重要的影响,特别足TIBA对MSPC-5的助催化活性最高,烷基铝的加入量有一个较佳值,聚合温度为80度时活性最高,H_2的加入使催化剂的活性明显降低且聚合物的分子量也减小;、新型氯化镁载体负载单活性中心催化剂催化乙烯聚合本文创造性采用固体MAO与无水氯化镁直接进行共研磨,制备出了一种的新型的氯化镁载体,并将该载体用于多种单活性中心催化剂的负载化研究,研究表明: 1、通过BET、XRD的表征,再次证实了MAO与MgCl_2之间具有直接作用,与XPS的研究结果相一致; 2、当研磨时间高于12小时时,延长研磨时间对载体的结构没有显著的影响; 3、将配合物3负载于共研磨时间不同的一系列载体上,乙烯聚合结果表明,尽管共研磨时间对负载催化剂的活性具有明显的影响,但是它对聚合物的性能以及催化剂的影响不明显。
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In the second part the critics are uncertain as to whether the last editing was the work of the Deuteronomic or the Priestly editor; they agree in this that the same hands those of J, E, D, and P are at work in both parts, and that the portions which must be assigned to P have characteristics which are not at all found in his work in the Pentateuch.
在第二部分( 13 - 22 )的批评不确定是否是最后的编辑工作的Deuteronomic或祭司编辑;他们同意在此,同样的人手中的J ,电子商务, D和P的在工作在这两个地区,而且部分,必须分配到P的特徵,不是所有在工作中发现的摩西五。
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We deeply understood the work method with 8259A in this topic, work principle and work condition;Knew to break off existent important meaning in the meantime, break off the popular comprehension can think to be a "abnormality", under the sistuation that have excrescent occurrence output circumstance, at two procedures wh ic h put in the at present thing to win election to choose to even need to i
在本课题中我们深刻的了解到了8259A的工作方式,工作原理和工作状况;同时知道了中断存在的重要意义,中断通俗的理解可以认为是&异常&,在有异常发生的情况下产生的情况,在两件摆在眼前的事物中选择更需要立刻执行响应的程序,即是在中断中所说的优先级。
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We deeply understood the work method with 8259A in this topic, work principle and work condition;Knew to break off existent important meaning in the meantime, break off the popular comprehension can think to be a "abnormality", under the sistuation that have excrescent occurrence output circumstance, at two procedures which put in the at present thing to win election to choose to even need to immediately carry out to respond to, is in the interruption say of have the initiative class.
在本课题中我们深刻的了解到了8259A的工作方式,工作原理和工作状况;同时知道了中断存在的重要意义,中断通俗的理解可以认为是&异常&,在有异常发生的情况下产生的情况,在两件摆在眼前的事物中选择更需要立刻执行响应的程序,即是在中断中所说的优先级。
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Article 34 The administrative departments of work safety of the people's governments at the districted municipality level or at the county level shall take charge of the daily supervision and examination of the fireworks and firecrackers production enterprises that have obtained work safety licenses within the administrative regions thereof and shall report any problems, if any, as found in the supervision and examination to the administrative organ in charge of issuing work safety licenses in a timely manner.
第三十四条设区的市、县级人民政府安全生产监督管理部门负责本行政区域内取得安全生产许可证的烟花爆竹生产企业的日常监督检查,并将监督检查中发现的问题及时报告安全生产许可证颁发管理机关。
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Article 36 The administrative departments of work safety of the people's governments at the districted municipality level or at the county level shall take charge of the daily supervision or examination of the hazardous chemical production enterprises that have obtained work safety licenses within the administrative regions thereof and shall report any problem as found in the supervision and examination to the administrative organ in charge of issuing work safety licenses in a timely manner.
第三十六条设区的市、县级人民政府安全生产监督管理部门负责本行政区域内取得安全生产许可证的危险化学品生产企业的日常监督检查,并将监督检查中发现的问题及时报告安全生产许可证颁发管理机关。
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Dongguan public security will not forget, but even the bank gave up the bird, is not clear elsewhere, but in Yantian is the case, the bank (Agricultural Bank of China said that for the time being, And to say you grow up with really good hateful) on Saturdays and Sundays do not work well, you do not let it go to work, but at that time of day, teller machines are often of bad, you do not believe to see Sometimes a long row of the team, when their turn will come out of it, has sometimes broken, you have to change banks, but so many people that put hard-won days of leave, but the money was to Hu You, This is not, wanted to send money home to the (home only the Agricultural Bank), then went on Tuesdays, the results can be, others less your leisure, said that the money can only be 30,000 or more VIP users so that she can serve So that An Men to automatically deposit it, happen to know is: there is already a long queue, when their turn will come myself ah, the Lao PM would also like to go to work, then at noon on a come-hour rest period to the hard-won She is not to do since I was a halo home, so Anjiu for her to do to help, people can be that the birds do not you, not VIP user is not done, you can of us...
东莞的治安不好也就算了,可是连银行都给鸟起来了,别的地方不清楚,但在雁田却是如此,银行(暂且说农业银行,还说什么伴你成长,真的是好可恶)星期六及星期日不上班,好,你不上班也就算了,可是在那二天的时候,取款机却是经常性的坏,不信你去看看,有时排了好长的队,可轮到自己时它却坏了,有时是已经坏了,你不得不换个银行,可是那么多人,好不容易放天假,还要被钱给忽悠了,这还不算,本想寄点钱给家里,于是在星期二去了,可结果呢,人家闲你家少,说只能是30000钱以上的VIP用户才能让她伺候,让俺们到自动存款那,可要知道的是:那里已经是长龙了,什么时候轮到自个儿啊,老子下午还要上班的,中午就那么一个来小时的休息时间,好不容易来了,她既然不给办,我真是晕到家了,于是俺就求她,帮忙给办了,可人家就是不鸟你,不是VIP用户就是不办,你能咱的。。。
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I finished my school and decided to go to the university...now i understand that university is not useful and this is just spending my money not more...before i entered the university i lived with all my family:mother,father,me and sister...even in another flat,separate to our lived my grandfather and grandmother...then granpa died...i was going to 5-th class at school...when i entered the university i moved to another city and now lived alone...sometimes i visit them...now i'm going to a distance learning at my university and will travel and work...my work is connected with internet technologies,so i can work all over the worldin every country which i want...now i'm earning good money,even more than all my parents and feel not happy...because,Pic Top,i'm alone...this is really bad feelling...who is nanna?
我完成高中之后决定上大学。。。现在我明白了其实大学并不是那么的有用,对我来说除了花钱没有别的了。。在我进入大学之前,我一直与我整个家庭住在一起:我的父母和姐姐。。。甚至不远的另一间公寓里还住着我的爷爷奶奶。。之后爷爷去世了。。我当时在学校里即将要上第五节课。。有时我会看望他们。。而现在我在离家有一些距离的大学校园里读书,并且还要去旅游和工作。。我的工作与互联网技术有关。这使我能够走访全世界去工作,到每一个我想要去的国度。。现在我的收入不菲,甚至比我父母赚的加起来还要多,但我感觉不到快乐。。。因为。。Pic Top,我很孤独。。这种感觉糟糕透了。。谁是nanna奶奶)?
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Qualification:Have at least 8 years J2EE programming and architecture design experience. Have Ph.D or master degree on computer engineering or computer science. Have in-depth knowledge on J2EE and web technologies, including Web2.0 framework, Portal/Portlet, Struts/Struts2, Hibernate, Spring, JMS, Jboss tool kit, application servers, WSDL. Have deep domain knowledge on computer applications, grid computing and virtualization, and rich experience with customers in those domains. Be familiar with software engineering and produce development process. Have work experience with multiple OS, e.g. UNIX and Windows. Have serious work attitude, good team work and communication skill. Good at English reading and writing. Prefer to speak English fluently.
人员要求:至少八年J2EE开发及架构设计经验;有计算机工程/计算机科学博士或硕士学位;在J2EE和Web领域有很深的研究和广博的知识,包括Web 2.0架构,Portal/Portlet, Struts/Struts2, Hibernate, Spring, JMS, Jboss tool kit, application servers, WSDL;对计算机应用,网格计算,虚拟计算领域有很深的了解和客户经验;熟悉软件工程和软件产品开发流程;有多种操作系统上的工作经验,如Linux, Solaris, AIX和 Windows等;有良好的团队协作精神,认真负责、精益求精的工作态度和沟通能力;有很强的英语文档编写能力;有流利的英语口语能力者优先。
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- 推荐网络例句
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According to the clear water experiment, aeration performance of the new equipment is good with high total oxygen transfer coefficient and oxygen utilization ratio.
曝气设备的动力效率在叶轮转速为120rpm~150rpm时取得最大值,此时氧利用率和充氧能力也具有较高值。
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The environmental stability of that world - including its crushing pressures and icy darkness - means that some of its most famous inhabitants have survived for eons as evolutionary throwbacks, their bodies undergoing little change.
稳定的海底环境─包括能把人压扁的压力和冰冷的黑暗─意谓海底某些最知名的栖居生物已以演化返祖的样态活了万世,形体几无变化。
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When I was in school, the rabbi explained everythingin the Bible two different ways.
当我上学的时候,老师解释《圣经》用两种不同的方法。