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The third part of this thesis is reactive simulating calculation In this section, some well-known auxiliaries are selected to compute in density functional theory B3LYP on Gaussian 03, from which the relationship between reaction active energies of transition states and enantiomeric excess of chiral products homoallylic alcohols isobtained based on relative reactive ratio theory. Using this relationship, calculations on the reaction of more than eight auxiliaries with four other aldehydes are carried out in AMI and MNDO, proving that N,N\'-dibenzyl tartamide has higher enantioselectivity than others in this reaction.

第三部分为计算化学部分，运用密度泛函理论B3LYP方法在Gaussian03软件上对已经报道的几种手性配体参与的醛不对称烯丙基化反应过程进行模拟计算，基于相对反应速率理论找出两种构型过渡态间活化能的差异与产物光学收率之间的关系；并以此为基础，用AM1和MNDO方法对上述合成的几种配体控制的反应过程进行量化计算，从而在理论上证实了N-苄基酒石酸二酰胺配体在醛的不对称烯丙基化反应中具有较高的立体选择性。

The UV and IR spectroscopic studies of the monomer films showed that the photoreaction ratio of monomer (about 50%) was higher than the corresponding photosensitive polymer (about 10%, PVCi). The polarized IR spectra proved that obvious anisotropic absorption was displayed in the irradiated photosensitive film. With polarizing microscopy method, we found that these kinds of photoalignment films exhibited good alignment ability, and the stability of the photoalignment film could reach about 100℃. 2 A photosensitive self-assembled monolayer was fabricated that contained photo-cycloadditable groups, such as, coumarin and cinnamate. The reaction process were detected by contact angle method because the IR absorption of monolayer was very weak. The photosensitive self-assembled monolayer promote uniform alignment of nematic liquid crystals by LPUV, and it thermal stability could reach about 130℃. 3 A cationic bolaform amphiphiles was synthesized that had two photosensitive double bonds, and can be polymerized by ultraviolet. A layer-by-layer self-assembled deposition film was prepared in aqueous solution by using this material and poly (sodium 4-styrenesulfonate). The UV-Vis. spectra proved that the multilayers film was uniform and layer-by-layer. When LPUV irradiated the film, the photopolymerizable double bond underwent [2+2] cycloaddition, and the production of the reaction distributed along the polarized direction of incident LPUV. Polarized UV-Vis. spectra indicated that the irradiated self-assembled multiplayer film was anisotropic, and the dichromic ration is about 0.09, it is higher than the spin-coating method of photosensitive polymer or monomer. We used this anisotropic film as alignment layer of nematic liquid crystals, and obtained a uniform and stability alignment result, the static contrast ratio is about 100, which is very close to application of liquid crystal device. This thesis is an instance that the photochemical material was used in the physics region of liquid crystals, the route that was from photosensitive monomer, self-assembled monolayer film to self-assembled multiplayer film was undergone, by this logical research method photoailgnment of liquid crystal was extended and consummated.

围绕上述思路开展了如下工作：1合成了三种可进行光二聚反应的光敏小分子单体，LPUV 辐照制作了光控取向膜；用紫外-可见光谱法和红外光谱法分析了薄膜中的光化学反应，发现小分子的光反应程度可达到50%以上，至少比光敏高分子高出5倍；薄膜的偏振红外光谱证实，经过LPUV 辐照后薄膜出现了明显的各向异性；将小分子光控取向膜制成液晶器件，在偏光显微镜下观察看到均匀一致的液晶取向；并且热稳定性达到100℃左右，接近实用化要求。2制备了含肉桂酸、香豆素基团的自组装单层膜；采用接触角的方法监测自组装反应的动力学过程；紫外-可见光谱证实了自组装单层膜在石英基板表面形成；自组装单层膜经LPUV 辐照后能诱导液晶均匀取向，而且热稳定性可达130℃，热稳定性进一步提高。3合成了含有光敏双键的双季铵盐，在水溶液状态下将它和聚乙烯基苯磺酸钠沉积生成layer-by-layer 自组装多层膜，紫外-可见光谱证实这是一个逐层均匀的沉积；在LPUV 照射下，自组装膜中的光敏双键按照偏振方向发生[2+2]环加成反应，形成取向膜，用二向色性值评价的分子取向度高于高分子及小分子光控取向膜的水平；实验证明用自组装多层膜制成的液晶器件亮暗态均匀，静态对比度约为100，达到实用化器件的水平。

From this viewpoint, this thesis firstly study the reason and the characteristic of the Double Favorable balance of payments in China, then try to find out how to coordinate the monetary policy and exchange rate policy in this situation ,and in the end of the thesis put forward our suggestion in order to solve this dilemmatic situation China face recently.

因此，本文试图分析当前中国面临的双顺差环境及其成因，从理论上把握货币政策与汇率政策协调机制，从而为解决宏观经济内外失衡的问题提供政策建议。

This paper puts forward that a distributed control system can be used to monitor and control vessel gate within a real-time or remote distance,the basic project,structure,applications and functions of computerized SCADA system in hydraulic system of vessel gate is introduced.A double layer network structure,Epigynous and hypogynous machine network,is applied to this system.In accord with the application of technique such as PLC,integrated software etc,this paper introduces the methods and application to achieve the computerized SCADA system in the task,and analyzes the characteristic of this system.

另外，本文提出了建立船闸控制系统的分布式控制系统，介绍了船闸液压控制系统的计算机监控系统的方案、结构、应用和主要功能，采用双层网络化结构：上位机网络和下位机网络，并结合PLC通信网络技术和组态软件等技术构成的计算机监控系统的实现方法，实际应用，分析了这种较新的系统模式在船闸液压控制系统的计算机监控系统的功能实现中所具有的特点。

The A Xiang after abdication is faineant, an accidental opportunity vended empty glove through the classmate's relation, managed a bit fund, begin to immerse oneself in the Internet item that makes him then, his discovery is aimed at market of Yang Ling this locality, especially recreation lives kind, the website that is aimed at undergraduate of Yang Ling place especially is returned, then, he prepared to construct Yang Ling city connects a network, a collect hits communication of the member that fold news peace conference to live at the recreation of an organic whole kind of website, he still made a city know member card, oneself a person begins to begin to sell in ave lane of Yang Ling, with the businessman the negotiation cooperates, although initial stage is very much,the person does not approbate this his website, but, a Xiang relies on him hold to and try hard, technology of collect of a person, beauty is made up, sale, business affairs cooperates at a suit, the operation that makes Yang Ling city connects a network eventually was on the right path, yang Ling city connects a network the member of this website also expands with each passing day, become build Yang Ling between local businessman and consumer a ligament, a Xiang also carries businessman ad eventually, the member collects fees the road that waited for mode to be on gain, from a first month hundreds of yuan, go to thousands of yuan again, the scale that reachs ten yuan one year of present again, be less than time of two years, in the small town that A Xiang is not worth 100 thousand population this in Yang Ling, enter a when went out to belong to oneself poineering grade.

辞职之后的阿祥无所事事，偶然的一个机会通过同学的关系倒腾了一次空手套，弄出了一点资金，于是开始埋头做他的互联网项目，他发现针对杨凌本地市场，尤其是娱乐生活类的，特别是针对杨凌当地大学生的网站还没有，于是，他筹建了杨凌城市通网，一个集打折信息和会员交流于一体的娱乐生活类网站，他还制作了城市通会员卡，自己一个人开始在杨凌的大街小巷开始销售，与商家谈判合作，尽管初期很多人并不认可他的这个网站，但是，阿祥依靠自己的坚持和努力，一个人集技术、美编、销售、商务合作于一身，终于使杨凌城市通网的运营走上了正轨，杨凌城市通网这个网站的会员也日渐壮大，成为搭建杨凌当地商家和消费者之间一根纽带，阿祥也终于通过商家广告，会员收费等模式走上了盈利之路，从最初的一个月几百元，再到几千元，再到现在的一年十几万元的规模，不到两年的时间，阿祥在杨凌这个不足十万人口的小城里，闯出了属于自己的一条创业之路。

When we have meat before us and such eatables we receive the impression, that this is the dead body of a fish, and this is the dead body of a bird or of a pig; and again, that this Falernian is only a little grape juice, and this purple robe some sheep's wool dyed with the blood of a shell-fish: such then are these impressions, and they reach the things themselves and penetrate them, and so we see what kind of things they are.

当肉食摆在我们面前，令人馋涎欲滴时，一个念头出现在我们头脑中：这是一条鱼的尸体，或一只鸟的尸体，或一头猪的尸体，而且，这杯法勒恩酒不过是少许葡萄汁，这件紫袍不过是用贝类的血浸染过的羊毛：这些念头在那里，它们自己达于事物，渗透事物，如此我们才看清事物的本质。

On the basis of systematically reviewing relevant theory and practice about social order and its construction, this paper thoroughly investigates the systematic inspirations of HEXIE Management Theory to the developing theme of establishing and forming harmonious society order, and the value of this theory. With a view of systems engineering and by using HEXIE Management Theory as an instructing idea and analyzing tool, this paper systematically constructs the forming mechanism of harmonious society order from three aspects:(1) the optimization and improvement of government's designing and planning function,(2) the independent evolution of social system under environmental inducement, and (3) the organic coupling between the forementioned two aspects surrounding developing theme. This paper finally gets a HEXIE-Management-Theory-based realization way of the anticipated man-made order, the evolved increscent order and finally the complete order in harmonious society.

在系统回顾社会秩序及其构建途径相关理论与实践的基础上，深入地考察了和谐管理理论对建立、形成和谐社会秩序这一发展主题的系统性启示及其价值，并以该理论作为指导思想及分析工具，运用系统工程视角，从政府设计规划职能的优化与完善、环境诱导下社会系统的自主演化以及二者围绕发展主题的有机整合等三个方面对和谐社会秩序的形成机制进行了系统的构建，从而探索出一条基于和谐管理理论的和谐社会中预期的人造秩序、演化的增长秩序乃至最终完整秩序的实现路径。

Wang Hang: Our eye comes round to say, because we are pure iatrical this kind discharge, this kind of discharge occupies us highest, because of other our person of the same trades they basically are a healthy people with patient confuse sth with sth else, actually healthy person follows such word the patient's demand is completely different, for instance healthy person pays close attention to very much, you can see a lot of health now kind the website is being done doing became bisexual and healthy website, so say really impolite, this kind of information I feel to be able to drive away the patient, they do not need the patient that needs a help this kind of information.

王航：我们现在来说，因为我们是纯医疗的这类的流量，这类流量占我们最高的，因为其他的我们的同行他们基本上都是把健康人跟患者混为一谈，这样的话其实健康人跟患者的需求完全不一样，比如健康人很关注，现在你可以看到很多健康类的网站做着做着都成了两性健康网站，这么说确实不客气，这种信息我觉得会把患者赶走，需要帮助的患者他们不需要这种信息。

In the implementation of this system, All the functions of Microsoft NetMeeting are integrated seamlessly by using Microsoft NetMeeting COM. In this system, the transmission and the share of information are reunited according to the actual needs. It solves the incompactness between NetMeeting and medical system, and also avoids much research work in redeveloping lower level network service in this way. It reduced the periods of software development and improved the reliability of this system by using mature module.

本系统在实现过程中利用Microsoft NetMeeting COM组件将Microsoft NetMeeting的所有功能无缝的纳入到本远程医疗会诊系统中，并按实际需要重新组织信息的传递与共享，既解决了视频会议系统与医疗系统结合不紧密的问题，又避开了重新开发网络底层服务的大量工作，大大节省了系统的开发周期，而且借用成熟的系统模块也大大提高了系统的可靠性。

Peasants who suffered unreasonable deprivation would allege even exaggerate irrationality of the treatment in order to endow legitimacy with his incompliance. And if this treatment had no validity, he may also threat prosecuting or finally indicting his antagonist ,this means will give him great courage in the game. The effect of this strategy also lies on the type of the antagonist. Whether he takes law as a weapon or not in the dispute is decided by cost calculation of this means.

另一方面，被不合理但合法剥夺的农民，会想尽办法先避开利益剥夺的合法性，之后宣称甚至夸大这种利益剥夺的不合理性，从而为自己的不顺从行为创造正当性，这种行动策略最常见于官民纠纷当中，因此它的效果就与基层干部的&摆平&能力相关；如果是不合理且不合法的利益剥夺，那么除了宣传、夸大不合理性外，他还会以诉讼相威胁或者诉讼的方式来维护自己的利益，将追求合理性与追求合法性两者统一起来，这种抗争策略的效果同样与抗争对象的层次有关。

She gently rebuff ed him, but agreed that they could be friends

她婉言拒绝了，但同意作为朋友相处。

If in the penal farm, you were sure to be criticized.

要是在劳改农场，你等着挨绳子吧！