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According to these results, it is considered that in the matrix of gray cast iron nitrogen solid-solubilizes as interstitial atom in the octahedron interstice of ferrite and cementite which is not occupied by carbon atom, and causes the crystal lattice of ferrite and cementite to distort, so that the micro-hardness of the matrix increases.

依据这一实验结果,作者认为,在灰铸铁基体组织中,氮以间隙原子的方式固溶在铁素体和渗碳体中未被碳原子占据的八面体间隙里,造成铁素体和渗碳体晶格畸变,从而提高了基体组织的显微硬度。

In addition,for both the cases of a uniformly accelerated two-level atom interacting with a quantized real massless scalar field and a uniformly accelerated multilevel atom interacting with a quantized electromagnetic field,we calculate the rate of change of the mean atomic energy from the point of view of a coaccelerated frame.

另外,对于匀加速的两能级原子与无质量的量子实标量场相互作用以及多能级原子与量子电磁场相互作用的情况,我们还在一个共同加速的框架下计算了原子的平均能量变化率。

For Nitro derivatives of methylbenzenes, the pyrolysis initial reaction is an isomerization reaction. It means the alpha C-H bond in methyl rupture, then the Hydrogen atom transfer to the Oxygen atom in nitryl to form isomer.

甲苯的硝基衍生物的热解引发反应为异构化反应——α_中的C-H键断裂,氢原子转移到邻位硝基(-NO_2)中的氧原子上,生成新的异构体化合物。

Based on the Hmiltonian expression for hydrogen atom in combination with the theory proposed, the theoretical value s of the hydrogen atom's energy, ground state energy and spectrum constant and the electron orbital angular momentum are given.

根据氢原子的量子哈密顿量表示,结合创新的量子算符代数理论,得到氢原子的能量、氢原子的基态能量、电子轨道角动量、氢原子的光谱常数等各种物理量的理论值。

We prepared bulk samples of metastable solid solutions with bcc and fcc structuresin the Fe-Cu system by using shock compression with mechanical alloying, and the magnetization and valence electron were measured and calculated. The saturation magnetic-moment curve versus mumber of electrons per atom at 0K was found to be reasonably similar to the-electrons/atom curve of other transition-metal binary systems.

用机械合金化锻压方法制备了bcc和fcc结构的块状亚稳态Fe-Cu固溶体系统,并对系统的磁化强度、价电子结构进行了测量和计算,从亚稳态 Fe-Cu固溶体的饱和磁化强度Ms-e/a曲线可看出:大约在26.2e/a的区域Ms有最大值,并且在大约28.6e/a的区域接近零。

Based on them, we calculated precisely some enegy levels of P-wave and D-wave of a helium atom, presented and proved the general interdimensional degeneracies for a quantum N-body system, derived the general spherical spinor functions and the exact solution to the Dirac equation for the hydrogen atom, and proved uniformly the Levinson theorem for the Dirac equation in D-dimensions.

在此基础上,我们精确计算了氦原子P波和D波若干较低能级,建立和证明了量子N体系统不同维数状态间最普遍的简并,推导出任意 D 维空间广义球旋函数和Dirac方程氢原子的精确解,统一地提出和证明了任意 D维空间Dirac方程Levinson定理的一般形式。

Two special structural features of the sulfonium salt were proved to stabilize its corresponding ylide and depress the 2,3-sigma rearrangement. One is that there is a trimethylsilyl in the end of the allylic double band. This silicon atom can stabilize a α-carbon anion and the corresponding ylide. Another is that there is hydroxy group in the beta-position of sulfonium atom. The oxygen of this hydroxy group may stabilize the sulfonium cation.

为了稳定生成的烯丙基硫叶立德,并抑制它的2, 3-sigma 重排反应,在硫叶立德结构上做了两方面的考虑:一是在烯丙基双键的未端引入硅基,利用硅原子对 a -碳负离子的稳定作用来稳定烯丙基硫叶立德;二是在硫原子的 b -位引入羟基,利用羟基氧对硫正离子的作用来稳定硫叶立德。

CH3OH could attack the phosphor atom in 1,3,2-dioxaphopholane of compiound (1) to give O-methyl O-hydroxyethyl-O-phthalimidoethyl thiophosphate in 85% yield; in the presence of potassium hydroxide aryl selenol could attack the carbon atom in 1,3,2-diox-aphopholane of the cyclic phospholipid conjugate of N^1-(2-furanidyl)-N^3--5-fluorouracil to give the corresponding product of ring-opening in high yields.

在室温下,以异丙醇作溶剂,苯硒酚与化合物2不反应。在氢氧化钾存在下,以异丙醇/水作溶剂(体积比20:1,在室温下,硒酚可以有效地进攻中化合物2中1,3,2-二氧磷杂环戊烷中的碳原子生成相应的开环产物。按照这一反应条件,顺利实现了硒酚对N^1-(2-呋喃基)-N^3-羟烷基-5-氟脲嘧啶硫代环甘油磷脂缀合物的亲核开环,生成甘油骨架的端碳原子上带有芳硒基新颖的磷脂核苷缀合物。

The calculated results show that H atom preoccupies the twofold bridge site of the subsurface on the intact W(100) surface at low coverage, and obtains the perpendicular vibration frequency of 156 meV. The H-atom adsorption on bridge site, top site and fivefold hollow site (the top site on the second W layer) were observed at high coverage.

计算结果表明,低覆盖度下, H原子优先吸附在W(100)面的内层吸附位二层桥位B',获得156 meV的垂直振动频率,随着覆盖度的增加, H原子稳定吸附在表层的五重洞位、桥位及顶位。

The copper atom is in a planar coordination site of [N_2O_2] and it devites from the mean plane by only 0.80 pm. Byπ-πstacking interactions, a alabastrine structure was obtained.(2)Schiff-base complex [Cu(H_2O)]·H_2O, where H3GS is the 3-carboxyl -salicylidene glycine, was synthesized and characterized by elemental analysis, IR spectra and single-crystal analysis. The crystal belongs to monoclinic system, space group P2(1)/c, a=848.46(3)pm, b=681.54(3)pm, c=1967.16(8)pm,β=95.8210(10)°, Z=4, R_1=0.0279, wR_2=0.0724. The copper atom is in a square-pyramidal field with the base

结果表明该晶系属单斜晶系,空间群P2(1)/c,晶胞参数:a=848.46(3)pm,b=681.54(3)pm,c=1967.16(8)pm,α=90°,β=95.8210(10)°,γ=90°,Z=4,R_1=0.0279,wR_2=0.0724,Cu原子位于轻微变形的四方锥场底心,底面被氮原子、酚氧原子、甘氨酸羧基的一个氧原子和一个水分子氧原子占据,而甘氨酸羧基的另一个氧原子占据相邻分子的锥顶,因而形成一维链状结构;合成了单核双聚配合物Na_2[Cu_2_2]·2H_2O ,铜三核配合物Cu_3_2·5H_2O和铜锌异三核配合物ZnCu_2_2·5H_2O,并用元素分析,IR光谱,电子光谱和磁化率测定对配合物的组

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