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It was shown that the improvement of electric properties in 1%Eu-PZT can be attributed to Eu donor doping, which decreases the concentration of defects such as oxygen vacancies and holes, while the degradation in fatigue and leakage current properties shown in the films with more than 1mol% Eu dopant results from the apparently dominant acceptor doping, which increases the concentration of oxygen vacancies and holes.

结果表明,1mol%Eu施主掺杂,可以减少氧空位以及空穴等缺陷浓度,因此1%Eu-PZT薄膜的极化疲劳和漏电流特性得到明显改善;高于1mol%Eu的受主掺杂作用使薄膜中氧空位以及空穴等缺陷浓度增加,导致PZT薄膜电学性能恶化。

First, some critical problems in crystal growth like crystal seeding, Zn dephlegmation, geometrical selection and temperature fields are discussed in theory, and the possible kinds of defects appeared in crystal growth progress and the reasons are carefully researched. To control the concentration of Cd vacancies, a new method by which the Cd vacancies were compensated with excess Cd in the Cd rich starting materials has been developed, and a new kind of two-area tube furnace with good linear temperature distribution was designed.

首先,本文从理论上对坩埚下降法生长碲锌镉单晶体中的成核、Zn分凝、几何淘汰生长与温场等关键性问题进行了讨论,对在生长过程中可能出现的各种缺陷类型和形成原因进行了详细分析,提出了碲锌镉单晶体生长过程中Cd空位缺陷控制原理及方法,并针对坩埚下降法生长特点自行设计了两区域独立加热管式生长炉,获得具有较好线性分布的温场。

Based on introducing the grey system theory,this paper discusses on the principle of the forecast of equidimensional filling vacancies,advances the dynamic model of grey forecasting of equidimensional filling vacancies in the medium-long term load forecasting of power system,and forecasts the yearly load value of this area in the period of 1999-2009 with the model established by using the historical load data of some areas.

在介绍灰色系统理论的基础上,讨论了等维递补预测原理,提出了电力系统中长期负荷预测的灰色等维递补预测动态模型,并利用某地区的历史负荷数据建模预测出了该地区1999—2009年的年负荷值。

It was indicated by SEM spectra of ZnO thin films that the surface of the sample was leveled off, and the crystals were felsitic. It was found from the experiment that, with the increasing of substrate temperature, there were more oxygen vacancies in the films, which lead the conductance of the sample become larger , and the absorb edge of ZnO thin films shifted toward higher wavelength; with increasing of Ar:O2 ratio, there were lesser oxygen vacancies in the films, which lead the absorb edge of ZnO thin films shifted toward lower wavelength.

实验还发现,随着衬底温度的升高,薄膜中产生的氧空位将会增多,使得ZnO薄膜的电导逐渐增大,而且其紫外透射吸收截止边带向高波长方向漂移;随着氩氧比例的增加,薄膜中的氧缺陷相对减少,薄膜的透射吸收截止边向低波长方向漂移。

The FBI said on Monday it had launched one of the largest hiring blitzes in its 100-year history involving 2,100 professional staff vacancies and 850 special agents aimed at filling its most critical vacancies.

美国联邦调查局于本周一宣布,该机构日前启动了其100年历史上规模最大的一次招聘行动,此次招聘的职位包括2100名专业人士和850名特工,填补最关键岗位的空缺。

The FBI said on Monday it had launched one of the largest hiring blitzes in its 100-year history involving 2,100 professional staff vacancies and 850 special agents aimed at filling its most critical vacancies.

周一,FBI宣布启动它百年历史上最大一次招聘,涉及到2100个专业岗位和850个特工,以填补最关键的岗位空缺。

The results show that although both Ni substitution and Mg vacancies are effective in desorbing hydrogen at lower temperatures, the substitution of Ni at the Mg site is energetically more favorable than the formation of Mg vacancies. The Ni atoms of NiF2 can replace some Mg atoms of MgH2 systems, the reaction of NiF2+3MgH2=MgF2+Mg2NiH4 during mill process is accelerated, thus, MgH2 with the higher stability can be changed into Mg2NiH4. Because of a ternary hydride Mg2NiH4 with lower stability forming, the dehydrogenating properties on Ni doped MgH2 systems are improved.

结果表明:Ni替代Mg和创造Mg空位对MgH2体系解氢而言,均发挥有益作用,而形成Mg空位所需能量(6.51 eV)高于Ni替代Mg所需能量(2.12 eV),表明低温下Ni替代Mg对MgH2体系解氢而言更有利,至此NiF2中的Ni替代MgH2中的Mg,有利于加速化学反应NiF2+3MgH2=MgF2+Mg2NiH4向右进行,使结构稳定的MgH2发生转变,生成结构不稳定的Mg2NiH4,这样体系解氢过程不是通过MgH2,而是转变为通过Mg2NiH4进行,因此,Ni掺杂提高了MgH2体系的解氢性能。

The main creating aspects are finding and clarify such a fundamental physical process that the grain boundaries emit vacancies under compressive stress to induce solute non-equilibrium grain boundary dilution and absorb vacancies under tensile stress to induce non-equilibrium grain boundary segregation, formulizing the structural equations and the composition equations in force equilibrium in grain bounary region to describe this physical processes and the kinetic equations for non-equilibrium grain boundary segregation under tensile stress, calculating the modulus in grain boundary region from the expermental data of grain bounday segregation using the structure and coposition equations and calculating the diffusion coefficients of vacancy-solute atom complexes using the kinetic equation simulating the experimental results of grain boundary segregation.

本项目的主要创新点是,发现并阐明了弹性应力场作用下空位与晶界交互作用的基本物理过程:在张应力作用下,晶界会吸收空位,引起溶质非平衡晶界偏聚;压应力作用下,晶界会发射空位,引起非平衡晶界贫化。建立了描述此物理过程的晶界区力学平衡的结构方程和成分方程;?建立了张应力引起的非平衡晶界偏聚动力学方程?;用晶界区力学平衡的结构方程和成分方程?,首次通过实验测量计算出多晶材料晶界区的弹性模量;通过建立的动力学方程模拟实验结果,首次获得溶质原子-空位形成的复合体的扩散系数。

The result showed that the density of vacancies decreased and the dimension of vacancies increased as the aging time was prolongated.

结果发现,随着时效时间的延长,空位浓度不断降低,空位尺寸不断增大。

When vacancies happen in the Representation from any state, the executive authority thereof shall issue writs of election to fill such vacancies.

良好的人性,恰当的理性,和对上帝的信仰。规则的美在于简单,个性的美在于丰富,语言的美在于逻辑。

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