查询词典 triene

THE FIRST TOTAL SYNTHESIS OF TAXAMAIRIN B Taxamairin B, representive of rare naturally-occuring rearrang-ed 9(10→20)-abeo-8, 11, 13-triene diterpenoids, has been firstsynthesized by a eleven-step route in an overall yield of 8.19%,starting from commercially available catechol and 1,3-cyclohexan-dione. The improved Friedel-Crafts annulation, thermodynamicallycontrolled-geminal pairing methylation, the selective oxidation ofallyl group and the selective reduction of the less-hindrancecarbon-carbon double bond are the key steps.

二。美丽红豆杉素B的全合成研究 1，美丽红豆杉素B的首次全合成以价廉，易得的邻苯二酚和1，3-环己二酮为原料，经过改良的Friedel-Crafts烷基化反应，热力学控制的α，β-不饱和酮结构的α一位双烷基化，烯丙位的选择性氧化，以及选择性还原位阻较小的碳碳双键等十一步反应，以8.19％的总收率首次完成了美丽红豆杉素B的全合成。

When the tree changes from health to weak, the main terpene compounds changed, such as the amount of 3-carene, isolimonene,β-pinene, 4-carene were significantly enhanced, and santolina triene,α-fenchene,β-myrcene,β-phellandrene were declined. It will provide a basis for Monochamus urussovi Fischer to select suitable parasitic Picea jezoensis.

鱼鳞云杉树势由健康向衰弱转变时，主要烯萜类化合物含量发生变化，3-蒈烯、异柠檬烯、β-蒎烯、4-蒈烯、α-蒎烯等含量显著上升，而神圣亚麻三烯、α-葑烯、β-月桂烯、β-水芹烯等含量下降，这些烯萜类化合物的变化，为云杉大黑天牛定位选择适宜寄生的鱼鳞云杉提供了依据。

The results showed that there are 42 kinds of matters in health trunk, among which, the biggest relative mass fraction was santolina triene (16.04%), the second was α-fenchee (14.24%), and 43 kinds of matters were found from damaged trunk, the highest was β-pinene (18.07%), the second was α-pinene (12.39%).

结果表明：健康鱼鳞云杉干部挥发性物质共42种成分，其中相对质量分数最大的是神圣亚麻三烯(16.04%)，其次是α-葑烯(14.24%)；被害鱼鳞云杉干部挥发性物质共43种，其中相对质量分数最大的成分是β-蒎烯(18.07%)，其次是α-蒎烯(12.39%)。

RESULTS β-sitosterol(1),2,6-dihydroxyhumlan-9-3(12),7(13),9-triene(2),quercetin-7-methyl ester(3),protocatecheuic acid(4),shikimic acid(5),shikimic acid methyl ester(6) and daucosterol(7) were isolated from Ill...

结果从厚皮香八角果皮中分离得到了7个化合物，分别是β-谷甾醇(1)2、，6-dihydroxyhumulan-9-3(12)，7(13)，9-triene(2)、槲皮素-7-甲基醚(3)、原儿茶酸(4)、莽草酸(5)、莽草酸甲酯(6)和胡萝卜苷(7)。

Using extensie MS, U, and NMR spectral analyses, the structure has been established as compound 1, aureoerticillactam, a 22-atom macrocyclic lactam incorporating both triene and tetraene conjugated olefins.

运用包括质谱、紫外及核磁共振的多种光谱分析，解析确定了该化合物1的结构，是一个含有共轭三烯和共轭四烯的22元环大环内酰胺。

In these chromophores, the ring-locked triene employed as a conjugation bridge and the thiobarbituric acid moiety was as an electron acceptor in a D-π-A units.

在这些发色团中，环锁定的三烯和9，10-二氢蒽用作共轭桥，巴比妥酸和甲氧其分别作为吸电子和给电子基，组成非共轭的两个D-π-A单位。

Using extensive MS, UV, and NMR spectral analyses, the structure has been established as compound 1, aureoverticillactam, a 22-atom macrocyclic lactam incorporating both triene and tetraene conjugated olefins.

运用包括质谱、紫外及核磁共振的多种光谱分析，解析确定了该化合物1的结构，是一个含有共轭三烯和共轭四烯的22元环大环内酰胺。

Second, using DBU as the base for enolization of propargylic esters of unsaturated acids 18e-k, we developed a tandem Ireland-Claisen rearrangement /isomerization reactions. It has been shown that the reaction sequence affords triene molecules 42a-b and 43a-b in moderated to high yields. Interestingly, with allyl hexa-3,5-dienoates 18i-j as the substrate, the rearranged products underwent further aromatization to give uniquely substituted benzyl acids 44a-b.

其次，以含有活泼质子的烯酸炔丙酯18e-k为底物，在DBU为烯醇化碱、TMSCl为硅试剂的条件下，底物18e-h发生了Ireland-Claisen重排/异构化串联反应，得到完全共轭的三烯类化合物42a-b及43a-b；而以己二烯酸炔丙基酯18i-j为底物时，重排/异构化后的产物进一步发生电环化等反应最终得到芳构化产物——取代苯甲酸类化合物44a-b。

The searching result indicated that many components such as 2-Heptenal,-, Hexadecanal, Octadecanal, Megastigma-4, 6, 8-triene and Megastig-matrienone were identified the first time in studies of aroma components of Chaenomeles fruits.

检索结果表明，试验检测出的-2-庚烯醛、十六醛、十八醛、甲酸叶醇酯、辛酸环己酯、4，6，8-巨豆三烯、巨豆三烯酮等多种化合物，在木瓜果实香气成分研究中尚属首次发现。

Neither the killing of Mr Zarqawi nor any breakthrough on the political front will stop the insurgency and the fratricidal murders in their tracks.

在对危险的南部地区访问时，他斥责什叶派民兵领导人对中央集权的挑衅行为。

In fact,I've got him on the satellite mobile right now.

实际上 我们已接通卫星可视电话了