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In the 2a1 state of Ga3P2 ,the singly-occupied 5a1 orbital is made of Ga1....................on the other hand ,the 2b1 HOMO of the 2B1 state of the edge-capped tetrahedron consists of P1............................,where the P orbitals and Ga orbital make a significantly enhanced contribution .thus , while Ga orbitals make significant contributions to the 1A1 state with the distorted trigonal bipyramidal structure ,the P orbitals contribute significantly to the open shell MOs of the two structures.

另一方面在Ga3P2 2a1状态，被唯一占领的5a1轨道由Ga1做成。。。。。。。。。。。。。。。。。。。。，边缘加盖的四面体的2B1状态的2b1拉人包括P1 。。。。。。。。。。。。。。。。。。。。。。。。。。。。， P轨道和Ga轨道做显著改进的贡献。thus，而Ga轨道做对1A1状态的重大摊缴与被变形的三角bipyramidal结构的地方， P轨道对二个结构的开放壳MOs极大贡献。

The copper atom changed six-coordinate in a distorted octahedral configuration to five-coordinate in a distorted trigonal bipyramidal configuration.

在2个配合物中，金属Cu的配位数都由前体中的6转变为5，由原来前体中的畸变的八面体结构转变成畸变的三角双锥结构。

A rearrangement model for the complex and its isomers of the2+ was proposed, in which there could be two competed steric courses with the trigonal bipyramidal intermediate or intermediates.

利用[Co(3，3-tri)Cl]2+体系配合物及其异构体结构模型提出了一个2+型的配合物及其几何异构体相互转换所遵循的重排机理模型。认为在该类型配合物异构体转化过程中同时存在两个竞争途径，其中间过渡态或中间体分别为三角双锥或四角锥形式。

The Xray diffraction analysis of the compounds (3) and (4) shows the presence of an intramolecular coordination of oxygen to the tin atom giving rise to a fivemembered ring in which the metal exhibits a distorted trigonal bipyramidal geometry.

并通过X-射线衍射测定了（3）和（4）的晶体结构，其空间群均为P2〓/c，晶胞内分子数Z=4，分子结构是以锡原子为中心金属原子、含分子内O→Sn配位键五员环的扭曲三角双锥结构，碳碳双键的两个氢是顺式构型。

The crystal structures of two complexes have been determined by X-ray diffraction as: complex (11) is distorted octahedron configuration,α=15. 9002 (6), b=16. 2413 (5), c=23. 4401 (8)〓,β=90°, V=6053. 2 (4)〓, Z=8 and R=0.0531; complex (8) is trigonal bipyramidal configuration,α=9. 3476 (8), b=17. 4236 (13), c=9. 7836 (8)〓,β=91. 197 (3)°, V=1593. 1 (2)〓, Z=2 and R=0.0325, which shows that three secondary amine groups (N-1, N-2, N-3) of the glycosylamine ligand forms the equatorial plane, and the tertiary amine (N-4) and one Cl〓 are pointed on the apical positions.

分别对其进行X-ray衍射分析可以得出：配合物(11)的晶体数据为α=15.9002(6)，b=16.2413(5)，c=23.4401(8)〓，β=90°，V=6053.2(4)〓，Z=8 and R=0.0531，为畸变的八面体构型，而配合物(8)中，α=9.3476(8)，b=17.4236(13)，c=9.7836(8)〓，β=91.197(3)°，V=1593.1(2)〓，Z=2 andR=0.0325，为三角双锥构型，糖胺配体的三个氮原子（N-1，N-2，N-3）位于赤道平面上，而另外一个氮原子（N-4）和一个Cl〓位于轴向上。

The result is that both tin atoms are five-coordination, have a distorted trigonal bipyramidal geometry with an additional week interaction between another oxygen atom and tin atom.

分子中四个羧酸酯基有桥联双齿和单齿两种不同的配位模式；在内环锡和外环锡的配位单元中，锡均形成具有五配位的畸变三角双锥配位构型，同时另有一氧原子与中心锡原子之间有弱相互作用。

In the crystal, the tin atoms are five-coordinated in trigonal bipyramidal structure by bridging pyridine N atoms, resulting in the chain organotin compound.

该化合物中心锡原子为五配位三角双锥构型，并且通过4-吡啶甲酸配体的氮原子桥联作用形成一维无限链状结构。

The results indicated that the Sn atom in bistin Schiff base complexes was five-coordinated in trigonal bipyramidal geometries thanks to the existence of intermolecular ligands of Sn←N.

Schiff碱具有良好的配位作用，它们与不同的有机锡化合物配位后可以形成形式多样、结构不同的配合物，而且Schiff碱具有多种生物活性，与有机锡化合物生成配合物后，配合物的生物活性可能更宽广。

Base-catalysed hydrolysis is a typical course involving deprotonation leaving of Cl- and formation of the trigonal bipyramidal intermediate; edge displacement and ligand folding courses involve leaving of Cl- and formation of the square pyramidal intermediates.

典型的途径有经式异构体的碱催化水解，过程通过脱氢、脱氯以及三角双锥中间过渡态或中间体的形成来完成；另一途径为边沿取代及配体翻转历程，过程通过脱氯及四角锥的形成来完成。

Nm~3,μ= 4.836 mm~(-1), F(000)= 677, R = 0.0403, wR = 0.0673. Both of the complex adopt distorted trigonal bipyramidal geometry, with the basal plane defined by the SS atoms of the tridentate ligand and the oxo-group. The N of the tridentate ligand and the S of the monodentate ligand occupy two apical positions. Ionization of the sulphur atoms leads to a neutral compound.

0403，wR = 0.0673。配合物的两个部分均采取扭曲的三角双锥几何结构，基底面由三齿配体的两个硫原子与氧原子构成，三齿配体的一个氮原子和单齿配体的一个硫原子分别占取两个顶角位置，硫原子的离子化致使配合物呈电中性。

With Death guitarist Schuldiner adopting vocal duties, the band made a major impact on the scene.

随着死亡的吉他手Schuldiner接受主唱的职务，乐队在现实中树立了重要的影响。

But he could still end up breakfasting on Swiss-government issue muesli because all six are accused of nicking around 45 million pounds they should have paid to FIFA.

不过他最后仍有可能沦为瑞士政府&议事餐桌&上的一道早餐，因为这所有六个人都被指控把本应支付给国际足联的大约4500万英镑骗了个精光。