查询词典 tertiary amine

And to make the product be easy of purification, the excess of amine was reduced to 50% from 150%. Then the diiodoalkane reacted with dialkylmethylamine into diquaternary ammonium iodide, and obtained three diquaternary compounds whose spacer groups were -(CH2)6-, N,N"-dimethyl- N,N,N",N"-tetraoctyl-1,6-hexane diammonium diiodide, N,N"-dimethyl-N,N,N",N"-tetradecyl-1,6-hexane diammonium diiodide, N,N"-dimethyl-N,N,N",N-tetradodecyl -1,6-hexane diammonium diiodide.

对于更长间隔链的双子型季铵盐，一方面为了加快亲核取代反应速率，先将1，6-二氯己烷、3-氧杂-1，5-二氯戊烷转化成1，6-二碘己烷、3-氧杂-1，5-二碘戊烷，另一方面为了降低产物提纯的难度，将叔胺的过量由150%降到50%，使二碘代烷与双长烷基甲基叔胺在相同的温度下、反应相同的时间，经过相同的后处理，得到3个间隔链为-(CH2)6-的双子型季铵碘化物，(C8H17)2N+(CH3)(CH2)6 (CH3)N+(C8H17)2·2I-、(C10H21)2N+(CH3)(CH2)6(CH3)N+(C10H21)2·2I-和(C12H25)2N+(CH3)(CH2)6(CH3)N+(C12H25)2·2I-。

It's found that the aromatic dinitro compounds can be monoreduced to nitroanilines in high selectivity, aromatic nitro compounds and muti-cycle aromatic nitro compounds can be quantitively reduced to the corresponding amine by selenium catalyst with CO/H2O in polar aprotic solvents under atmospheric pressure using medical inorganic bases as co-catalysts.

在实验的基础上提出了对硒催化CO/H_2O还原芳香硝基化合物机理的一些粗浅认识。

A bis-imdazoline corrosion inhibitor JUC was synthesized by reacting with divinyl three amine,and its quaternary ammonium JUCI was also synthesized for corrosion inhibition in acids.

以己二酸、二乙烯三胺为原料合成了双环咪唑啉缓蚀剂JUC，并对其季铵化后得到了适于酸化用的双环咪唑啉季铵盐缓蚀剂JUCI；采用静态挂片失重法对合成的缓蚀剂在酸化条件下的缓蚀性能及与非离子表面活性剂SA-1复配后的缓蚀性能进行了评价研究。

Using 2-bromo-ethanesulfonic acid sodium salt ,α,ω- binary primary amine and dodecanoic acid as the main raw materials, drawing support from two-step synthesis of experiments—Alkylated reaction and Schotten-Baumann acylation, A series of LAS(12-s-12) gemini surfactants were synthesized.

并以2-溴乙基磺酸钠、α，ω-二元伯胺、月桂酸等为主要原料，借助胺基的烷基化和Schotten-Baumann酰基化反应制备了α，ω-烷撑-双钠盐LAS(12-s-12)表面活性剂，联结基团为亚甲基—(CH2)s—(S=2，4，6，8，12)，取得以下进展

By systemic studies in the lab, the optimal technical and operational conditions had been determined as follows: the dosage of duodenary amine of 100 g/t. the pressure of circulating pulp of 0.045 MPa, the concentration of pulp of 43%, the floatation time of 7-8 min.

通过在实验室浮选柱系统上的试验，优化确定了如下工艺和操作参数：十二胺药剂用量100g/t，循环矿浆压力0.045 MPa，矿桨浓度43%，浮选时间7~8 min。

The results show that:(1) When Cu〓 equatorially coordinated by four nitrogen atoms from amine ligands such as ethylenediamine, N-methylethylenediamine, 1, 2-diaminopropane and 1, 4, 8, 11-tetraazacyclotetradecane, etc., Cu〓 could be axially coordinated by oxygen atoms of-SO〓 group.

研究结果表明：（1）当Cu〓在赤道平面与来自胺配体（如乙二胺、N-甲基乙二胺、1，2-丙二胺和1，4，8，11-四氮杂环十四癸烷等）的四个氮原子配位后，在轴向则可以与来自磺酸根离子的-SO〓基团氧原子配位。

When Ni〓 was equatorially coordinated by four nitrogen atoms from the same amine ligands such as ethylenediamine and N-methylethylenediamine, arenedisulfonates did not axially coordinated to Ni〓.

Ni〓与同样的胺配体（如乙二胺、N-甲基乙二胺）的四个氮原子在赤道平面配位后，芳烃二磺酸根离子并没有在轴向与Ni〓配位，水分子仍然占据轴向的位置。

Wool fabrics were treated with potassium fluotitanate and amine modified organic silicone in one or two bath process to develop multifunctional and new-style wool fabrics which had the functions of retardation of flaming and softness .

以氟钛酸钾和氨基改性有机硅为功能整理剂，分别利用一浴法和二浴法2种工艺对羊毛织物进行功能整理，开发出具有阻燃、柔软多重功能的新型毛纺织品。

First, we synthesized a new monomer,1-(3\'-aminopropyl)-4-acrylamido-1,2,3-triazole hydrochloride,via click chemistry and its block copolymer with NIPAM, PNIPAM-b-PAPAT,via RAFT polymerization.On the basis of the reaction between amine groups of the PAPAT block and glutaric dialdehyde,core cross-linked and shell cross-linked micelles with inverted structures were prepared at 25℃and 50℃,respectively.

借助于PAPAT嵌段上含有的氨基及PNIPAM嵌段的LCST效应，我们在其20℃和50℃的水溶液中分别制备了CCL胶束和SCL胶束，进一步地，我们利用由Click反应产生的1，2，3-三氮唑环对金属的强络合和稳定作用，分别对CCL胶束的内核与SCL胶束的外壳用金纳米粒子进行选择性修饰。

Stability of electrodeposition liquid, the physical and chemical resistance properties of the film depend on amine value, kinds of glycidic ester used, GA content and the amount of blocked polyisocyanate used.

结果表明，环氧基在固化过程中会参与交联反应，电泳液的稳定性、涂膜的物理性能和耐化学品性能由胺值、缩水甘油酯单体种类、丙烯酸缩水甘油酯含量和封闭型多异氰酸酯用量等因素决定。

You can snipe the second and third union leaders from this position.

您可以鹬第二和第三工会领袖从这一立场出发。

Aiming at the currently shortage of XML streams quality detecting, this paper proposes a new forecasting method of XML streams quality by least squares support vector machines, which is used the method of XML keys' vector matrix as windows, and vector product wavelet transform to multilevel decompose and refactor the XML streams series, that can fulfill real-time checking demand of XML quality, and ensure constraint, consist- ency and integrality. For even more adapting net load, it proposes a control strategy by weight and adaptive adjustment to ensure XML streams quality.

针对当前XML数据流质量检测存在的不足，提出构建XML键的矢量矩阵作为窗口，利用矢量积小波变换多级分解与重构XML数据流，再结合最小二乘支持向量机对XML数据流质量进行预测的一种方法，满足XML数据流质量重构时实时检测的要求，保证XML数据的约束性、一致性与完整性；为了更好的适应网络负载，采取加权与自适应窗口调整等调度策略充分保证XML数据流的质量检测。