查询词典 tertiary amine

A series of pyrroles were synthesized from primary amine(including fatty amine and aromatic amine)and acetonyl-acetone through a Paal-Knorr reaction catalyzed by formic acid at room temperature under solvent-free conditions.

以甲酸为催化剂，无需使用任何溶剂，在室温条件下，多种伯胺与2，5-己二酮发生Paal-Knorr缩合反应，生成相应的吡咯衍生物。

The crystal structures of two complexes have been determined by X-ray diffraction as: complex (11) is distorted octahedron configuration,α=15. 9002 (6), b=16. 2413 (5), c=23. 4401 (8)〓,β=90°, V=6053. 2 (4)〓, Z=8 and R=0.0531; complex (8) is trigonal bipyramidal configuration,α=9. 3476 (8), b=17. 4236 (13), c=9. 7836 (8)〓,β=91. 197 (3)°, V=1593. 1 (2)〓, Z=2 and R=0.0325, which shows that three secondary amine groups (N-1, N-2, N-3) of the glycosylamine ligand forms the equatorial plane, and the tertiary amine (N-4) and one Cl〓 are pointed on the apical positions.

分别对其进行X-ray衍射分析可以得出：配合物(11)的晶体数据为α=15.9002(6)，b=16.2413(5)，c=23.4401(8)〓，β=90°，V=6053.2(4)〓，Z=8 and R=0.0531，为畸变的八面体构型，而配合物(8)中，α=9.3476(8)，b=17.4236(13)，c=9.7836(8)〓，β=91.197(3)°，V=1593.1(2)〓，Z=2 andR=0.0325，为三角双锥构型，糖胺配体的三个氮原子（N-1，N-2，N-3）位于赤道平面上，而另外一个氮原子（N-4）和一个Cl〓位于轴向上。

Starting from boldine (56), secoboldine (57) was prepared by ring opening at N6 position. Then the resulting secondary amine, secoboldine (57), was treated with various substituted benzaldehydes, to form a series of diarybutanoid-like tertiary amine alkaloids.

以波尔定碱(boldine， 56)做起始物，在N 6位置做开环反应可以得到次波尔定碱(secoboldine， 57)，再用还原胺化反应在二级胺上接上不同的苯醛，可以得到一系列的三级胺生物碱化合物。

Accordingly, we start the thesis from two small oil fields of Beipu and Laoyemiao in Nanpu depression. Firstly, we analyze regional geology background of the area and find that its structure evolvement can be divided into three greatest stages: the formation and evolution of pre-tertiary basement, the lower-tertiary fault basin and the upper-tertiary depression basin.

因此本论文从南堡凹陷北堡和老爷庙两个小型油田入手，首先分析了研究区的区域地质背景，明确了其构造演化分为三大阶段：即前第三纪基底的形成与演化、早第三纪断陷盆地的形成与演化、晚第三纪坳陷盆地的形成与演化。

By studying the inorganic CO〓 and helium isotopes in Yinggehai Basin, and investigating the Tertiary lithology and geothermal condition, combined with the results of thermal simulation test, it was suggested that inorganic CO〓 gas principally came from thermal decomposition of Tertiary calcareous shales and Pre-Tertiary carbonate under the burial depth of 6000m, approximately at a strata temperature of about 250℃.

通过系统地剖析莺歌海底辟带气田无机CO〓的碳、稀有气体同位素特征与第三系及古生界基底的岩性及热源条件，结合热模拟实验资料，认为无机CO〓主要来深埋的梅山-三亚组钙质泥岩热分解和前第三系基底碳酸岩的热变质，这种钙质泥岩和碳酸岩热分解产生CO〓的初始温度大约为250℃，相当于埋深约6000m。

The study of 9－12 indicate that it is easy to get polyoxomolybdate with organic amine at weak acidity conditions when there are organic amine and organic acid in the same reaction systems.

化合物 9－12 的研究结果表明，在弱酸性条件下，同时存在有机酸和有机胺时，易形成含有机胺的钼氧簇，而有机酸不易进入产物晶相。

Moreover, it was successfully linked with lactobionic acid through amine groups on the surface of particles, and used to recognize living liver cells successfully.(3) In order to simplify the proceeding of preparation of silica-coated qdots, a novel one-pot method using 3-mercaptopropyl-trimethoxysilane as a capping molecule was proposed for the first time. Furthermore, amine and phosphonate groups were also modified on the surface of silica-coated qdots simultaneously. This was the first time the synthesis and the surface modification of qdots were performed in the same system.

3在前一部分工作的基础上，进一步简化量子点的合成与包壳步骤，以MPS为稳定剂，制备了硅壳包被的CdTe量子点，并在硅壳外同步修饰氨基及磷酸基团，首次成功实现了量子点的合成与表面的功能化修饰在同一体系中进行，从而制得了水溶性的、表面带有氨基和磷酸基团的硅壳型CdTe量子点。

The invention discloses an InP quantum point preparing method, comprising the steps of:(1) mixing InCl3 with trioctylphosphine oxide, and preserving heat at 90-110DEG C to prepare a solution whose In content is 0.1-0.3mol/L;(2) raising temperature to 130-180DEG C, and charging argon gas;(3) injecting PSi(CH333 into InCl3-TOPO compound in the molar ratio of 1 to 1-1 to 2;(4) when the solution color turns into transparent red or orange, raising temperature to 260-270DEG C and preserving heat;(5) lowering temperature to 90-110DEG C and injecting dodecyl amine, decyl amine or mercaptan;(6) dissolving reacting mixture in nonpolar solvent to form transparent colloidal solution, then adding in polar solution until the colloidal solution is muddy, and centrifugally separating and obtaining deposits and supernatant; and (7) centrifugally separating the supernatant, where the above steps (1)-(5) are performed.

本发明公开了一种InP量子点的制备方法，其步骤为：①将InCl 3 与三辛基氧膦混合，在90～110℃保温制得In含量为0.1～0.3mol/L的溶液；②升温到130～180℃，通入氩气；③将PSi(CH 3 3 3 注射入InCl 3 -TOPO复合物中，其摩尔比为1∶1～1∶2；④待溶液颜色变为透明的红色或橙红色，将升温260～270℃保温；⑤降温到90～110℃，注入十二胺、癸胺或硫醇；⑥将反应混合物溶于非极性溶剂，形成透明的胶体溶液，然后加入极性溶剂，直至胶体溶液出现混浊状，然后离心分离获得沉积物和上层清液；⑦取上层清液进行离心分离。上述步骤①～⑤在保护气氛下进行。

The effect of coconut amine on the viscosity and stability of residue asphaltene system was studied and the change in viscosity and colloid stability with coconut amine content was discussed briefly.

考察了表面活性剂椰子胺对石油沥青质体系粘度和胶体稳定性的影响，初步探讨了粘度和胶体稳定性随椰子胺质量分数变化的原因。

The test result which through degrading fatty amine flotation collectors separate by Fenton oxidation, titanium dioxide supported on stilbite photocatalytic oxidation or UV/H2O2/air oxidation method indicates that UV/H2O2/air oxidation method which degradation rate and mineralization degree are very high is the most suitable for degrading fatty amine flotation collectors, and it reacts peaceably, operate simply, consume low energy consumption.

通过Fenton试剂氧化法、辉沸石负载型二氧化钛光催化氧化法和UV/H2O2/air氧化法分别降解脂肪胺浮选捕收剂的试验结果表明，UV/H2O2/air氧化法最适于降解脂肪胺浮选捕收剂，其降解率和矿化程度都很高，且反应条件温和、操作简易、能耗低。

Listen,point and check your answers.

听，指出并且检查你的答案。

Warming needle is one of effective treatment methods for knee arthralgia aggravated by cold,and it is simple,safety,so it should be developed in clinical acupuncture and moxibustion extensively.

但以本院科针灸门诊在2005年1月—2006年6月期间共收治膝痛患者100余例，经过临床的诊断后，其中施以温针治疗的48例，疗效显著，报道如下。1临床资料本组病例48