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tetrazine相关的网络例句

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与 tetrazine 相关的网络例句 [注:此内容来源于网络,仅供参考]

A novel synthetic approach of 3,3'-azobis(6-amino-1,2,4,5-tetrazine) was firstly devised. Taking 3,6-bis(3,5-dimethylpyrazol-1-yl)-1,2,4,5-tetrazine as a primary material, DAAT was synthesized by high pressure ammonolysis and potassium permanganate oxidation. Compared with the four-step reaction in the literature, this new approach was reduced to two steps with a yield of 58.1%. The intermediate and DAAT were characterized by elemental analysis, IR and NMR spectra.

自行设计了3,3'-偶氮双(6-氨基-1,2,4,5-四嗪)新合成路线、采用3,5-双(3,5-二甲基吡唑-1-基)-1,2,4,5-四嗪为原料,由文献报道的4步反应缩减为2步,经高压氨解、高锰酸钾氧化合成了DAAT,总收率大幅提高,达到58.1%,并采用元素分析、红外光谱、核磁共振光谱等进行了结构表征。

Diazido-1,2,4,5-tetrazine has been synthesized from 3,6-bis(3,5-dimethylpyrazol-1-yl)-1,2,4,5-tetrazine by hydrazinolysis and diazotization.

以3,6-双(3,5-二甲基吡唑基)-1,2,4,5-四嗪为原料,经过肼解反应和重氮化反应,制得了3,6-二迭氮基-1,2,4,5-四嗪。

3,6-Diazido-1,2,4,5-tetrazine has been synthesized from 3,6-bis(3,5-dimethylpyrazol-l- yl)-1,2,4,5-tetrazine by hydrazinolysis and diazotization.

以3,6-双(3,5-二甲基吡唑基)-1,2,4,5-四嗪为原料,经过肼解反应和重氮化反应,制得了3,6-二叠氮基-1,2,4,5-四嗪。

For distinctly understanding the mutual influence between the structural units, a series of compounds from five and six-membered C-N heterocycle substituting the tetrazine ring are designed. These several types of compounds are studied by means of the quantum chemistry calcualtions and discussed the influence of the structural units upon the main performance (heat of formation, density, velocity and pressure of detonation) and found out the best combination of performance.

为了更清楚的了解结构单元之间的相互影响,设计了六元氮杂环和五元氮杂环取代1,2,4,5-四嗪得到了一系列化合物,采用量子化学计算方法对它们进行了详细的理论研究,讨论了各种氮杂环的改变对四嗪类化合物性能(包括生成热、密度以及爆速和爆压等)的影响,并找出爆轰性能较好的结构单元组合。

Study on the Synthesis of Uracil Derivatives Ⅱ.Study on the Synthesis of 1, 4-Dihydro-s-Tetrazine Derivatives and Their Antitumor Activity

论文标题:Ⅰ。药物中间体尿嘧啶衍生物合成研究Ⅱ。1,4-二氢-s-四嗪衍生物的合成及抗肿瘤活性研究

Three aspects were included here:The derivatives of dihydrol,2,4,5-tetrazine-3,5-dicarboxylic acid were synthesized via three different routes:(1) four new compounds were synthesized via the reaction bet ween dihydrol,2,4,5-tetrazine-3,5-dicarboxylic acid, thionyl chloride and corresponding alcohol ;(2) first ,dimethyl dihydro-1,2,4,5-tetrazine-3,5-dicarboxylate wer e synthesized, then ,another four new compounds were obtained t hrough the alcoholysis under the catalyst ;(3) three acylamines were got through the ammonolysis betw een dimethyl dihydro-1,2,4,5-tetrazine-3,5-dicarboxylate and amines.

本论文分别通过三条不同的路线合成了1,4-二氢-3,6-二甲酸-s-四嗪的衍生物:(1)通过1,4-二氢-3,6-二甲酸-s-四嗪与氯化亚砜和相应的醇反应,制备了四个新化合物;(2)合成1,4-二氢-3,6-二甲酸甲酯-s-四嗪,在催化剂的作用下,与高沸点的醇进行酯交换反应,合成了四个新化合物;(3)合成1,4-二氢-3,6-二甲酸甲酯-s-四嗪后,与胺进行氨解反应,合成三个新的1,4-二氢-3,6-二甲酰胺-s-四嗪化合物。

Relevant works of other groups worldwide are introduced, espically as the synthesis, performance and application investigation of tetrazine, tetrazole and furazan based HiNC.

本文综述了新型高氮化合物及其含能材料的研究进展,介绍了国内外近十年来众多研究小组的相关工作,重点阐述了四嗪、四唑和呋咱3大类高氮含能化合物的合成、性能及应用研究进展。

Relevant works of research groups worldwide are introduced,espically the synthesis,performance and application investigation of tetrazine,tetrazole and furazan based HiNC.

要实现这些目标,作为武器能量载体的含能材料必须满足高能量密度、低易损和环境适应性等要求。

In part two, the synthesis of tetrazine and its derivatives, the corresponding antitumor activities were also studied.

第二部分:研究有关四嗪类衍生物的合成,并考察其抗肿瘤活性。

Tetrazine ring is an energetic nitrogen hexa-heterocyclic group with nitrogen mass fraction of 68.3%,so it is a very effective structure unit in the design of high energetic,insensitive materials.The tetrazine high-nitrogen energetic materials are new kinds of ones researched and reported widely at home and abroad in recent years.

四嗪环是一种含氮质量分数达68.3%的六元氮杂环含能基团,是设计高能钝感含能材料中非常有效的结构单元;四嗪类高氮含能材料也是近年来国内外研究和报道较多的一种新型含能材料,部分具有生成焓高、热稳定性好和感度较低等特点。

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