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We found out one kind of new orange-red long afterglow material La2O2S: Eu3+, Mg, Zr.2 In the phosphor Gd2O2S, Mg, Ti which was prepared by high-temperature solid-state method, the orange afterglow phenomenon can be seen after illuminated with UV light.3 Using the high-temperature solid-state method, Gadolinium oxysulfide phosphors doped with rare earth ions were synthesized. We can observe the red or orange phosphorescence in Gd2O2S doped with Eu3+, Sm3+, Tm3+, Yb3+, Dy3+, Er3+, Nd3+or Ho3+. This is a new result of the long afterglow phosphors research.4 Using the microwave radiation method, the new Sm3+ doped gadolinium oxysulfide phosphor, which has the orange-red long afterglow emission after illuminated with UV light or visible light, was synthesized for the first time.5 In fluorescent materials YOX doped with europium ions, the long afterglow phenomenon wasnt observed but the blue luminescence of Eu2+ and red luminescence of Eu3+ are simultaneously examined. This is a new result of the valence stability and change of Eu2+ in yttrium oxyhalide .We systematically studied the effects of the host, addition agents and reaction atmosphere on the valence change and fluorescence property of europium ions.

经过系统的研究总结得到以下的结论与成果： 1采用高温固相反应法合成了一系列稀土离子掺杂的硫氧化镧发光粉，发现了该体系中Eu~(3+)的长余辉发光，从而得到一种迄今未见文献报道的红色长余辉发光材料：La_2O_2S：Eu~(3+)，Mg，Zr； 2在Gd_2O_2S，Mg，Ti磷光粉中观察到橙色的长余辉发光现象； 3采用高温固相反应法合成了一系列稀土离子掺杂的硫氧化钆磷光粉，在掺杂Eu~(3+)、Sm~(3+)、Tm~(3+)、Yb~(3+)、Dy~(3+)、Er~(3+)、Nd~(3+)、Ho~(3+)的Gd_2O_2S中观察到红色和橙色长余辉发光； 4首次采用微波法合成了Gd_2O_2S：Sm~(3+)，Mg，Ti磷光粉，该磷光粉经紫外或可见光激发后呈现明显的橙红色长余辉发光； 5在YOX中同时观察到Eu~(2+)和Eu~(3+)的发射，系统研究了基质、添加剂及反应气氛对Eu价态和发光的影响。

FeSi nanoparticles were synthesized via thermal decomposition of iron pentacarbonyl in the solution of dioctyl ether, stabilizers oleic acid and oleylamine. The TEM images showed that FeSi nanoparticles had cubic shape, but it seemed that the composition was not uniform. According to the EDS results, the Fe:Si ratio of gray-uniform nanopaiticles was almost 1:1, and blacker FeSi nanoparticles contained more Fe atoms. Although FeSi didn't have uniform structure, it still could be proved that the incorporation of Fe and Si existed in a single nanoparticle. All possible structure, lattice, binding, morphology, surface condition would be discussed. These results indicated that perhaps FeSi2 was the main structure of the new products; however, due to incompletely combination and less synthesized time, it might still contain some part of Si and Fe structure. Besides, FeSi nanoparticles preserved the optical properties from Si atoms, but the PL intensity was much lower. The maxima PL peak appeared at 388 nm with the excitation at 300 nm. Their saturation magnetization, remanent magnetization and coercivity were measured by the SQUID, exhibiting their nearly superparamagnetic behavior.

利用热裂解系统可成功将研磨矽奈米粒子及五羰铁结合，制备出铁矽奈米粒子；从穿透式显微镜照片可知其粒子呈现立方体型态，但颜色深浅及组成不均，EDS结果则显示颜色均匀之粒子铁与矽之组成大致为1：1，颜色较深之粒子则含有较高量的铁元素；尽管组成比例并不统一，但单颗粒子同时含有矽与铁两种元素，初步说明铁矽奈米粒子之形成；进行多种结构与表面分析并探讨所有可能之键结、结构及表面元素后，推测铁矽奈米粒子可能以FeSi2之结构形成，并同时包含未重组完成的矽及铁之结构；利用PL分析得知铁矽奈米粒子确实保留矽之放光特性，并在300 nm激发光源下，於波长388 nm处有一最强放光特性峰，但整体发光效益不及研磨矽奈米粒子之结果；最后，利用超导量子干涉磁化仪量测其饱和磁化量、残留磁化量、与矫顽磁力，发现磁滞现象并不明显而几乎呈超顺磁性。

To discover new strobilurin analogues with high pesticidal activity, a series of new strobilurin derivatives containing substituted pyrazole and pyrimide ring, which included 124 novel compounds (73 compounds containing substituted pyrazole ring and 51 compounds containing substituted pyrimide ring) were designed and synthesized. In addition, 36 new intermediates were synthesized. Their structures were characterized by ~1H NMR and elemental analysis, partial compounds were characterized by MS and IR once again.

为了发现具有更好生物活性的新型Strobilurin类化合物，本论文在详尽总结文献的基础上，设计并合成了含吡唑和嘧啶环的新型Strobilurin类化合物124个，其中含吡唑环的新型Strobilurin类化合物73个，含嘧啶环的新型Strobilurin类化合物51个；未见文献报道的中间体36个，所合成的化合物经过~1H NMR、IR、LC-MS或元素分析等确定了结构。

To discover new strobilurin analogues with high pesticidal activity, a series of new strobilurin derivatives containing substituted pyrazole and pyrimide ring, which included 124 novel compounds (73 compounds containing substituted pyrazole ring and 51 compounds containing substituted pyrimide ring) were designed and synthesized. In addition, 36 new intermediates were synthesized. Their structures were characterized by 1H NMR and elemental analysis, partial compounds were characterized by MS and IR once again.

为了发现具有更好生物活性的新型Strobilurin类化合物，本论文在详尽总结文献的基础上，设计并合成了含吡唑和嘧啶环的新型Strobilurin类化合物124个，其中含吡唑环的新加热管型Strobilurin类化合物73个，含嘧啶环的新型Strob 加热管 ilurin类化合物51个；未见文献报道的中间体36个，所合成的化合物经过1H NMR、IR、LC-MS或元素分析等确定了结构。

In this research, two novel compounds in which alkylenedithiomethylene Malonic acid act as the main coordination agents and the compounds containing N atom (such as pyridine, Phenanthroline Ethanediamine and 4,4'-Bipyridinyl) act as the associating coordination agents have been synthesized by the means of solution and solid-liquid diffusing reactions. 9 coordination complexes and polymers have been designed and synthesized in which the transition metals Cu and Zn acted as the centre ions. These compounds have been characterized by X-ray single crystal diffraction analysis, and some properties of them have been tested and analyzed.

本论文设计合成了两种结构新颖的含有二硫缩烯酮结构的丙二酸类化合物，以此为主要配体，以含氮化合物(吡啶、邻菲罗啉、乙二胺和4，4'-联吡啶)为辅助配体，采用常规溶液合成和固-液相扩散等方法，设计合成了9个过渡金属Cu和Zn离子配合物和配位聚合物，采用单晶X-射线衍射等技术对晶体结构表征，并对其部分性质进行了测试和分析。

The famciclovir was synthesized from purine by a series of steps by Acylation, Decarboxylation, Reduction ,and so on; Derivatives of these intermediates is described from the 6-chloro- 9H- purin-2-amine as raw materials in different conditions when the iodine and bromide were synthesized with the addition of two intermediate 6-bromo-9H-purin-2-amine and 6-iodo-9H-purin-2-amine; There is elaborated from the main part of a acetophenone, urineaminohydrochloride, phenylhydrazine, ethyl acetoacetate as raw material through a series of reactions to synthetic 3-phenyl-4-formylphenyl pyrazole and 5-chloro-3-methyl-1-phenyl-1H-pyrazole-4-aldehyde two pyrazole aldehyde, and then with 2-amino-6-chlorine-9-(2-methicillin-oxo-co-methyl-4-yl) purine reaction of the two new pyrazole purine Schiff bases.

本论文主是采用以鸟嘌呤为原料，经过一系列的酰基化，脱羧，还原等反应作用下最终得到了产物2-氨基-9-(4-乙酰氧基-3-乙酰氧基甲基丁基)嘌呤；其中的中间体衍生物主要是阐述从以2-氨基-6-氯鸟嘌呤为原料通过在不同的条件下进行溴代与碘代分别合成了另外两种中间体2-氨基-6-溴鸟嘌呤及2-氨基-6-碘鸟嘌呤；还有一部分主要是阐述从以苯乙酮，盐酸氨基脲，苯肼，乙酰乙酸乙酯为原料通过一系列的反应先合成3-苯基-4-醛基吡唑及5-氯-3-甲基-1-苯基-1H-吡唑-4-甲醛这两个吡唑醛，然后再与2-氨基-6-氯-9-(2-甲氧羰基丁酸甲酯-4-基)嘌呤反应得到了两个新型的吡唑嘌呤席夫碱

The C_(60)-fused tetrahydrofuran derivatives are excellent synthons for further functionalization.While treated with different equiv,of BF_3·OEt_2 at various temperature,several novel functionized fullerene derivatives have been successfully synthesized.2.1,4-Fullerenols C_(60)ArOH were synthesized via the reaction of[60]fullerene with 4-substituted phenylhydrazine hydrochlorides and sodium nitrite under moisture and aerobic conditions.

这种四氢呋喃环合富勒烯衍生物作为一个合成中间体又可发生进一步的衍生化反应，其与不同当量BF_3·OEt_2在不同温度条件下可以得到二氢呋喃环合富勒烯衍生物、三元环合富勒烯衍生物等。2。

Tetrahydroisowuinolin derivatives and phthalide derivatives were designed and synthesized on the basis of a PDE4 inhibitor pharmacophore model set up through computer simulation. Some tetrahydroisowuinolin derivatives synthesized were evaluated on their activity against PDE4 for study on the structure-activity relationship.(7-cyclopentyloxy)-6-methoxy-3,4-dihydroisoquinolin-2(1H)-yl(4-hydroxy-3-methoxyphenyl)methanone (155) and Methyl 7--6-methoxy-2-(4-methoxy- benzoyl)-1-phenyl-1,2,3,4-tetrahydroisoquinoline-3-carboxylate (170) showed good activity against PDE4, which were chosen as the lead compounds to design and synthesize another analogs in order to develop selective PDE4 inhibitors with better activity.

分别设计合成了以四氢异喹啉和氨基苯酞为骨架的两类小分子杂环化合物，并对部分四氢异喹啉衍生物测试了其相关的生物活性，初步确定了其构效关系，发现了两个对PDE4有较好抑制活性的先导化合物(7-cyclopentyloxy)-6-methoxy-3，4-dihydroisoquinolin-2(1H)-yl(4-hydroxy-3-methoxyphenyl)methanone (155)和Methyl 7--6-methoxy-2-(4-methoxy- benzoyl)-1-phenyl-1，2，3，4-tetrahydroisoquinoline-3-carboxylate (170)。

A series of 2-substituted benzimidazoles were synthesized by the reaction of o-phenylenediamine with corresponding acid in polyphosphoric acid under microwave. 11 Compounds were synthesized in this way first time.

以邻苯二胺及相应的羧酸为原料，微波辐射下，合成了18种2-取代苯并咪唑衍生物，其中11种化合物的微波合成未见文献报道，研究并优化了反应条件。

In this paper, twenty novel meso-substituted porphyrins of four series were designed and synthesized by increasing the conjugation of porphyrins or introducing substituents with high fluorescence quantum yield into the meso-position of porphine, and then red OLEDs were fabricated by doping porphyrins into a suitable host using ten porphyrins compounds and their electrolumin -escence properties were tested. The main contents and results were generalized as follows:Three meso-tetrakisporphyrins 4a-c and three conjugations of porphine-triarylamine linked by styrene 10a-c were synthesized and characterized by 1H NMR, MS, UV-vis spectra and fluorescence emission spectra.

本文通过增大卟啉分子的共轭结构或将具有高荧光量子产率的基团连接到卟吩环的中位得到了四类共20个新型的卟啉化合物，并选取其中10个化合物制备有机发光器件来考察材料的电致发光性能，具体内容包括以下几个部分：设计合成了3个中位直接被三芳胺取代的卟啉化合物4a-c和3个通过苯乙烯连接的卟吩-三芳胺共轭体10a-c，通过核磁氢谱、质谱、紫外吸收光谱和荧光发射光谱表征了新化合物的结构。

As she looked at Warrington's manly face, and dark, melancholy eyes, she had settled in her mind that he must have been the victim of an unhappy attachment.

每逢看到沃林顿那刚毅的脸，那乌黑、忧郁的眼睛，她便会相信，他一定作过不幸的爱情的受害者。

Maybe they'll disappear into a pothole.

也许他们将在壶穴里消失