查询词典 tridentate

Nm~3,μ= 4.836 mm~(-1), F(000)= 677, R = 0.0403, wR = 0.0673. Both of the complex adopt distorted trigonal bipyramidal geometry, with the basal plane defined by the SS atoms of the tridentate ligand and the oxo-group. The N of the tridentate ligand and the S of the monodentate ligand occupy two apical positions. Ionization of the sulphur atoms leads to a neutral compound.

0403，wR = 0.0673。配合物的两个部分均采取扭曲的三角双锥几何结构，基底面由三齿配体的两个硫原子与氧原子构成，三齿配体的一个氮原子和单齿配体的一个硫原子分别占取两个顶角位置，硫原子的离子化致使配合物呈电中性。

Moreover, the relative percentage of each type of oxane bonds in the sample of APS-modified LDHs can be determined from their relative peak intensities; these results are summarized in Table 2.The oxane bonds attached on surface of AL-M can be mainly attributed to bidentate (T2)and tridentate(T3)types.

此外，相对比例的每种类型的oxane债券样品中黄芪多糖改性水滑石可确定其相对峰强度；这些结果的摘要列于表2 oxane债券所附表面的Al - M可以是主要原因以双齿和三齿（的T3 ）类型。

The study of crystal structure indicates that the complexes belongs to tetragonal,14(1)/a, a=b=27.047(5) A, c=14.103(3) A, a=b=y =90,V=10317(4)A3, Z=16, Dc=1.071g/cm3, F(000)=3408, R,=0.1395, R2=0.1766 and every unit of the tetranuclear complexes is four-coordinated to tridentate ligand and nitrogen atom in pyrazolone from other ligand. The complexes is slightly deformed square-planar geometry.

晶体结构研究表明，该配合物为四方晶系，空间群I4(1)/a，a=b=27.047(5)，c=14.103(3)，α=β=γ=90°，V=10317(4)，Z=16，Dc=1.071g/cm~3，F(000)=3408，R_1=0.1395，ωR_2=0.1766，其结构单元是由一个三齿配体中的ONO和另一个配体吡唑啉酮环二位上的N配位后形成略微畸变的平面四边形构型，其中Cu的配位数为4。

Synthesis and characterization of tridentate chiral ligands, a series of Schiff-bases which are synthesized by salicylaldehyde, 2-pyridinecarboxaldehyde and amino alcohols derived from the amino acids without coordination group on side chain.

由侧链不带配位基团的天然氨基酸合成的氨基醇与水杨醛及2-吡啶醛缩合的Schiff-Base等三齿配体的合成与结构分析。

All carboxylates from acetate ligands coordinated in tridentate mode and bridge two M centers in adjacent different sheets.

而通过乙酸根配体以三齿模式桥联相邻近的毯子状网络结构的两个金属离子而形成三维网状结构。

With good stability and high reactivity, pyridine-based tridentate N-ligands have been widely used in the fields of coordination chemistry, organic synthesis and homogeneous catalysis.

吡啶基含氮三齿配体具有良好的稳定性和反应活性，在配位化学，有机合成和均相催化中均得到了广泛的应用。

Herein, using grafting strategy we have developed a new kind of sulfamide-amine alcohol ligands by grafting a activator to the traditional aminoalcohols, which led to more rigid tridentate coordination model and benefit to the control of chiral surrounding.

本文提出一种嫁接策略设计新的手性配体，即在传统的氨醇配体上嫁接上一个活化剂就可以得到一类新型的手性磺酰胺-氨醇配体。

CH3OH has been designed, synthesized and characterized by X-ray diffraction analysis. In this dinuclear complex, it is worthy of notice that the source of tridentate chelate atoms (1N2O) of IDA is different from that of the reported complex.

合成过程中，我们还首次得到了与1，10-邻菲咯啉及亚氨基二乙酸络合的铜的不对称双核配合物晶体。

Chapter 1 describes the synthesis and characterization of a novel tridentate benzamidinato ligand[2SiNMe2](Si=linking group)la.

第一章根据含氮的胺类化合物的良好的反应性和配位性。

Based on density functional theory with the generalized gradient approximation and a full-potential linearized augmented plane wave method, the calculation of the electronic structures and the magnetic properties on [Cuμ-1,3-N3](ClO4), where L is the tridentate Shiff base, has been performed.

基于广义梯度近似密度泛函和全势能线性缀加平面波方法，本文对聚铜络合物[Cuμ1，3-N3](ClO4)（其中L=tridentate Schiff base为三齿席夫基）的态密度和磁矩进行了计算。

The split between the two groups can hardly be papered over.

这两个团体间的分歧难以掩饰。

This approach not only encourages a greater number of responses, but minimizes the likelihood of stale groupthink.

这种做法不仅鼓励了更多的反应，而且减少跟风的可能性。