查询词典 trithiocarbonate

The possible mechanism was discussed. These bowl-shaped aggregates are promising candidates for nano reactor or drug carrier.4 2,7-dimethylene-1,4,6-trioxaspiro[4, 4]nonane with two vinyls was prepared to be used as electron-donor and crosslinker. The ATRP of this crosslinker and excess methylacrylate (used as electron-accpetor) was proved to mainly form homopolymers. With the chain-transfer agent S-1-Dodecyl-S\'-(α,α\'-dimethyl-α-acetic acid)trithiocarbonate, the copolymerization of the spiro hydrocarbon, maleic anhydride and MA by RAFT method produced star PMA.

这些由聚电解质复合物自组装形成的聚集体，在微反应器和药物释放等领域具有潜在的应用前景。4合成了双乙烯基的2，7-二亚甲基-1，4，6-三氧杂螺环烷，作为给电子单体和交联剂，与吸电子单体马来酸酐或过量的丙烯酸甲酯形成电荷转移络合物共同聚合，尝试了用ATRP和RAFT方法一步法合成星形聚合物。

In addition, environmental induced structure conversion of amphiphilic block copolymer film is also being investigated.3. Acrylic acid was polymerized directly in aqueous phase in the presence of a water-soluble trithiocarbonate as RAFT agent, and well-defined poly with low polydispersity index and high molecular weight was successfully prepared.

与同类文献比较，具有方法简单易操作并在以环境友好的水为介质的条件下反应的优点，且在高的单体和RAFT试剂比例与高转化率的情况下，没有观察到链转移的现象，为进一步合成高分子量的嵌段共聚物提供了潜在的方法。

Keywords: cyclic trithiocarbonate;RAFT polymerization; multiblock polymer; narrow molecular weight distribution.

中文关键词：环状三硫酯；RAFT聚合；多嵌段聚合物，窄分子量分布

Firstly, the homopolymerization of acrylamide was carried out in aqueous phase by reversible addition-fragmentation chain transfer radical polymerization using a trithiocarbonate as a chain transfer agent.

整个过程分为两步，首先在水溶液中，通过RAFT控制得到亲水性单体丙烯酰胺的均聚物；然后以得到的均聚物作为水溶性的大分子链转移剂，在水相中条件下参与亲油性单体苯乙烯无皂乳液聚合。

Dithioester and trithiocarbonate RAFT reagents were synthesizedby different methods, and were used for the polymerization of styrene ormethacrylates, by thermal, thermo-initiator and photo-initiation.

针对这一问题，本文尝试用三种方法合成了结构不同的RAFT试剂，考察了热引发、引发剂引发以及紫外光引发条件下，二硫酯／三硫酯调控的常见单体苯乙烯以及丙烯酸酯的RAFT聚合。

Bis-(2-oxo-2-phenyl-ethyl) trithiocarbonate(TTC2) were synthesized with anion-exchange resin for the first time.

首次用阴离子交换树脂法合成了S，S′-二三硫代碳酸酯(TTC2)。

A monomer, trithiocarbonate anion is successfully"immobilized"onto the polymeric support by reaction of CS〓 with strong-base quaternary ammonium in anion exchange resin with OH〓 form.

研究了把CS〓离子固定到阴离子交换树脂上，以及它在CS〓悬浮体系中和另一单体，α，α'-二溴代二羧酸甲酯在阴离子树脂表面上进行的亲核取代反应。

Reversible Addition-Fragmentation Transfer polymerization; Living Free Radical Polymerization; Photoinitiate polymerization; Trithiocarbonate

工程科技I，化学，高分子化学可逆加成-断裂链转移自由基聚合；活性聚合；紫外光聚合；苯乙烯St

CTTC undergoes ring-opening process to incorporate a trithiocarbonate moiety. The trithiocarbonate moiety in turn, functions as a reversible addition fragmentation chain transfer agent.

即环状三硫酯受到自由基进攻以后，发生开环反应并转化为线形三硫酯进入到聚合物的链中；线形三硫酯基团可以进一步作为RAFT试剂控制其后的聚合反应。

TrithiocarbonatesS,S\'-bis (α,α′-dimethyl-α-acetic acid) trithiocarbonate (TTC1),3-(2-carboxyethylsulfanylthiocarbonylsulfanyl) propionic acid (TTC3),2-(2-carboxyethylsulfanylthiocarbonylsulfanyl) propionic acid (TTC4) and2-(2-carboxyethylsulfanylthiocarbonylsulfanyl)-2-methylpropionic acid (TTC5) weresynthesized by phase transfer method.

用相转移法合成了S，S′-二(α，α′-甲基-α&-乙酸)三硫代碳酸酯(TTC1)、S，S′-二丙酸三硫代碳酸酯(TTC3)、S-丙酸-S′-三硫代碳酸酯(TTC4)和S-丙酸-S′-(α，α′-甲基-α&-乙酸)三硫代碳酸酯(TTC5)。

By the time of its fall, most of the prisoners were writers who had written against the corruptions of the government.

到它被攻陷的时候，里面多数的犯人是写了反对政府贪污文章的作家。

The most obvious variation to ovum morphological character was that the color was changed from light green to sepiaceous in embryonic development, and all the ovums were almost hatched after 96h.

在胚胎发育过程中卵的形态特征最明显的变化是颜色从淡绿到深褐色，卵在发育96h后卵基本全部孵化。