查询词典 vibronic

The energy levels of free metallic ion were calculated with a 13 parameters model including the 2-body and 3-body interactions. The Stark energy levels of crystal field were calculated using the model proposed by Newman based on 1 electron orbital approximation The f-f oscillator strength calculation includes the contribution of electrostatic-induced, ligand polarization, vibronic-induced, magnetic dipolar transitions.

其中，自由f离子能级计算采用包括双电子与叁电子组态相互作用的二三参数模型，晶体场Stark分裂计算采用单电子轨道近似，用Newman角叠加模型计算晶体场参数。f-f跃迁振子强度计算包括静电诱导偶极跃、配体极化偶极跃、振动诱导电偶极跃迁及磁偶极跃迁的贡献。

Anharmonic vibronic oscillator model, two levels model, bond parameter model and bond charge model were established in 1960's, which came from classical or qualitative concepts.

非谐振子模型，双能级模型，键参数模型，键电荷模型，电荷转移模型，阴离子基团模型，双重基元模型。

Seven new vibronic transition bands were observed and analyzed.

观察并分析了7个新的振动谱带。

A new technique to characterize microstructure of RE complexes withcooperative vibronic spectra of RE ions is established and developed.

本文建立和发展了一种利用稀土离子的电子振动光谱来表征物质微观结构的新技术。

The correlation between the vibronic spectrum of Eu〓 and the site substitution of other co-doped ions was first studied, and many useful data can be derived from the vibronic spectrum.

首次研究了Eu〓振动光谱与其它掺杂离子格位取代的关系，发现从振动光谱的研究可以获得许多有用的信息。

A general form of Hamiltonian for vibronic Jahn-Teller systems is derived on the basis of adiabatic approximation and group theory. The electronic operators and active Jahn-Teller modes appeared in a vibronic system are also discussed.

本文基于绝热近似和群论导出了电声耦合系统的哈密顿量的一般形式，讨论了电声耦合系统中的电子算符和活跃的声子模式。

Based on the analysis of the Jahn-Teller effect, vibronic interaction and the resolution of group representations, the possible geometrical configurations of 〓 have been derived for the first time. The Gaussian-98 program has been used to optimize the geometrical configurations of 〓 based on B3LYP/6-311G method. It is found that there are at least six different stable geometrical configurations for 〓 The results show that the multiplicity of 2S＋1=7 for cluster 〓 is the most stable state among the eight geometry configurations.

基于多体项展式理论方法，研究得到了〓、HZrCo和〓三原子分子的分析势能函数，这些分析势能函数正确反映了它们的结构特点，可用于研究HZrCo、〓和〓的微观分子反应动力学。3从群的分解与直积理论出发，通过Jahn-Teller变形，vibronic相互作用以及群表示的分解的分析，首次导出了Jahn-Teller效应引起D〓和〓构型〓分子几何构型变化及其可能的电子状态。

The relationship between the ratio of intensity of the third vibronic band to that of the first vibronic band in pyrene monomer fluorescence spectrum and its environmental polarity is used to probe the effects of alkali-metal chlorides MCl(M+= Li+, Na+, K+) on the microenvironment of b-cyclodextrin cavity.

基于芘的单体荧光光谱振动结构与其所处环境极性的相关性，研究了碱金属氯化物对β-环糊精空腔微环境的影响。

The fluorescent intensity ratio of the first vibronic peak (λ=373 nm) to the third vibronic peak (λ=383 nm) of pyrene solubilized in micelle decreased gradually, which was different from the conventional surfactant, such as SDS. The aberrant property indicated a broad micelle size for the m+nAr-T surfactants. That is, the aggregates of the studied surfactants gradually grew in size with increasing concentration over wide concentration range.

与传统表面活性剂不同，增溶于N-酰基牛磺酸钠胶团中的芘的第一个电子振动峰(λ=372nm)的荧光强度I1和第三个电子振动峰(λ=385nm)的荧光强度I3之比I1/I3值随着表面活性剂浓度的增加而缓慢降低，说明了N-酰基牛磺酸钠表面活性剂在低浓度区形成疏松的聚集体，随着浓度的增大则有更多的表面活性剂分子挤入已形成的聚集体。

The relationship of the amounts of emulsifier, organosilicon monomer (D4) and initiator with the ratio of fluorescence intensity between first vibronic peak of pyrene (λ= 373 nm) and third vibronic peak of pyrene (λ=384nm)Ⅰ1/Ⅰ3 were discussed during the emulsion polymerization process, in which pyrene was used as fluorescence probe. The polymerization behavior of the organosilicon-acrylate latex with core-shell structure was investigated in line with the relationship of monomer conversion and development of morphology in latex particles with the value of Ⅰ1/Ⅰ3 for probe pyrene during the polymerization process.

以芘为荧光探针，探讨了有机硅-丙烯酸酯核壳乳液聚合过程中，芘的第一振动峰(373nm处)与第三振动峰(384nm处)荧光强度的比值Ⅰ1/Ⅰ3与乳化剂、有机硅单体（D4）和引发剂用量之间的关系，并结合聚合过程中探针芘的Ⅰ1/Ⅰ3 峰值与单体转化率及乳胶粒形态演变之间的关系，研究了核壳结构有机硅-丙烯酸酯乳液的聚合行为。

Breath, muscle contraction of the buttocks; arch body, as far as possible to hold his head, right leg straight towards the ceiling (peg-leg knee in order to avoid muscle tension).

呼气，收缩臀部肌肉；拱起身体，尽量抬起头来，右腿伸直朝向天花板（膝微屈，以避免肌肉紧张）。

The cost of moving grain food products was unchanged from May, but year over year are up 8%.

粮食产品的运输费用与5月份相比没有变化，但却比去年同期高8％。