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Sc, there are two kinds of isotopes shaped body, the structure is trigonal system and the hexagonal Department, is found in the periodic table predicted decades before the first one confirmed the correctness of the periodic table of elements, which is very famous.

周期表中ⅢB族有银白色金属光泽的固体金属过渡元素,又属稀土元素,原子序数Z=21,原子量4959,化学符F号Sc,有两种同位素异形体,结构正方晶系和六角晶系,是周期表预言十年后才发现的第一个证实周期表正确性的元素,因而很有名气。

In this article, the stress inside a quantum-wire structure is studied. Based on the derived expression of the stress inside a quantum-wire structure with arbitrarily shaped cross section, the analytical solution of the stress inside a trigonal quantum-wire structure in an infinite matrix is obtained.

研究了晶格失配和热失配在半导体量子线结构中所产生的弹性场,在分析圆柱形量子线结构弹性场的基础上,推导得到了任意截面形状量子线结构解的一般形式,并给出无限大基体内横截面为三角形量子线结构的解析结果。

They are trigonal bipyamidal structure and ionic structure.

结果得到两种没有虚频的稳定结构,即三角双锥结构和离子结构。

One was trigonal bipyamidal structure, the other was ionic structure.

得到Ph_3PI_2离子形式,三角双锥形式,尖塔状三种结构形式。

The completely diagonalized Hamiltonian matrices of 3d2/3d8 ion configuration in the trigonal symmetry have been established by irreducible representation method. Taken into account the influence of the spin-spin coupling interactions omitted in previous publications, the spectra and the constants of crystal structure and zero-field splitting parameters of CsNiCl3 crystal and CsNiCl3: Mg2+ crystal are calculated and the influence of the doping to the spectra, the constants of crystal structure, zero-field splitting parameters and Jahn-Teller effect are studied. The results show that doping can change the structure of crystal which brings about the changes in the spectra and zero-field splitting parameters as well as Jahn-Teller effect.

应用不可约张量理论构造了三角对称晶场中3d2/3d8态离子的45阶可完全对角化的微扰哈密顿矩阵,在考虑了以前工作中被忽略的自旋-自旋耦合作用的基础上计算了CsNiCl3晶体和CsNiCl3:Mg2+晶体的基态能级、晶体结构、零场分裂参量和Jahn-Teller效应,研究了掺入Mg2+对CsNiCl3晶体的光谱、零场分裂参量及Jahn-Teller效应的影响和自旋单重态对基态能级的贡献,发现掺杂使得晶体结构产生畸变,从而改变晶体光谱的精细结构和零场分裂参量,不改变Jahn-Teller效应的分裂规律但改变分裂的大小。

The complete diagonalized Hamiltonian matrixes of order 120 of 3d~3/3d~7 ions configuration in the trigonal symmetry have been established by irreducible representation method and group theory,taking spin-orbit interaction,spin-spin interaction and spin-other-orbit interaction into account.

应用不可约张量方法和群的理论构造了三角对称晶场中考虑自旋-轨道相互作用,自旋-自旋相互作用和自旋-其它轨道相互作用的3d3/3d7态离子的可完全对角化的120阶微扰哈密顿矩阵。

The completely diagonalized Hamiltonian matrices of 3d2/3d8 ion configuration in the trigonal symmetry sites have been established by irreducible representation method. Taken into account microscopic magnetic interactions, the spectral fine structure, local structure and zero-field splitting parameters of V3+:α-Al2O3 and Ni2+:α-Al2O3 crystals are investigated as well as the influence of the doping.

应用不可约张量方法构造了三角晶场中3d2/3d8态离子的45阶可完全对角化的能量哈密顿矩阵,在考虑了微小磁相互作用的基础上计算了V3+:α-Al2O3和Ni2+:α-Al2O3晶体的光谱精细结构、晶体局域结构和零场分裂参量,研究了掺入Ni2+和V3+对α-Al2O3晶体光谱精细结构、晶体局域结构和零场分裂参量的影响。

The completely diagonalized Hamiltonian matrixes of order 120 of 3d3/3d7 ions configuration in the trigonal symmetry have been established by irreducible representation method and group theory,taking into account spin-orbit interaction and spin-spin interaction.The ground-state energy levels,the zero-splitting parameter and Jahn-Teller effect of ruby crystal were calculated with the matrixes.

应用不可约张量方法和群的理论构造了三角对称晶场中考虑自旋-轨道相互作用,自旋-自旋相互作用的3d3/3d7离子的可完全对角化的120阶微扰哈密顿矩阵,利用该矩阵计算了红宝石晶体的基态能级、零场分裂参量和Jahn-Teller效应,研究了自旋-轨道的自旋二重态对基态能级的贡献,证明其二重态对基态能级的贡献是不可忽略的,理论计算值与实验值相符合。

The compounds are isomorphous and crystallize in the trigonal R-3 space group.

这些化合物的晶体结构都属于三方R-3空间群。

The tin atom of the title molecule exists in a distorted- trigonal- bipyramidal geometry, defined by three carbon,one iodineand one oxygen atoms leading to a five - membered chelate ring. The x- ray analysis show tha...

标题化合物分子中的锡原子被配体的三个碳、一个碘和一个氧原子配位;配位原子是畸变的三角双锥构型;标题化合物具有与卤素发生取代反应而不发生加成反应的性质。

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