查询词典 valence electron

The luminescence properties were investigated with PL and PLE spectra.Emission peaks were at about 450 nm.This emission was ascribed to the recombination between the sulfur vacancy-related electron trap donor having an energy level just below the conduction band and the Ag-related hole trap acceptor above the valence band.

通过发射光谱和激发光谱对产品的光学性质进行研究，发射峰位于450 nm左右，归属于硫空位相关的电子陷阱施主和银相关的空穴陷阱受主的复合；激发峰位于333 nm左右，归属于ZnS基质的带边吸收。

Learning the valence shell electron pair repulsion theory, they need to determine the shapes of simple molecules with the help of models and 3-D animations.

通过学习价电子对互斥理论，在模型和3D 动画的帮助下，构建出分子的形状。

This paper analyzes shell electron pair repulsion theory, valence-bond theory and molecular orbital theory on molecular structure of noble gas compounds.

对稀有气体化合物的分子结构分别用"价层电子对互斥理论"、价键理论"和"分子轨道理论进行了分析处理。

The x-ray photoelectron spectroscopy of La-Pr-Mn-O reveals that the valence state of Pr include Pr〓, which indicates that the La-Pr-Mn-0 manganite is another new electron-doped CMR compound.

XPS谱研究表明：La-Pr-Mn-O中有pr〓存在，而且这种材料几乎在整个掺杂范围都是单相。

Upon this we measure the conbination energy spectrum and momentum spectrum of valence orbital electron of C2H6. furthmore we get the isolation spectrum of valence orbital electron of N2 and C3H8 for the first time.

在此基础上，测量得到乙烷分子(C_2H_6)价轨道电子的结合能谱和动量谱，并用EMS方法测量得到氮分子(N_2)和丙烷分子(C_3H_8)价轨道电子的电离能谱。

An element bonding parameter topological index HLA is proposed based on topological principle and valence shell electron structural character.

基于元素键参数拓扑指数原理以及镧系元素价层电子结构特征构建了一种新的拓扑指数HLA。

The density of states, the electron occupation of valence orbits and difference electron density are combined to analyze the viewpoint mentioned above.

并结合态密度、价轨的电子占据数和电子密度对其进行了综合分析。

Forbidden-band-width of mono-clinic phase of bismuth vanadate (mBiVO4) is high enough to 2.3-2.4 eV, it could be valence band to carry out entirely that hole band degrade organic pollutants,and the conduction band possesses high oxidizability to make for reduction of photoinduced electron,and oxidation potential of its valence band with 2.4 eV nearby could achieve decomposition of water and degradation of organic pollutants under visible light.

单斜晶相钒酸铋(mBiVO4)的禁带宽度为2.3 - 2.4 eV，它足够高的价带完全可以实现空穴对有机污染物的降解，并且导带位置也有利于光生电子的还原，具有较高的氧化能力，且其价带氧化电位位于2.4 eV附近，可实现在可见光下分解水和降解有机污染物。本文综述了mBiVO4应用于降解污染物、光解水产氧以及光电化学分解水的研究概况，及其在光催化降解有机物等领域的应用前景。

The novel molecular topological index was recommendedrelating to such atomic properties as electronegativity,electron number of valence shell,number of bonding electrons,the main quantum number of valence shell and bond length.

采用该拓扑指数对饱和烷烃、烷基苯、烷氧氯硅烷、卤代苯、含氮杂环化合物、碱金属卤化物及卤化锡的性质/活性进行了相关关系的研究。

The formal potentials in cyclic voltammograms of these 3+ valence complexes are followed: Co〓-TPPS (-0.08V )＞Fe〓TPPS (-0.14V)＞Mn〓-TPPS (-0.23V). The electrochemical reaction of Mn〓-TPPS is reversible, and both of Co〓-TPPS and Fe〓-TPPS are quasi-reversible. The standard heterogeneous rate constants of Co〓-TPPS and Fe〓-TPPS were determined to be 1. 4×10〓cm/s and 1.4×10〓cm/s respectively. The rates of electrode reaction are as followed: Mn〓-TPPS＞Co〓-TPPS＞Fe〓-TPPS, e.i. Mn〓-TPPS is the most easily oxidized by the dissolved oxygen, and Fe〓-TPPS is oxidized slower than Co〓-TPPS. Ni〓-TPPS can not be oxidized. It is considered that oxygen plays an important role in the valence change of central metal atom and the rate of electron transfer in some metalloporphyrins.

三价金属卟啉络合物在循环伏安图上可得到三价到二价的还原和氧化响应，电极电位从大到小排列为：Co〓-TPPS(-0.08V)＞Fe〓-TPPS(-0.14V)＞Mn〓-TPPS(-0.23V)，电极反应可逆性也不相同，Mn〓-TPPS是可逆过程，Co〓-TPPS、Fe〓-TPPS是准可逆过程，实验测得Co〓-TPPS的标准电极反应速率常数ks＝1.4×10〓cm/s，Fe〓-TPPS的ks＝1.4×10〓cm/s，电极反应的速率从大到小为：Mn〓-TPPS＞Co〓-TPPS＞Fe〓-TPPS，即Mn〓-TPPS最容易被溶解氧所氧化，Fe〓-TPPS被氧化的速度最慢，Ni〓-TMPyP不能被氧化，因此我们认为溶解氧对金属卟啉中心离子的价态和电子转移速率起着重要作用。

The split between the two groups can hardly be papered over.

这两个团体间的分歧难以掩饰。

This approach not only encourages a greater number of responses, but minimizes the likelihood of stale groupthink.

这种做法不仅鼓励了更多的反应，而且减少跟风的可能性。