查询词典 vicinal

Hydrolysis of 2,3-epoxy-butanol-p-methylbenzensulfonate (12) in acidic aqueous media gave chiral vicinal diol (2) in high enantioselectivity (95% ee).2. The chiral vicinal diol s play an important role in organic .

手性邻二醇在有机合成中具有重要的用途，它们是理想的手性合成砌块，可用于合成多种手性药物，许多含有手性邻二醇结构的药物或生物活性物质将有更重要的应用。

The invention relates to a method for the extraction of keratin from dead animal skins, characterised in the treatment of dead animal skins with a substance of general formula, or at least one corresponding alkali metal, earth alkali metal, ammonium, or phosphonium salt, the variables having the following definitions: R, R = together or independently, H, C6-C14 aryl, C1-C12 alkyl, unsubstituted or substituted with one or several SH or OH groups, R, R = together or independently, H, C6-C14 aryl, C1-C12 alkyl, unsubstituted or substituted with one or several SH or OH groups, whereby at least one of R or R is not H, or R and R are not H and two vicinal groups of R to R together may be C3-C10 alkylene, R = H, C1-C12 alkyl, H-C=O or C1-C4-Alkyl-C=O, X, X, X and X = OH, SH or NHR, whereby where Rto R contains at least one sulphur atom, at least one of X to X = SH and where R to R contains no sulphur atom, at least two of X to X= SH.

本发明涉及一种从死亡动物原皮中除去角质的方法，其特征在于用通式I的物质或至少一种对应的碱金属盐、碱土金属盐、铵盐或∴盐处理死亡动物原皮，式I中各变量定义如下：R 1 和R 4 相同或不同且选自氢、C 6 -C 14 芳基和C 1 -C 12 烷基，其未被取代或被一个或多个SH或OH基团取代；R 2 和R 3 相同或不同且选自氢、C 6 -C 14 芳基和C 1 -C 12 烷基，其未被取代或被一个或多个SH或OH基团取代，其中至少一个基团R 2 或R 3 不为氢，或R 1 和R 4 不为氢，且两个相邻基团R 1 -R 4 可以一起为C 3 -C 10 亚烷基；R 5 选自氢、C 1 -C 12 烷基、H-C＝O或C 1 -C 4 烷基-C＝O；X 1 、X 2 、X 3 和X 4 选自OH、SH和NHR 5 ，其中若R 1 -R 4 含有至少一个硫原子，则至少一个基团X 1 -X 4 为SH，以及若R 1 -R 4 不含硫原子，则至少两个基团X 1 -X 4 为SH。

In addition, a new vicinal diol with potential practical value was prepared by asymmetric pinacol coupling reaction under the inducement of substrate.

另外，利用底物诱导的不对称Pinacol偶联反应合成了具有潜在实用价值的新的手性邻二醇。

MeOH system at rt for 25min～60min, which gave vicinal diol in 41%～97% yield.

MeOH体系中反应，室温下 2 5min～ 60min内得到 41 %～ 97%的偶联产物邻二醇。

Pinacol reductive coupling reaction of aldehyde and ketone is one of the most important methods in forming C-C bond, which may also produce vicinal diol as valuable intermediate compound applied in the synthesise of natrual products.

醛酮的Pinacol还原偶联反应是合成C—C键的重要方法之一，同时合成的邻二醇类化合物是重要的有机合成中间体，已被应用于许多含有邻二醇结构的复杂天然化合物总合成中。

The strategy of building the syn-anti chiral vicinal diolmoiety of sphingosine intermediate and the synthetic studies of anti-fungal antibioticssphingofungin using sugar as chiral pool are also described.

这些物质生理作用极强，但在机体中储存量极少、结构具有高度不均一性、生物和化学稳定性又差，它们的化学合成具有十分重要的理论和应用意义。

Finally, laser induced thermoelectric voltage effect was measured for the first time in BT/BST superlattices grown on vicinal-cut single crystal substrates, which was not measured in BT and BST single-layer films.

最后，在倾斜单晶衬底上制备的BT/BST超晶格中还首次发现了在BT和BST单层膜中都没有发现的激光感生热电电压效应。

If Indian English still keeps vicinal, Indians will lose some parts of World Business.

如果印度英语依然保持如此本地话，印度人将失去世界经济的一部分。

A more general way to prepare vicinal diamines selectively is thus still sought after.

选择性地准备附近的 diamines 的一个比较一般的方法仍然如此追求。

It is a notable case when the vicinal slopes or excavations are likely to reduce significantly the bearing capacity of foundation.

临近基坑或边坡的既有建筑物地基承载力减损情况是一个值得关注的问题。

The circulation, consumption and reproduction of the trilogy have not only testified to its historical significance and literariness, but also invested it with new meanings.

该三部曲的流通、消费与再生产不仅验证了其历史意义及文学性，而切还赋予它以新的意义。

If he thought that he could buy me off, he would be wrong.

如果他认为他可以收买我，那他就大错特错了。