查询词典 terephthalic acid

The invention relates to a preparation process for synthesizing polyethylene terephthalate 1, 3- terephthalate catalyst, which comprises adding titanic acid ester, germanium compounds and cobalt compound into liquid dispersed phase of organic solution, wherein the total weight concentration is 4-10%, and preparing the catalyst through mechanical stirring or ultrasonic wave mixed ligand for 10-60 minutes in 0-120 DEG C, wherein the adding content of titanic acid ester, germanium compounds and cobalt compound are respectively 200-500ppm, 50-300ppm and 100-400ppm of reaction monomer mass of terephthalic acid or dimethyl terephthalate.

本发明涉及一种合成聚对苯二甲酸1，3-丙二醇酯催化剂的制备方法，将钛酸酯、锗化合物和钴化合物加入到有机溶剂的液体分散相中，总重量浓度为4～10％，在0-120℃通过机械搅拌或超声波混配10-60min制得；钛酸酯、锗化合物和钴化合物加入量分别是对苯二甲酸或对苯二甲酸二甲酯反应单体质量的200-500ppm、50-300ppm、100-400ppm；用此催化剂制备PTT产品，酯化和缩聚反应时间相对于单独使用钛酸四丁酯缩短了30-60min，产品特性粘数0.70-1.05dL/g，色相b值在2-6之间，切片可用于加工新型合成纤维及工程塑料产品。

Methyl-2,3,5,6-tetrafluoro-benzene methanol was synthesized by chlorination, acylation, fluorination, esterifica- tion, reduction, bromization, reduction from terephthalic acid. Tefluthrin was obtained from-(1RS,3RS)-3-(2-chloro-3,3,3-trifluoro-1-propenyl)-2,2-dimethyl cycolpropa-necarboxylate acid by reacting with 4-methyl-2,3,5,6-tetrafluoro-benzene methanol.

以对苯二甲酸为原料，经氯化、酰氯化、氟化、酯化、还原、溴化、还原七步反应合成了4-甲基-2，3，5，6-四氟苄醇，甲基苄醇与-(1RS，3RS)-3-(2-氯-3，3，3-三氟丙-1-丙烯基)-2，2-二甲基环丙甲酸一步酯化合成了七氟菊酯。

Tetrachloroterephthalic acid was prepared by chlorinating terephthalic acid, oleumsolvent and iodine catalyst. Tetrachloroterephthalic acid was acylated by sulphurous oxychloride in the presence of DMF to form tetrachloroterephthaloyl chloride. The acyl chloride product was fluorinated by potassium fluoride and esterified by methanol to synthesize dimethyl tetrafluoroterephthalate. The ester was reduced with potassium borohydride and lithium chloride to give tetrafluoroterephthalyl alcohol. The above product was bromated in the hydrobromic acid to obtain 4-bromomethyl-2,3,5,6-tetrafluoro-benzene methanol. 4-Methyl-2,3,5,-6-tetrafluorobenzene ethanol was obtained by reducing the bromide with magnesium. In the exist of DCC and DMAP, tefluthrin was got by the condensation reaction between 4-methyl-2,3,5,6-tetrafluoro-benzene methanol and-(1RS,3RS)- 3-(2- chloro-3,3,3-trifluoro-1-propenyl)-2,2-dimethyl cycolpropanecar-boxylate acid.

对苯二甲酸与氯气在碘存在下以发烟硫酸为溶剂进行氯化制备四氯对苯二甲酸；再以DMF为催化剂与二氯亚砜反应生成四氯对苯二甲酰氯；以氟化钾为氟化剂，环丁砜为溶剂置换氟化，再与甲醇酯化得到四氟对苯二甲酸甲酯；以KBH4-LiCl为还原剂二甲醚为溶剂反应制得四氟对苯二甲基苄醇；以氯苯为溶剂在溴化氢溶液中溴化得到溴化产物；在乙醇溶液中经镁粉还原得到4-甲基-2，3，5，6-四氟苄醇；甲基苄醇与功夫酸在催化剂二环己基碳二亚胺和4-二甲氨基吡啶作用下缩合得到七氟菊酯，总收率达43.6%。

In this thesis, five polydentate ligands including azido, oxalate, terephthalic acid, isophthalic acid and Pyridine-2,6-dicarboxylic acid were used to construct new transition metal complexes (M = Ru, Fe and Zn). Eight new complexes as listed below were synthesized and fully characterized.

本论文以草酸根、叠氮根、对苯二甲酸、间苯二甲酸和吡啶-2，6-二羧酸等含O、N的多齿共轭配体为研究对象，合成了以下八个结构新颖的化合物，并对它们的结构和谱学性质进行了详细的表征。

In this study, poly (PA12T), poly (PA12I) and PA(12T-co -121) were synthesized using terephthalic acid, isophthalic acid with dodecamethylene diamines.

中和成盐的过程中，十二碳二元胺可分别与对苯二甲酸、间苯二甲酸直接进行成盐反应，可以通过电导滴定法来判定等当量点。

The new type semi-aromatic transparent nylon has been successfully developed for the first time using cheaper monomers,including linear chain aliphatic diamines,terephthalic acid,isophthalic acid and so on,by means of polybasic copolycondensation.

采用无侧基的脂肪族混合二元胺、对苯二甲酸、间苯二甲酸等为单体，通过多元无规共缩聚方法制备了半芳香透明尼龙，研究了SA型透明尼龙的静态热机械性能和动态力学性能。

Dodecamethlyene diammonium terephthalate(PA12T salt) and dodecamethlyene diammonium isophthalate(PA12I salt) can be prepared by using terephthalic acid or isophthalic acid with dodecamethylene diamines in ethanol solution, respectively.

通过 对PA 1 ZT、PA12I及其共聚物的聚合反应的研究发现，随着PA121组分的增加，相同反应条件下，产物的粘数呈增大趋势，熔点逐步降低，透明性逐渐增大，韧性增强。4。

Reparation of PBO was begun with the polymerization process in which composite salts that contained 4,6-diaminoresorcinol and terephthalic acid were dissolved in polyphosphoric acid and phosphorus pentoxide.

BO纤维制备：以4，6-二氨基间苯二酚的盐酸盐为单体原料，与对苯二甲酸混合，经过中和反应、脱色处理、干燥后制成复合盐；再以多聚磷酸为溶剂，添加五氧化二磷和抗氧化剂，经过预聚合反应制备出PBO聚合物；聚合物通过双螺杆挤出机进一步进行聚合，然后通过喷丝板挤出，在磷酸水溶液中凝固成型，经过洗涤、干燥等过程，最终卷绕成型。

For resolving the lack of solubility data terephthalic acid in aqueous acetic acid, a method of determining the solubility at high temperature was developed.

针对对苯二甲酸工业中的溶解度基础数据缺乏的问题，提出了一种测定高温下对苯二甲酸在醋酸水溶液中的溶解度的方法。

The solubility of terephthalic acid in aqueous acetic acid was experimentally determined at 423.15~503.15 K and at the weight percent of the acetic acid of 60%, 70%,80%, 90% and 100% by using this method.

用该法测定了423.15~503.15K下对苯二甲酸在醋酸质量分数为60%、70%、80%、90%和100%的醋酸水溶液中的溶解度。

This one mode pays close attention to network credence foundation of the businessman very much.

这一模式非常关注商人的网络信用基础。

Cell morphology of bacterial ghost of Pasteurella multocida was observed by scanning electron microscopy and inactivation ratio was estimated by CFU analysi.

扫描电镜观察多杀性巴氏杆菌细菌幽灵和菌落形成单位评价遗传灭活率。