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The yields and ees obtained in the AD reaction of eight olefins utilizing 10 in PEG/NMO system were 72~90% and 79~96%(except for trans-5-decene and ally naphthyl ether).

3配体10和配体8是一对假对映异构体,在AD反应中立体选择面相反,可得到相反构型的产物。

The results of AD reactions are as follows:(1) When the AD reaction of eight olefins was performed at 0.5mo1% OsO〓 and 2mol% ligand 8 in PEG/NMO system, the diols were obtained in 78~90% yields and 78~96% ees (except for trans-5-decene and ally naphthyl ether).

催化结果如下:(1)在PEG/NMO体系中,将配体8用于八种烯烃的AD反应,配体、OsO〓和底物的摩尔比为0.02/0.005/1时,化学产率为78~90%,除反式-5-癸烯和萘基烯丙基醚较低外,其它六种烯烃的相应二醇产物的ee值为78~96%。

The efficiency of IRES-dependent translation is concerned with the infectivity of viruses, but whether the IRES is concerned with neurotropism or not is still controversial.

另一方面,病毒IRES与核醣体的结合需要细胞中IRES trans-acting factors的参与,而目前对肠病毒71型ITAF的了解仍然有限。

This text direct of our country new economic environment behind the accession to the WTO against, utilize policy of foreign capitals need , go on to our country what kind of adjustment act as the discussion; And analyzing the capital operation from two respects under the newing situation , the innovation had develops; To the reason of the transnational capital operation sequentially in terms of macroscopic finally, positive effect and negative effect have been analyzed, thus made the win-win strategy of the trans-corporation and state-owned enterprise .

本文针对我国加入WTO后的新经济环境,对我国利用外资的政策需要进行怎样的调整作了探讨;并从两个方面分析了资本运营在新形势下所具有的创新发展;最后从宏观的角度依次对跨国资本运营的动因,积极效应和负面影响进行了分析,从而作出了跨国公司和国有企业的双赢战略。

Secondly, the nomological basis of trans-boundary environmental damage is a hot issue focused by international law circles.

国家因造成跨界环境损害事故而违背了环境义务,就应当承担国际法上的国家责任。

The reaction of cyclic b-keto esters with CF3CO2ZnCH2I provides the corresponding ring-expanded products with the advantage of mild condition in moderate to good yields. A simple and efficient procedure has been developed for a variety of 1,3-diketones converted into the corresponding 1,4-diketones and trans-1,2-disubstituted cyclopropanols in high yields. In conclusion, this new type of organozinc reagents has been developed for many useful reaction in organic synthesis.

利用有机锌试剂所具有的双重特性,在新型的Baylis-Hillman反应中,可以直接与炔基酮和醛反应一锅制得多官能团的三取代的顺式烯;在b-酮酯化合物的扩环反应中,取得了重要进展,得到了增加一个碳的扩环产物,&一步法&合成,反应条件温和、环境友好;在1,3-二酮分子中成功地插入1个碳,合成出1,4-二酮和环丙醇,为现代有机合成提供了新的合成方法,具有良好的应用前景。

Compared with those bipolar-transporting materials containing carbazole and aryl oxadiazole groups connected with conjugated groups, these bipolar-trans- porting materials here presented high HOMO and LUMO energy levels and thermal stability.

与共轭基团桥联咔唑和芳基噁二唑的双极传输材料相比, HOMO/LUMO能级相应地提高,热稳定性能增强。

Oxalyl fluoride neutral molecule ; trans-configuration ; cis-configuration ; density function theory; stability ; frequency analysis

草酰氟分子;平面反式构型;顺式构型;密度泛函;稳定性;频率分析

Finally, the cytotoxic and antibacterial activities of the oxamido-bridged binuclear complexes were studied in vitro.. This dissertation consists of three sections as follows:1. The crystal structure of a oxamide dinitrate,(1) [H_4dmaeoxd](NO_3)_2 H_2dmaeoxd = N,N\'-bis[2-ethyloxamide, has been obtained. The diversity of complexes with different structures is carried out by successful synthetic strategy of controlling species of metal ions, counter anions, pH values and solvents in the course of synthesis. Four dinuclear complexes bridged by trans-dmaeoxd2-: [Cu_2_2](ClO_4)_2 (2), [Cu_2_2](ClO_4)_2 (3),、[Cu_2(Me_2phen)_2](ClO_4)_2 (4), [Cu_2_2(H_2O)_2] (5); Four dinuclear complexes bridged by cis-dmaeoxd2-: [NiNi_2](ClO_4)_2 (6), [CuNi_2](ClO_4)_2·2CH_3OH (7), [CuZn_2]-(ClO_4)_2·2H_2O (8), [Cu(H_2O)Ni_2](ClO_4)_2.0.5CH_3OH (9); three 1-D polynuclear complexes: [Cu_2]_n·nH_2O (10), [Cu_2(H_2O)_2-]_n·4nH_2O (11), [Cu_2(H_2O)]_n(NO_3)_n·2nH_2O (12); one 2-D polynuclear complex,[Cu_6_3(μ_3-OH)_2(H_2O)_2]_n(ClO_4)_(4n).2nH_2O (13); the others: [VO(H_2O)]·2H_2O (14), [Zn_2_4](ClO_4)_2·H_2O (15), [Cu_2]·2DCM (16) have been synthesized and characterized by X-ray single crystal diffraction, elemental analysis, IR spectra.

本论文主要包括以下三部分:一、合成得到了一个草酰胺配体硝酸盐的单晶结构,[H_4dmaeoxd](NO_3)_2 (1);通过调控金属离子的种类、端基配体、抗衡阴离子、溶剂、pH值等条件定向合成了四个反式草酰胺桥联双核铜配合物:[Cu_2_2](ClO_4)_2 (2)、[Cu_2_2](ClO_4)_2 (3)、、[Cu_2(Me_2phen)_2](ClO_4)_2 (4)、[Cu_2_2(H_2O)_2] (5);四个顺式草酰胺桥联同/异双核配合物:[NiNi_2](ClO_4)_2 (6)、[CuNi_2](ClO_4)_2·2CH_3OH (7)、[CuZn_2]-(ClO_4)_2·2H_2O (8)、[Cu(H_2O)Ni_2](ClO_4)_2.0.5CH_3OH (9);三个一维聚合物: [Cu_2]_n·nH_2O (10)、[Cu_2(H_2O)_2-]_n·4nH_2O (11)、[Cu_2(H_2O)]_n(NO_3)_n·2nH_2O (12);一个二维聚合物: [Cu_6_3(μ_3-OH)_2(H_2O)_2]_n(ClO_4)_(4n)。2nH_2O (13);单核钒配合物[VO(H_2O)]·2H_2O (14)、草酸根桥联双核锌配合物[Zn_2_4](ClO_4)_2·H_2O (15)、美洛西康铜配合物[Cu_2]·2DCM (16),利用元素分析、摩尔电导、红外光谱、电子光谱和单晶X-射线衍射对上述所得化合物进行了结构表征,探讨了结构影响因素,并研究了其超分子结构。

The PAHO task force suggested seeral measures to speed up the process of eliminating trans fats from food in the Americas, including promoting unsaturated fats as an alternatie.

PAHO的专责小组提出了几条措施以加速美洲食品中反式脂肪的清除,包括鼓励促进不饱和脂肪酸作为替代。

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推荐网络例句

This one mode pays close attention to network credence foundation of the businessman very much.

这一模式非常关注商人的网络信用基础。

Cell morphology of bacterial ghost of Pasteurella multocida was observed by scanning electron microscopy and inactivation ratio was estimated by CFU analysi.

扫描电镜观察多杀性巴氏杆菌细菌幽灵和菌落形成单位评价遗传灭活率。

There is no differences of cell proliferation vitality between labeled and unlabeled NSCs.

双标记神经干细胞的增殖、分化活力与未标记神经干细胞相比无改变。